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公开(公告)号：US5489733A
公开(公告)日：1996-02-06
申请号：US346943
申请日：1994-11-29
IPC分类号： B01J23/63 , B01J23/652 , B01J23/888 , B01J27/185 , B01J27/186 , B01J27/188 , C07B61/00 , C07C5/27 , C07C9/16 , C07C5/13
CPC分类号： C07C5/2724 , B01J23/6527 , B01J23/888 , B01J27/185 , B01J27/188 , C07C5/2791
摘要： The present invention is directed to novel catalyst compositions, their preparation, and their use in a selective paraffin isomerization process. The solid acid catalyst compositions comprise a zirconium hydroxide support, a Group VIII metal, and a heteropolyacid selected from the group consisting of the exchanged aluminum salt of 12-tungstophosphoric acid, the exchanged salt of 12-tungstosilicic acid, and mixtures thereof. The use of said catalysts in an isomerization process comprises contacting said catalysts with a feed comprising C.sub.n or C.sub.n + paraffins, wherein n=4.
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2.发明授权Group IVB oxide addition to noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst 失效第IVB族氧化物添加到稀土改性二氧化硅氧化铝上的贵金属作为烃转化催化剂
公开(公告)号：US5254518A
公开(公告)日：1993-10-19
申请号：US916759
申请日：1992-07-22
IPC分类号： B01J21/12 , B01J23/10 , B01J23/62 , B01J23/63 , B01J23/656 , C10G35/09 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , B01J23/12 , B01J23/16
CPC分类号： B01J23/10 , B01J23/626 , B01J23/63 , B01J23/6567 , C10G35/09
摘要： By this invention there is provided a catalyst composition comprising a Group IVB oxide, an amorphous silica-alumina support having dispersed thereon a rare earth oxide, which as herein used also includes yttrium oxide, and a metal(s) selected from the group consisting of Group VIII noble metal(s), mixtures of Group VIII noble metal(s) and tin, mixtures of Group VIII noble metal(s) and rhenium, and mixtures of Group VIII noble metal(s), tin and rhenium. The amorphous silica-alumina support contains at least about 50% silica by weight. The catalyst can function as a hydrocarbon conversion catalyst in reactions where platinum on halided (Cl,F)-alumina is typically used.
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3.发明授权Oxide addition to noble metal on rare earth modified silica alumina as hydrocarbon conversion catalyst 失效氧化物加入贵金属稀土改性二氧化硅作为烃转化催化剂
公开(公告)号：US5457253A
公开(公告)日：1995-10-10
申请号：US359764
申请日：1994-12-20
IPC分类号： B01J21/12 , B01J23/10 , B01J23/62 , B01J23/63 , B01J23/656 , C10G35/09 , C10G45/10 , C10G45/12 , C10G45/62 , C10G45/64 , C07C2/52 , C07C5/13 , C10G35/06 , C10G73/00
CPC分类号： B01J23/10 , B01J23/626 , B01J23/63 , B01J23/6567 , C10G35/09
摘要： By this invention there is provided a catalyst composition comprising a Group IVB oxide, an amorphous silica-alumina support having dispersed thereon a rare earth oxide, which as herein used also includes yttrium oxide, and a metal(s) selected from the group consisting of Group VIII noble metal(s), mixtures of Group VIII noble metal(s) and tin, mixtures of Group VIII noble metal(s) and rhenium, and mixtures of Group VIII noble metal(s), tin and rhenium. The amorphous silica-alumina support contains at least about 50% silica by weight. The catalyst can function as a hydrocarbon conversion catalyst in reactions where platinum on halided (Cl,F)-alumina is typically used.
摘要翻译： 通过本发明，提供了一种催化剂组合物，其包含IVB族氧化物，其上分散有稀土氧化物的无定形二氧化硅 - 氧化铝载体，其在本文中还包括氧化钇和选自以下的金属： VIII族贵金属，第VIII族贵金属和锡的混合物，第VIII族贵金属和铼的混合物，以及第VIII族贵金属，锡和铼的混合物。 无定形二氧化硅 - 氧化铝载体含有至少约50重量％的二氧化硅。 在通常使用卤化（Cl，F） - 氧化铝上的铂的反应中，催化剂可以用作烃转化催化剂。
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公开(公告)号：US5420092A
公开(公告)日：1995-05-30
申请号：US58605
申请日：1993-05-06
IPC分类号： B01J23/63 , B01J23/652 , B01J23/888 , B01J27/185 , B01J27/186 , B01J27/188 , C07B61/00 , C07C5/27 , C07C9/16 , B01J27/18 , B01J21/08 , B01J23/30 , B01J27/182
CPC分类号： C07C5/2724 , B01J23/6527 , B01J23/888 , B01J27/185 , B01J27/188 , C07C5/2791
摘要： The present invention is directed to novel catalyst compositions, their preparation, and their use in a selective paraffin isomerization process. The solid acid catalyst compositions comprise a silica support, a Group VIII metal, and a heteropolyacid selected from the group consisting of 12-tungstophosphoric acid, 12-tungstosilicic acid, the exchanged aluminum salt of 12-tungstophosphoric acid, the exchanged aluminum salt of 12-tungstosilicic acid and mixtures thereof. The use of said catalysts in an isomerization process comprises contacting said catalysts with a feed comprising C.sub.n or C.sub.n + paraffins, wherein n=4.
