摘要:
Rubber compounds comprising a specific type of polyorganosiloxane of the following formula ##STR1## in which R and R' independently represent a hydrocarbon substituent and n is an integer of not smaller than 3 provided that at least 6 mole % of the substituents R and R' consists of a hydrocarbon group having Small's molecular attraction constant not smaller than 350. Carbon black is added to the polyorganosiloxane whereby various physical properties are improved including breaking strength, water and hot water resistances. The rubber compound may further comprise at least one organic rubber other than the above polyorganosiloxane.
摘要:
An improved process for molding and vulcanizing rubber products using a curing bladder, characterized in that the bladder is one which is made of a rubber compound containing (A) organic rubber and (B) polyorganosiloxane, the ratio of (A)/(B) being 95/5 to 5/95, or the bladder is one which is produced by surface treating (A) organic rubber with a silicone composition containing (A) organic rubber and (B) polyorganosiloxane, said polyorganosiloxane comprising at least two monovalent substituted or unsubstituted hydrocarbon groups having five or more carbon atoms and a C.dbd.C double bond connected to the silicon atom through at least one carbon atom, and having a degree of polymerization greater than 20.
摘要:
A curing bladder containing (A) organic rubber which is surface treated with a curable silicon composition containing (B) polyorganosiloxane, which comprises at least two monovalent substituted or unsubstituted hydrocarbon groups having five or more carbon atoms and a C.dbd.C double bond connected to the silicon atom through at least one carbon atom, and having a degree of polymerization greater than 20.
摘要:
The high aromatic oil provided in the present invention is characterized by that a glass transition point is -45 to -20.degree. C. and an aromatic component measured by Clay-Gel method accounts for 55 to 90% by weight and that a polycyclic aromatic compound measured by IP 346 method accounts for less than 3% by weight based on the whole components of hydrocarbons contained in the oil.This high aromatic oil can suitably be used for various rubber compositions such as tires, rubber vibration insulators and fenders, oil extended synthetic rubbers, printing inks and writing inks.
摘要:
In a flame-retardant rubber tire comprising an outer rubber body portion consisting essentially of a tread rubber layer, a sidewall rubber layer extending inward from each side edge of the tread rubber layer toward the vicinity of a bead portion in radial direction and a rubber chafer layer arranged in the vicinity of the bead portion, a flame-retardant rubber composition having an oxygen index of not less than 19.8 but not more than 27.5 is disposed so as to amount at least 20% by weight of the tread rubber layer. Such rubber tires are used in electric vehicles, automobiles, airplanes and the like and have excellent self-extinguishing property and flame-delaying property without damaging other rubber properties.
摘要:
A method for incorporating metal salts of .alpha.,.beta.-ethylenically unsaturated carboxylic acids into polymers and improving the cured physical properties of vulcanizable rubber compositions based on such polymers. The method includes the steps of preparing a polymer cement in a suitable organic solvent, forming a suspension of the metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid in a suitable aliphatic hydrocarbon solvent miscible with the organic solvent, mixing the polymer cement and the suspension together and thereafter removing the solvents to provide the metal salt uniformly dispersed within the polymer.
摘要:
A method of molding and vulcanizing more than 40 rubber products successively by using a curing bladder, which has been treated at the surface thereof with a silicone composition including:(a) 100 parts by weight of a polyorganosiloxane composed mainly of polydimethylsiloxane with a viscosity at 25.degree. C. of from 3,000 to 5,000,000 cst,(b) from 30 to 300 parts by weight of a polymethylhydrogensiloxane with a viscosity at 25.degree. C. of from 10 to 70 cst,(c) from 2 to 25 parts by weight of a finely powderous silica, and,(d) from 0 to 30 parts by weight of an organic acid salt of one or more of metals selected from the group consisting of zinc, magnesium, manganese and cobalt.
摘要:
A production process for a viscosity-stabilizer-containing natural rubber comprising a step of adding a viscosity stabilizer liquid diluted with a solvent to a natural rubber, and a viscosity-stabilizer-containing natural rubber latex to which added is a viscosity stabilizer dissolved in an aliphatic chain compound, and a viscosity-stabilizer-containing natural rubber obtained by adding a viscosity stabilizer liquid diluted with a solvent to a natural rubber after it was coagulated.
摘要:
Elastomer compositions comprising (A) ultra high molecular weight copolymer compositions of 1,3-conjugated dienes and aromatic vinyl compounds having a weight average molecular weight of greater than about 1,000,000 and (B) oil are described. The ultra high molecular weight copolymer compositions which are also characterized as having an intrinsic viscosity in tetrahydrofuran of at least about 4.0 may be obtained by a process which comprises polymerizing a 1,3-conjugated diene and a vinyl aromatic compound in a hydrocarbon solvent in the presence of a trimetalated 1-alkyne catalyst which comprises the reaction product of a 1-alkyne containing at least 4 carbon atoms, an organo metallic compound R.degree.M and a 1,3-conjugated diene wherein R.degree. is a hydrocarbyl group, M is an alkali metal, the mole ratio of R.degree.M to 1-alkyne is about 3:1 and the mole ratio of conjugated diene to 1-alkyne is from about 2:1 to about 30:1. The oil extended elastomer compositions of the present invention preferably contain large amounts of oil such as 80 parts or higher per 100 parts of copolymer.
摘要:
A reinforcing agent for vulcanizable rubber compounds comprises an anhydrous metal salt of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid having a crystalline structure consisting essentially of plates and fibers. Vulcanizable rubber compounds containing such reinforcing agents have improved physical properties over rubber compounds containing conventional metal carboxylic acid salts. Methods for the preparation of such anhydrous metal salts and methods for the reinforcement of vulcanizable rubber compounds therewith are also provided.