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公开(公告)号：US09950979B2
公开(公告)日：2018-04-24
申请号：US15313606
申请日：2015-05-20
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Michael Mirion , Thomas Quell , Siegfried R. Waldvogel
IPC分类号： C07C41/30
摘要： A process for preparing unsymmetric biphenols, comprising: a) adding a first substituted phenol to the reaction mixture; b) adding a second substituted phenol having different substitution than the first phenol to the reaction mixture; c) adding selenium dioxide to the reaction mixture; d) adding a solvent; and e) heating the reaction mixture such that the first substituted phenol and the second phenol having different substitution are converted to an unsymmetric biphenol.
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公开(公告)号：US09624153B2
公开(公告)日：2017-04-18
申请号：US15103842
申请日：2014-12-10
申请人： Evonik Degussa GmbH , Marc Becker , Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Hanna Hahn , Marina Lazar , Markus Priske , Guido Stochniol
发明人： Marc Becker , Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Hanna Hahn , Marina Lazar , Markus Priske , Guido Stochniol
IPC分类号： C07C45/50 , B01D5/00 , B01J31/00 , B01D61/38 , B01J31/02 , B01J31/18 , C07C45/78 , B01D61/36 , B01J31/24 , C07C45/79 , C07C45/82
CPC分类号： C07C45/50 , B01D5/006 , B01D5/0072 , B01D61/362 , B01D61/38 , B01D2311/02 , B01D2311/04 , B01D2311/06 , B01D2311/263 , B01D2311/2669 , B01D2311/2673 , B01J31/0292 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J2231/321 , B01J2531/822 , C07C45/786 , C07C45/79 , C07C45/82 , C07C47/02
摘要： The invention relates to processes for preparing aldehydes by hydroformylation of alkenes, in which an alkene-containing feed mixture is subjected to a primary hydroformylation with synthesis gas in the presence of a homogeneous catalyst system, the primary hydroformylation being effected in a primary reaction zone from which a cycle gas containing at least some of the products and unconverted reactants of the primary hydroformylation are drawn off continuously and partly condensed, with recycling of uncondensed components of the cycle gas into the primary reaction zone, and with distillative separation of condensed components of the cycle gas in an aldehyde removal stage to give an aldehyde-rich mixture and a low-aldehyde mixture. The problem that it addresses is that of developing the process such that it achieves high conversions and affords aldehyde in good product quality even in the case of a deteriorating raw material position. More particularly, a solution is to be found for making legacy oxo process plants capable of utilizing lower-value raw material sources. This problem is solved by separating the low-aldehyde mixture into a retentate and a permeate by means of a membrane separation unit in such a way that alkenes present in the low-aldehyde mixture become enriched in the permeate, while alkanes present in the low-aldehyde mixture become enriched in the retentate. The alkene-rich permeate is then transferred into a secondary reaction zone and subjected to a secondary hydroformylation therein with synthesis gas in the presence of an SILP catalyst system. The reaction product obtained from the secondary hydroformylation is recycled into the aldehyde removal stage.
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13.发明授权Mixture containing a monophosphite ligand and the use thereof for catalysis of a hydroformylation reaction 有权含有单亚磷酸酯配体的混合物及其用于催化加氢甲酰化反应的用途公开(公告)号：US09221851B2
公开(公告)日：2015-12-29
申请号：US14716470
申请日：2015-05-19
申请人： Katrin Marie Dyballa , Robert Franke , Frank Geilen , Dieter Hess , Dirk Fridag
发明人： Katrin Marie Dyballa , Robert Franke , Frank Geilen , Dieter Hess , Dirk Fridag
CPC分类号： C07F9/141 , B01J31/185 , B01J31/2221 , C07C45/50 , C07C45/505 , C07F9/145 , C07F9/65742 , C07F9/65744 , C07F15/0073 , C07C47/02
摘要： A mixture containing a monophosphite ligand is useful for the catalysis of a hydroformylation reaction.
摘要翻译： 含有单亚磷酸酯配体的混合物可用于催化加氢甲酰化反应。
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14.发明授权Mixture of bisphosphites and use thereof as a catalyst mixture in hydroformylation 有权二亚磷酸酯的混合物及其在加氢甲酰化中作为催化剂混合物的用途公开(公告)号：US09206105B2
公开(公告)日：2015-12-08
申请号：US14434879
申请日：2013-09-27
申请人： Andrea Christiansen , Robert Franke , Dirk Fridag , Dieter Hess , Katrin Marie Dyballa , Bernd Hannebauer
发明人： Andrea Christiansen , Robert Franke , Dirk Fridag , Dieter Hess , Katrin Marie Dyballa , Bernd Hannebauer
IPC分类号： C07C45/50 , B01J31/18 , B01J31/02 , C07F9/6568
CPC分类号： C07C45/505 , B01J19/24 , B01J31/0209 , B01J31/0237 , B01J31/0271 , B01J31/185 , B01J2219/24 , B01J2231/321 , B01J2531/822 , C07C45/50 , C07C67/38 , C07F9/65683 , C07F9/65685 , C07F9/6571 , C07F9/65746 , C07F15/0073 , C07C47/02
摘要： The invention relates to a mixture of bisphosphites, to a process for preparation thereof, and to the reaction thereof with metals to give mixtures comprising complexes of the constitutionally isomeric bisphosphites and the metal, and to the use thereof as a catalytically active composition in hydroformylation reactions, and also to the hydroformylation reaction itself.