摘要翻译： 本发明涉及新型催化剂组合物及其制备方法及其在选择性石蜡异构化方法中的应用。 固体酸催化剂组合物包含二氧化硅载体，第Ⅷ族金属和选自12-钨磷酸，12-钨硅酸，12-钨磷酸的交换的铝盐，12-交换的铝盐12 钨硅酸及其混合物。 在异构化方法中使用所述催化剂包括使所述催化剂与包含C n或C n +链烷烃的进料接触，其中n = 4。
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公开(公告)号：US10023814B2
公开(公告)日：2018-07-17
申请号：US14714703
申请日：2015-05-18
申请人： Michael P. Lanci , Stuart L. Soled , Javier Guzman , Sabato Miseo , Thomas Elmer Green , Joseph Ernest Baumgartner
发明人： Michael P. Lanci , Stuart L. Soled , Javier Guzman , Sabato Miseo , Thomas Elmer Green , Joseph Ernest Baumgartner
IPC分类号： C10G45/52 , C10G45/00 , B01J23/42 , B01J23/44 , B01J31/02 , B01J31/28 , B01J21/12 , B01J23/46 , C10G45/34 , C10G45/46 , B01J37/02 , B01J21/08 , B01J21/04
摘要： Methods are provided for modifying hydrogenation catalysts having silica supports (or other non-alumina supports) with additional alumina, and using such catalysts to achieve unexpectedly superior hydrogenation of feedstocks. The modified hydrogenation catalysts can have a relatively low cracking activity while providing an increased activity for hydrogenation.
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公开(公告)号：US09035107B2
公开(公告)日：2015-05-19
申请号：US13515057
申请日：2010-12-17
申请人： Teng Xu , Stuart L. Soled , Edward A. Lemon , Joseph E. Baumgartner , Sabato Miseo , George H. Gamble
发明人： Teng Xu , Stuart L. Soled , Edward A. Lemon , Joseph E. Baumgartner , Sabato Miseo , George H. Gamble
CPC分类号： B01J23/42 , B01J21/08 , B01J37/0203 , C07C5/367 , C07C37/07 , C07C37/08 , C07C2523/58 , Y02P20/52 , C07C15/04 , C07C39/04
摘要： In a process for the dehydrogenation of dehydrogenatable hydrocarbons, a feed comprising dehydrogenatable hydrocarbons is contacted with a catalyst comprising a support and a dehydrogenation component under dehydrogenation conditions effective to convert at least a portion of the dehydrogenatable hydrocarbons in the feed. The catalyst is produced by a method comprising treating the support with a liquid composition comprising the dehydrogenation component or a precursor thereof and at least one organic dispersant selected from an amino alcohol and an amino acid.
摘要翻译： 在可脱氢烃脱氢的方法中，包含可脱氢烃的进料在有效转化进料中至少一部分可脱氢烃的脱氢条件下与包含载体和脱氢组分的催化剂接触。 催化剂通过包括用包含脱氢组分或其前体的液体组合物和至少一种选自氨基醇和氨基酸的有机分散体处理载体的方法制备。
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公开(公告)号：US20140027350A1
公开(公告)日：2014-01-30
申请号：US12315272
申请日：2008-12-02
申请人： Stuart L. Soled , Sabato Miseo , Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Hank JAn Tromp
发明人： Stuart L. Soled , Sabato Miseo , Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Hank JAn Tromp
IPC分类号： C10G45/10
CPC分类号： C10G45/10 , B01J21/16 , B01J23/85 , B01J23/8885 , B01J35/0013 , B01J37/0009 , B01J37/20 , C10G49/04 , C10G2300/301 , C10G2300/4018
摘要： The invention relates to a method for hydroprocessing hydrocarbon feedstocks, said process comprising contacting a hydrocarbon feedstock under hydroprocessing conditions with a bulk catalyst composition comprising bulk metal particles that comprise at least one Group VIII non-noble metal, at least one Group VIB metal and nanoparticles. The bulk metal catalyst composition comprises bulk metal particles that may be prepared by a manufacturing process comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles.
