摘要:
Microporous materials that include thermoplastic organic polyolefin polymer (e.g., ultrahigh molecular weight polyolefin, such as polyethylene), particulate filler (e.g., precipitated silica), and a network of interconnecting pores, are described. The microporous materials of the present invention possess controlled volatile material transfer properties. The microporous materials can have a density of at least 0.8 g/cm3; and a volatile material transfer rate, from the volatile material contact surface to the vapor release surface of the microporous material, of from 0.04 to 0.6 mg/(hour*cm2). In addition, when volatile material is transferred from the volatile material contact surface to the vapor release surface, the vapor release surface is substantially free of volatile material in liquid form.
摘要翻译:描述了包括热塑性有机聚烯烃聚合物(例如超高分子量聚烯烃,例如聚乙烯),颗粒填料(例如沉淀二氧化硅)和互连孔网络的微孔材料。 本发明的微孔材料具有控制的挥发性物质转移性能。 微孔材料可以具有至少0.8g / cm 3的密度; 以及从微孔材料的挥发性物质接触表面到蒸汽释放表面的挥发性物质转移速率为0.04至0.6mg /(小时* cm2)。 此外,当挥发性物质从挥发性物质接触表面转移到蒸汽释放表面时,蒸汽释放表面基本上不含液体形式的挥发性物质。
摘要:
Provided is a microporous material including (a) a polyolefin matrix which contains ultrahigh molecular weight polyolefin having a molecular weight greater than 7 million grams per mole and 30 to 80 weight percent high density polyolefin, (b) finely divided particulate filler having a density ranging from 2.21 to 3.21 grams per cubic centimeter distributed throughout the matrix, and (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material. The microporous material has a density ranging from 0.6 to 0.9 g/cc, a Sheffield smoothness of less than or equal to 40, and an air flow rate of 1000 or more Gurley seconds. Printed electronic devices prepared from and methods of making the microporous material also are provided.
摘要:
The present invention is directed to biodegradable microporous materials and multi-layer articles containing them. The biodegradable microporous materials comprise: (a) a polyolefin matrix, (b) finely divided, particulate filler distributed throughout the matrix, (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and (d) a biodegradation promoting material distributed throughout the matrix. Also provided are multilayer articles prepared from the above-described microporous materials.
摘要:
The present invention is directed to microporous materials comprising: (a) a polymeric matrix comprising a renewable polymer and optionally a polyolefin that is the same as or different from the renewable polymer, (b) finely divided, particulate filler distributed throughout the matrix, and (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material. Also provided are multilayer articles prepared from the above-described microporous materials.
摘要:
The present invention is related to treated filler and processes for producing said treated filler. Untreated filler slurry can be treated with a treating material and, optionally, a coupling material and then subjected to conventional drying method(s), to produce the treated filler of the invention. Treated filler has a wide variety of applications including but not limited to battery separators and rubber compositions such as tires.
摘要:
A microporous material is provided in the form of a singly extruded microporous sheet having opposing first and second surfaces, comprising: (a) a polymeric matrix component comprising: (i) 25 to 75 weight percent of low melt flow index polypropylene having a melt flow index ranging from 0.1 to 30 grams/10 minutes; (ii) 12.5 to 25 weight percent of ultrahigh molecular weight polyethylene; and (iii) 0 to 62.5 weight percent of high density polyethylene; (b) a finely divided, inorganic filler component dispersed throughout the polymeric matrix; and (c) a network of interconnecting pores communicating substantially throughout the microporous material, the pores constituting 10 to 80 percent by volume of the microporous material. The sheet typically has a thickness ranging from 3 to 8 mils and a stiffness of greater than 1 g/micron. In certain embodiments, the sheet has a density of greater than 0.75 g/cc. Also provided are multi-layer articles.
摘要:
The present invention is directed to biodegradable microporous materials and multi-layer articles containing them. The biodegradable microporous materials comprise: (a) a polyolefin matrix, (b) finely divided, particulate filler distributed throughout the matrix, (c) at least 35 percent by volume of a network of interconnecting pores communicating throughout the microporous material, and (d) a biodegradation promoting material distributed throughout the matrix. Also provided are multilayer articles prepared from the above-described microporous materials.
摘要:
Amorphous precipitated silica which may be used to form battery separators of very low specific resistance is characterized by (a) a CTAB surface area in the range of from 140 to 185 m.sup.2 /g; (b) a DBP oil absorption in the range of from 210 to 310 cm.sup.3 /100 g; (c) a mean ultimate particle size in the range of from 10 to 18 nm; (d) a total intruded volume in the range of from 2.6 to 4 cm.sup.3 /g; and (e) an intruded volume in the range of from 0.9 to 2 cm.sup.3 /g for pores having diameters in the range of from 20 to 100 nm.
摘要:
Amorphous precipitated silica which may be used to form battery separators of very low shrinkage is characterized by (a) a BET surface area in the range of from 60 to 200 m.sup.2 /g; (b) a CTAB surface area in the range of from 40 to 150 m.sup.2 /g; (c) a DBP oil absorption in the range of from 180 to 300 cm.sup.3 /100 g; (d) a mean ultimate particle size in the range of from 20 to 30 nm; (e) a total intruded volume in the range of from 2.5 to 4 cm.sup.3 /g; (f) an intruded volume in the range of from 0.3 to 1.2 cm.sup.3 /g for pores having diameters in the range of from 20 to 100 nm; and (g) a pore diameter at the maximum of the volume pore size distribution function in the range of from 30 to 200 nm.
摘要:
Provided is a multi-layer article including (1) a sheet of microporous material having opposing surfaces, and (2) an adhesive composition applied over at least a portion of at least one of the surfaces of the sheet. The microporous material contains (A) a polymeric matrix component of 5 to 100 weight percent of low melt flow index polypropylene; 0 to 90 weight percent of ultrahigh molecular weight polyethylene; and 0 to 90 weight percent of high density polyethylene; (B) a finely divided, particulate filler component dispersed throughout the polymeric matrix (A) including siliceous and non-siliceous materials; and (C) a network of interconnecting pores communicating substantially throughout the microporous material, the pores constituting 10 to 80 percent by volume of the microporous material, wherein the weight ratio of filler component (B) to polymeric matrix component (A) ranges from 0.1 to 10.0.