摘要翻译： 本发明涉及二亚磷酸酯的混合物，其制备方法及其与金属的反应，得到包含组成异构双亚磷酸酯和金属的络合物的混合物，以及其在加氢甲酰化反应中作为催化活性组合物的用途 ，还涉及加氢甲酰化反应本身。
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15.发明申请PROCESS FOR PREPARING 2,2'-SELENOBIARYL ETHERS OR 4,4'-SELENOBIARYL ETHERS USING SELENIUM DIOXIDE 审中-公开使用二氧化二铱制备2,2'-二苯并噻唑或4,4'-己二醇的方法公开(公告)号：US20150336885A1
公开(公告)日：2015-11-26
申请号：US14720063
申请日：2015-05-22
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
IPC分类号： C07C391/02
CPC分类号： C07C391/02
摘要： A process for preparing a 2,2′-selenobiaryl ether or a 4,4′-selenobiaryl ether, proceeds by a) adding a first phenol to the reaction mixture, b) adding a second phenol to the reaction mixture, c) adding selenium dioxide to the reaction mixture, d) adding a base having a pKb in the range from 8 to 11 to the reaction mixture, and e) adjusting the reaction temperature of the reaction mixture such that the first phenol and the second phenol are converted to said 2,2′-selenobiaryl ether or said 4,4′-selenobiaryl ether.
摘要翻译： 一种制备2,2'-硒二芳基醚或4,4'-硒二芳基醚的方法是通过以下步骤：a）向反应混合物中加入第一酚，b）向反应混合物中加入第二酚，c）加入硒 二氧化碳反应混合物，d）向反应混合物中加入具有8至11范围内的pKb的碱，以及e）调节反应混合物的反应温度，使得第一酚和第二酚转化为所述 2,2'-硒二芳基醚或所述4,4'-硒二芳基醚。
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公开(公告)号：US09879353B2
公开(公告)日：2018-01-30
申请号：US14772874
申请日：2013-12-10
摘要： Electrochemical process for coupling two phenols of different oxidation potential, and novel biphenols which can be prepared by this electrochemical coupling.
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公开(公告)号：US09670585B2
公开(公告)日：2017-06-06
申请号：US14773228
申请日：2013-12-10
摘要： The invention relates to an electrochemical method for the selective coupling of a phenol to a naphthol which differ in their oxidation potential. The invention also relates to compounds which can be produced by electrochemical coupling.
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公开(公告)号：US09221850B2
公开(公告)日：2015-12-29
申请号：US14715334
申请日：2015-05-18
申请人： Katrin Marie Dyballa , Robert Franke , Dieter Hess , Dirk Fridag , Frank Geilen
发明人： Katrin Marie Dyballa , Robert Franke , Dieter Hess , Dirk Fridag , Frank Geilen
CPC分类号： C07F9/141 , B01J31/185 , B01J31/2221 , C07C45/50 , C07C45/505 , C07F9/145 , C07F9/65742 , C07F9/65744 , C07F15/0073 , C07C47/02
摘要： A novel monophosphite ligand having a tert-butyloxycarbonyl group is useful as a ligand in hydroformylation of an olefin.
摘要翻译： 具有叔丁氧基羰基的新型单亚磷酸酯配体可用作烯烃加氢甲酰基化中的配体。
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公开(公告)号：US20150336865A1
公开(公告)日：2015-11-26
申请号：US14719900
申请日：2015-05-22
申请人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
发明人： Katrin Marie Dyballa , Robert Franke , Dirk Fridag , Siegfried R. Waldvogel , Thomas Quell , Michael Mirion
IPC分类号： C07C37/11
摘要： A process for preparing a 2,2′-biphenol, proceeds by a) adding a first phenol to a reaction mixture, b) adding a second phenol to the reaction mixture, c) adding selenium dioxide to the reaction mixture, d) adding an acid having a pKa in the range from 0.0 to 5.0 to the reaction mixture, and e) heating the reaction mixture such that the first phenol and the second phenol are converted to said 2,2′-biphenol.
摘要翻译： 制备2,2'-联苯酚的方法是由a）向反应混合物中加入第一酚，b）向反应混合物中加入第二酚，c）向反应混合物中加入二氧化硒，d） 对反应混合物具有0.0-5.0的pKa的酸，以及e）加热反应混合物使得第一酚和第二酚被转化成所述的2,2'-联苯酚。
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20.发明申请PROCESS FOR PHOTOCATALYTIC ACCEPTOR-FREE DEHYDROGENATION OF ALKANES AND ALCOHOLS 审中-公开碱性和醇类光催化无接触脱氢工艺公开(公告)号：US20150239814A1
公开(公告)日：2015-08-27
申请号：US14630018
申请日：2015-02-24
申请人： Robert FRANKE , Jennifer Julis , Dirk Fridag , Katrin Marie Dyballa , Nico Weding , Abhishek Dutta Chowdhury , Matthias Beller , Ralf Jackstell , Ivana Fleischer , Beatrice Percia
发明人： Robert FRANKE , Jennifer Julis , Dirk Fridag , Katrin Marie Dyballa , Nico Weding , Abhishek Dutta Chowdhury , Matthias Beller , Ralf Jackstell , Ivana Fleischer , Beatrice Percia
CPC分类号： C07C45/002 , C07C5/333 , C07C2531/02 , C07C2531/20 , C07C2531/24 , C07C2601/14 , C07C2601/18 , C07C49/403 , C07C49/413 , C07C49/08 , C07C47/02 , C07C11/02 , C07C13/263
摘要： A process for photocatalytic acceptor-free dehydrogenation of alkanes and alcohols, in which an alkane or an alcohol is irradiated in the presence of a rhodium complex containing organic phosphorus(III) compounds as ligands as a catalyst, and in the presence of at least one Lewis base is provided.
摘要翻译： 在含有有机磷（III）化合物作为催化剂的有机磷（III）化合物的铑络合物的存在下，在存在有至少一种有机磷（III））作为催化剂的情况下，对烷烃和醇进行光催化受体无氢脱氢的方法， 提供路易斯碱。
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