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    Catalysts for iso-alcohol synthesis from CO+H.sub.2
    11.
    发明授权
    Catalysts for iso-alcohol synthesis from CO+H.sub.2 失效
    用于从CO + H 2合成异构醇的催化剂

    公开(公告)号：US5508246A

    公开(公告)日：1996-04-16

    申请号：US341773

    申请日：1994-11-18

    申请人： Carlos R. Apesteguia ,  Stuart L. Soled ,  Sabato Miseo

    发明人： Carlos R. Apesteguia ,  Stuart L. Soled ,  Sabato Miseo

    IPC分类号： B01J23/78 ,  B01J23/10 ,  B01J23/83 ,  B01J37/03 ,  C07B61/00 ,  C07C29/153 ,  C07C31/04 ,  C07C31/12 ,  B01J21/10 ,  B01J23/02

    CPC分类号： C07C29/153 ,  B01J23/10 ,  B01J23/83 ,  B01J37/03 ,  Y02P20/52

    摘要： A new catalyst based on coprecipitated mixtures or solid solutions of alkaline earth oxides and rare earth oxides, such as mixtures or solid solutions of magnesium oxide and cerium oxide, Mg.sub.5 CeO.sub.x, or magnesium oxide and yttrium oxide, Mg.sub.5 YO.sub.x, which catalyze aldol condensation reactions leading to the selective formation of branched C.sub.4 alcohols. The catalysts may also contain a Group IB metallic component and further an alkali dopant. Preferably, Cu in concentrations at or lower than 30 wt % and K in concentrations at or lower than 3 wt % will be used. The catalyst affords the advantage of being run at pressures lower than those required by prior art catalysts and are more active and selective to methanol and isobutanol.

    摘要翻译： 基于共沉淀的混合物或碱土氧化物和稀土氧化物的固溶体的新催化剂，例如氧化镁和氧化铈的混合物或固溶体，Mg5CeOx或氧化镁和氧化钇Mg5YOx，其催化醛醇缩合反应，导致醛醇缩合反应 选择性形成支链C4醇。 催化剂还可以含有IB族金属组分和另外的碱掺杂剂。 优选地，将使用浓度为或低于30重量％的Cu和3重量％以下的K浓度。 催化剂具有在低于现有技术催化剂所需压力的压力下运行的优点，并且对甲醇和异丁醇具有更高的活性和选择性。

    Catalysts for iso-alcohol synthesis from CO + H.sub.2
    15.
    发明授权
    Catalysts for iso-alcohol synthesis from CO + H.sub.2 失效
    用于从CO + H2 + B合成异戊醇的催化剂

    公开(公告)号：US5387570A

    公开(公告)日：1995-02-07

    申请号：US60172

    申请日：1993-05-07

    申请人： Carlos R. Apesteguia ,  Stuart L. Soled ,  Sabato Miseo

    发明人： Carlos R. Apesteguia ,  Stuart L. Soled ,  Sabato Miseo

    IPC分类号： B01J23/78 ,  B01J23/10 ,  B01J23/83 ,  B01J37/03 ,  C07B61/00 ,  C07C29/153 ,  C07C31/04 ,  C07C31/12 ,  B01J21/10 ,  B01J23/02 ,  B01J23/72

    CPC分类号： C07C29/153 ,  B01J23/10 ,  B01J23/83 ,  B01J37/03 ,  Y02P20/52

    摘要： Applicants have discovered new catalysts based on coprecipitated mixtures or solid solutions of alkaline earth oxides and rare earth oxides, such as mixtures or solid solutions of magnesium oxide and cerium oxide, Mg.sub.5 CeO.sub.x, or magnesium oxide and yttrium oxide, Mg.sub.5 YO.sub.x, which catalyze aldol condensation reactions leading to the selective formation of branched C.sub.4 alcohols. Applicants' catalysts may also contain a Group IB metallic component and further an alkali dopant. Preferably Cu in concentrations at or lower than 30 wt % and K in concentrations at or lower than 3 wt % will be used. Applicants' catalysts afford the advantage of being run at pressures lower than those required by prior art catalysts and are more active and selective to methanol and isobutanol.

    摘要翻译： 申请人已经发现了基于共沉淀混合物或碱土氧化物和稀土氧化物的固溶体的新催化剂，例如氧化镁和氧化铈的混合物或固溶体，Mg5CeOx或氧化镁和氧化钇Mg5YOx，其催化醛醇缩合反应 导致选择性形成支链C 4醇。 申请人的催化剂还可以含有IB族金属组分和另外的碱性掺杂剂。 优选使用浓度为30重量％以下且Cu浓度为3重量％以下的Cu。 申请人的催化剂具有在低于现有技术催化剂所需压力的压力下运行的优点，并且对甲醇和异丁醇具有更高的活性和选择性。