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11.发明授权Preparation of diaryliodonium salt photoinitiators having long chain ester groups concatenated with aryl groups 失效制备具有与芳基连接的长链酯基的二芳基碘盐光引发剂
公开(公告)号：US5079378A
公开(公告)日：1992-01-07
申请号：US558627
申请日：1990-07-27
Applicant: James V. Crivello
Inventor： James V. Crivello
CPC classification number: C08F2/50 , C07C69/712 , C07J9/00 , C08G59/68 , C08G65/105 , G03F7/028
Abstract: A highcarbon-containing diaryliodonium initiator for cationic polymerization which possesses enhanced solubility characteristics over conventional diaryliodonium initiators. By the disclosed process, a novel photo/thermal initiator is obtained which is uniquely characterized by the concatenation of a long chain ester with an aryl group, resulting in a total number of carbon atoms in the entire moiety attached to the iodine atom in excess of 20.
Abstract translation: 具有比常规二芳基碘鎓引发剂更高的溶解性特征的用于阳离子聚合的高碳二芳基碘鎓引发剂。 通过公开的方法，获得了一种新型的光/热引发剂，其特征在于长链酯与芳基的连接，导致连接在碘原子上的整个部分中的总碳原子数超过 20。
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12.发明授权Encapsulation method, microelectronic devices made therefrom, and heat curable compositions based on epoxy resins, diaryliodonium hexafluroantimonate salts and free radical generators 失效封装方法，由其制成的微电子器件和基于环氧树脂的热固化组合物，二芳基碘鎓六氟锑酸盐和自由基发生剂
公开(公告)号：US5015675A
公开(公告)日：1991-05-14
申请号：US386670
申请日：1989-07-31
Applicant: Erik W. Walles , John H. Lupinski , James V. Crivello
Inventor： Erik W. Walles , John H. Lupinski , James V. Crivello
Abstract: A heat curable composition is provided which is useful for encapsulating microelectronic devices using a heat curable epoxy composition having a diaryliodonium hexafluoroantimonate salt as a catalyst in combination with an effective amount of a free radical generating aromatic compound as a cocatalyst.
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公开(公告)号：US4689289A
公开(公告)日：1987-08-25
申请号：US857662
申请日：1986-04-30
Applicant: James V. Crivello
Inventor： James V. Crivello
IPC: C08F293/00 , C08G85/00 , C08K5/00 , C08L53/00 , C08L83/10 , G03F7/075 , G03C1/495 , C08F2/50 , C08F30/08 , C08F230/08
CPC classification number: G03F7/0757 , C08G85/004 , C08K5/0025 , C08L83/10 , Y10S430/114 , Y10S430/122 , Y10S430/126
Abstract: Block polymer compositions are provided which are useful as positive or negative resists utilizing aryl onium salts in combination with silicone-organic block polymers, such as polydimethylsiloxane-poly-t-butylmethacrylate block polymers. A silicone prepolymer is used in combination with certain polymerizable vinyl monomers such as t-butylmethacrylate. The silicone prepolymer has chemically combined pinacolate groups in the backbone or terminal positions which are capable of generating free-radicals upon thermolysis.
Abstract translation: 提供嵌段聚合物组合物，其可用作利用芳基鎓盐与硅氧烷 - 有机嵌段聚合物如聚二甲基硅氧烷 - 聚甲基丙烯酸叔丁酯嵌段聚合物的组合的正性或负性抗蚀剂。 硅氧烷预聚物与某些可聚合的乙烯基单体如甲基丙烯酸叔丁酯组合使用。 硅氧烷预聚物在主链或末端位置化学结合频哪对的基团，这些基团能够在热分解时产生自由基。
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14.发明授权Photopolymerizable organic compositions and diaryliodonium salts used therein 失效其中使用的可光聚合的有机组合物和二芳基碘鎓盐
公开(公告)号：US4683317A
公开(公告)日：1987-07-28
申请号：US721244
申请日：1985-04-08
Applicant: James V. Crivello , Julia L. Lee
Inventor： James V. Crivello , Julia L. Lee
Abstract: Aryliodonium salts resulting from the condensation of aryliodosotosylates and aryl ketones are provided which are used as photoinitiators to effect deep section UV cures. Deep section photopolymerizable organic materials are also provided which can be used as encapsulating agents to encapsulate a wide variety of electronic components.
Abstract translation: 提供由芳基碘代甲酸酯和芳基酮缩合产生的芳基碘盐，其用作光引发剂以实现深部分UV固化。 还提供了深层可光聚合的有机材料，其可以用作封装剂以封装各种各样的电子部件。
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公开(公告)号：US4617238A
公开(公告)日：1986-10-14
申请号：US763758
申请日：1985-08-07
Applicant: James V. Crivello , Richard P. Eckberg
Inventor： James V. Crivello , Richard P. Eckberg
CPC classification number: C08G77/38 , C08K5/0025 , Y10T428/31663
Abstract: Photo-curable vinyloxy-functional organosiloxane polymers are provided. Also provided are release coating compositions made by combining said polymers with various photo-initiators. The polymers have a unique vinyloxy functionality; and the release coating compositions cure with brief exposure to ultraviolet radiation to form premium abhesive coatings. Process for preparing the vinyloxy-functional polysiloxanes and the release coating are also disclosed.
