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23 条记录 (耗时 0.052 秒)

    Reduction of fouling in thermal processing of olefinic feedstocks
    12.
    发明申请
    Reduction of fouling in thermal processing of olefinic feedstocks 审中-公开
    减少烯烃原料热处理中的结垢

    公开(公告)号：US20060222555A1

    公开(公告)日：2006-10-05

    申请号：US11364249

    申请日：2006-02-28

    申请人： Patricio Herrera ,  Andrzej Krzywicki ,  Micheal Sprague

    发明人： Patricio Herrera ,  Andrzej Krzywicki ,  Micheal Sprague

    IPC分类号： C22C38/44

    CPC分类号： C10G75/00

    摘要： Reduction of fouling in a thermal process for treating feed streams comprising naphtha, pyrolysis oils or a mixture thereof said feed stream having a combined olefinic content from 10 to 50 weight % and the balance inert hydrocarbons at a temperature from 100° C. to 300° C. which comprises decreasing the amount of carbon steel in the apparatus contacting said feed stream and increasing the amount of stainless steel.

    摘要翻译： 在用于处理包含石脑油，热解油或其混合物的进料流的热处理中减少污垢，所述进料流具有10至50重量％的组合的烯烃含量，余量为惰性烃，温度为100℃至300℃ 其包括减少与所述进料流接触的装置中的碳钢的量并增加不锈钢的量。

    Anode catalysts for fuel cell membrane reactors
    15.
    发明授权
    Anode catalysts for fuel cell membrane reactors 有权
    用于燃料电池膜反应器的阳极催化剂

    公开(公告)号：US08574786B2

    公开(公告)日：2013-11-05

    申请号：US13024249

    申请日：2011-02-09

    申请人： Jing-li Luo ,  Xian-zhu Fu ,  Nemanja Danilovic ,  Karl T. Chuang ,  Alan R. Sanger ,  Andrzej Krzywicki

    发明人： Jing-li Luo ,  Xian-zhu Fu ,  Nemanja Danilovic ,  Karl T. Chuang ,  Alan R. Sanger ,  Andrzej Krzywicki

    IPC分类号： H01M4/90

    CPC分类号： H01M4/8652 ,  H01M4/90 ,  H01M4/9016 ,  H01M8/0637 ,  H01M2004/8684 ,  H01M2008/1095 ,  Y02E60/566

    摘要： Anode catalysts for conversion of hydrocarbon feeds in solid oxide fuel cell membrane reactors. An anode catalyst may be a mixture of a metal with a metal oxide, for example a mixture of copper or copper-nickel alloy or copper-cobalt alloy with Cr2O3. Mixed oxides can be prepared by dissolving into water soluble salts of the different metals, chelating the metal ions with a chelating agent, neutralizing the solution, removing water by evaporation to form a gel which then is dried, and finally heating the dried gel to form a mixed oxide of the different metals. The chelating agent can be citrate ions, and ammonia can be added to the solution until the pH of the solution is about 8. The mixed oxide so formed then is reduced, for example by hydrogen, to form a composite comprising the metal (Cu, Cu—Co, Cu—Ni) and metal oxide, here Cr2O3. Typically, the composite oxides so formed comprise approximately spherical nanoparticles, and the reduced composites are nanoparticles comprising very small particles of the metal within a network of the oxide, Cr2O3.

    摘要翻译： 用于在固体氧化物燃料电池膜反应器中转化烃进料的阳极催化剂。 阳极催化剂可以是金属与金属氧化物的混合物，例如铜或铜 - 镍合金或铜 - 钴合金与Cr 2 O 3的混合物。 混合氧化物可以通过将不同金属的水溶性盐溶解，用螯合剂螯合金属离子，中和溶液，通过蒸发除去水以形成凝胶，然后干燥，最后加热干燥的凝胶形成 不同金属的混合氧化物。 螯合剂可以是柠檬酸根离子，并且可以向溶液中加入氨，直到溶液的pH为约8.然后如此形成的混合氧化物例如由氢还原形成包含金属（Cu， Cu-Co，Cu-Ni）和金属氧化物，这里是Cr 2 O 3。 通常，如此形成的复合氧化物包含近似球形的纳米颗粒，并且还原的复合材料是在氧化物Cr 2 O 3的网络内包含非常小的金属颗粒的纳米颗粒。

    IN SITU REMOVAL OF IRON COMPLEXES DURING CRACKING
    16.
    发明申请
    IN SITU REMOVAL OF IRON COMPLEXES DURING CRACKING 审中-公开
    在开裂期间钢铁复合物的原位移除

    公开(公告)号：US20120149962A1

    公开(公告)日：2012-06-14

    申请号：US13293259

    申请日：2011-11-10

    申请人： Vasily Simanzhenkov ,  Oleksiy Golovchenko ,  Andrzej Krzywicki

    发明人： Vasily Simanzhenkov ,  Oleksiy Golovchenko ,  Andrzej Krzywicki

    IPC分类号： C07C4/02

    CPC分类号： C07C4/04 ,  C10G9/16 ,  C10G75/04

    摘要： The presence of complexes predominantly of iron and one or more of chromium, nickel and oxygen and mixtures thereof on the surface of a stainless steel exposed to a feed stream containing hydrocarbons at elevated temperatures tends to give rise to decomposition products of the hydrocarbon. The amount of iron complexes may be reduced in situ without stopping the process by adding to the feed stream 0.001 to 1 vol % a silane and optionally from 0 to 500 ppm based on the weight of the feed stream of sulphur or a sulphur containing compound.

    摘要翻译： 主要由铁和铬，镍和氧中的一种或多种的混合物及其混合物的存在在暴露于含有烃的进料流的不锈钢的表面上升高，往往会引起烃的分解产物。 基于硫或含硫化合物的进料流的重量，铁配合物的量可以原位减少而不停止该方法，通过向进料流中加入0.001至1体积％的硅烷和任选的0至500ppm。