摘要翻译： 本发明涉及一种用于加氢处理烃原料的方法，所述方法包括在加氢处理条件下使烃原料与包含至少一种VIII族非贵金属，至少一种VIB族金属和纳米颗粒的本体金属颗粒的本体催化剂组合物接触 。 本体金属催化剂组合物包含可通过制备方法制备的本体金属颗粒，其包括以下步骤：在反应混合物（i）分散在液体中后，将具有小于约1m的尺寸的可分散纳米颗粒混合，（ii） 至少一种VIII族非贵金属化合物，（iii）至少一种VIB族金属化合物，和（iv）质子液体; 并在所述纳米颗粒存在下使所述至少一种第VIII族非贵金属化合物和所述至少一种第ⅥB族金属反应。
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公开(公告)号：US08203017B2
公开(公告)日：2012-06-19
申请号：US13006006
申请日：2011-01-13
申请人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Luo Shifang , Sabato Miseo , James Clarke Vartuli
发明人： Richard Henry Schlosberg , Jose Guadalupe Santiesteban , Stuart L. Soled , Andrzej Mariusz Malek , Joseph E. Baumgartner , Luo Shifang , Sabato Miseo , James Clarke Vartuli
CPC分类号： B01J29/0325 , B01J23/462 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0203 , B01J2229/186 , C07C51/36 , C07C67/303 , C07C2601/14 , C07C61/22 , C07C61/24 , C07C61/08 , C07C61/09 , C07C69/75
摘要： A process for hydrogenating benzenepolycarboxylic acids or derivatives thereof, such as esters and/or anhydrides, is provided.
摘要翻译： 提供了一种用于氢化苯多羧酸或其衍生物，例如酯和/或酸酐的方法。
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公开(公告)号：US20110294656A1
公开(公告)日：2011-12-01
申请号：US13150662
申请日：2011-06-01
申请人： Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Iulian Nistor , Pallassana S. Venkataraman , Chris E. Kliewer , Robert J. Chimenti , Javier Guzman , Gordon Kennedy , Doron Levin
发明人： Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Iulian Nistor , Pallassana S. Venkataraman , Chris E. Kliewer , Robert J. Chimenti , Javier Guzman , Gordon Kennedy , Doron Levin
CPC分类号： B01J31/04 , B01J23/882 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J31/0237 , B01J31/0247 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J37/0203 , B01J37/08 , B01J37/20 , B01J2231/60 , B01J2523/00 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/06 , C10G45/08 , C10G2300/1074 , C10G2300/202 , C10G2300/703 , C11B3/02 , B01J2523/56 , B01J2523/69 , B01J2523/847 , B01J2523/55 , B01J2523/845 , B01J2523/68
摘要： Described herein is a catalyst precursor composition comprising at least one metal from Group 6 of the Periodic Table of the Elements, at least one metal from Groups 8-10 of the Periodic Table of the Elements, and a reaction product formed from (i) a first organic compound containing at least one amine group, and (ii) a second organic compound separate from said first organic compound and containing at least one carboxylic acid group. A process for preparing the catalyst precursor composition is also described, as is sulfiding the bulk mixed metal oxide catalyst precursor composition to form a hydroprocessing catalyst.
摘要翻译： 本文描述的催化剂前体组合物包含元素周期表第6族中的至少一种金属，元素周期表第8-10族的至少一种金属和由（i） 含有至少一个胺基的第一有机化合物，和（ii）与所述第一有机化合物分离并含有至少一个羧酸基团的第二有机化合物。 还描述了制备催化剂前体组合物的方法，就是将本体混合金属氧化物催化剂前体组合物硫化以形成加氢处理催化剂。
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公开(公告)号：US07776205B2
公开(公告)日：2010-08-17
申请号：US11096499
申请日：2005-04-01
申请人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts
发明人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts
IPC分类号： C10G27/00 , C10G45/04 , C10G45/60 , C10G11/02 , C10G11/04 , C10G47/02 , C10G47/04 , C10G35/00 , C10G35/06 , B01J38/22 , B01J35/02 , B01J8/08
CPC分类号： C10G45/08 , B01J23/8877 , B01J23/888 , B01J37/0009 , B01J37/04 , C10G45/38 , C10G45/50 , C10G45/60 , C10G47/02 , C10G49/04
摘要： The instant invention relates to a process to produce liquid products through the hydroprocessing of hydrocarbonaceous feedstreams in the presence of a bulk metal hydroprocessing catalyst.
摘要翻译： 本发明涉及在本体金属加氢催化剂存在下通过烃类原料流的加氢处理来生产液体产物的方法。
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