Abstract translation: 提供光固化乙烯基氧基官能的有机硅氧烷聚合物。 还提供了通过将所述聚合物与各种光引发剂组合制备的脱模涂料组合物。 聚合物具有独特的乙烯基氧基官能团; 并且释放涂料组合物在短时间暴露于紫外线辐射下固化以形成优质的粘合剂涂层。 还公开了制备乙烯氧基官能聚硅氧烷和脱模涂层的方法。
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Patent Agency Ranking
公开(公告)号：US4535174A
公开(公告)日：1985-08-13
申请号：US667931
申请日：1984-11-02
Applicant: James V. Crivello
Inventor： James V. Crivello
CPC classification number: C07F7/1828
Abstract: Free-radical initiators are provided in the form of silylethers of arylpinacols. An aryl ketone is reacted with a monohalo- or dihalosilane having at least one olefinically unsaturated organic radical attached to silicon in the presence of an active metal reducing agent, such as magnesium.
Abstract translation: 自由基引发剂以芳基辛醇的水飞蓟宾的形式提供。 在活性金属还原剂如镁的存在下，将芳基酮与具有至少一个与烯属不饱和有机基团连接的单卤代或二卤硅烷反应。
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17.发明授权Photopolymerizable organic compositions and diaryliodonium ketone salts used therein 失效其中使用的可光聚合的有机组合物和二芳基碘鎓酮盐
公开(公告)号：US4529490A
公开(公告)日：1985-07-16
申请号：US497357
申请日：1983-05-23
Applicant: James V. Crivello , Julia L. Lee
Inventor： James V. Crivello , Julia L. Lee
IPC: C07C45/00 , C07C45/63 , C07C46/00 , C07C49/697 , C07C49/813 , C07C50/24 , C07C67/00 , C07F9/68 , C08F2/50 , C08G59/00 , C08G59/68 , C08G85/00 , C08K5/07 , C08L101/00 , G03F7/029
Abstract: Aryliodonium salts resulting from the condensation of aryliodosotosylates and aryl ketones are provided which are used as photoinitiators to effect deep section UV cures. Deep section photopolymerizable organic materials are also provided which can be used as encapsulating agents to encapsulate a wide variety of electronic components.
Abstract translation: 提供由芳基碘代甲酸酯和芳基酮缩合产生的芳基碘盐，其用作光引发剂以实现深部分UV固化。 还提供了深层可光聚合的有机材料，其可以用作封装剂以封装各种各样的电子部件。
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公开(公告)号：US4407759A
公开(公告)日：1983-10-04
申请号：US329485
申请日：1981-12-10
Applicant: James V. Crivello
Inventor： James V. Crivello
CPC classification number: C08G59/68 , C07C381/12
Abstract: Onium salts of Group VIa elements having an MF.sub.6.sup.- anion, where M is selected from P, As and Sb, have been found to be photo active under ultraviolet light. These onium salts can be employed as cationic photoinitiators when used with a variety of organic resins and cyclic organic compounds.
Abstract translation: 已经发现，在紫外光下，具有选自P，As和Sb中的M选自具有MF6-阴离子的VIa族元素的鎓盐是光活性的。 当与各种有机树脂和环状有机化合物一起使用时，这些鎓盐可用作阳离子光引发剂。
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公开(公告)号：US4399071A
公开(公告)日：1983-08-16
申请号：US357433
申请日：1982-03-12
Applicant: James V. Crivello , Julia L. Lee
Inventor： James V. Crivello , Julia L. Lee
IPC: C07C17/093 , C07C25/18 , C07C41/22 , C07C43/225 , C07C43/29 , C07C49/675 , C07F9/68 , C07F9/00 , C07F9/92
CPC classification number: C07C49/675 , C07C17/093 , C07C25/18 , C07C41/22 , C07D307/91
Abstract: A method is provided for making certain diaryliodonium salts which are useful as photoinitiators for a variety of cationic polymerizable organic materials. Reaction is effected between an aromatic iodo compound and an arylorganic aromatic compound in the presence of a peroxy organic acid and an organic sulfonic acid.
Abstract translation: 提供了制备某些可用作多种阳离子可聚合有机材料的光引发剂的二芳基碘鎓盐的方法。 在过氧有机酸和有机磺酸的存在下，在芳族碘化合物和芳基有机芳族化合物之间进行反应。
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公开(公告)号：US4388450A
公开(公告)日：1983-06-14
申请号：US243302
申请日：1981-03-13
Applicant: James V. Crivello
Inventor： James V. Crivello
IPC: C07C43/14 , C07C41/00 , C07C43/18 , C07C43/20 , C07C43/215 , C07C43/257 , C07C45/00 , C07C49/175 , C07C49/86 , C07C67/00 , C07C69/76 , C07C69/767 , C07C69/92 , C07C313/00 , C07C317/22 , C07C317/44 , C07C317/46 , C07C321/30 , C07C323/20 , C07C323/62 , C08F4/00 , C08F4/40 , C08F4/44 , C08F16/00 , C08F16/32 , C08G8/36 , C09D5/25 , C09K3/10 , C08L61/12 , C08L29/10 , C08L61/08
Abstract: Aromatic polyvinylethers and active hydrogen compound reaction products thereof have been found to provide fast heat curable molding compositions when used with various heat activated curing catalysts, for example, diaryliodonium salts in combination with aromatic polyvinylether soluble copper compounds, or dialkylhydroxyarylsulfonium salts in combination with certain organic oxidants.
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