Abstract:
A method for producing a silica aerogel, includes: (i) adding an electroconductive polymer to the sol of an aqueous alkaline silicate solution to convert the sol to a gel; (ii) aging the gel to cause said gel to grow; (iii) hydrophobizing the gel; and (iv) drying the gel. Further provided is a silica aerogel including an electroconductive polymer. Still further provided is a heat-insulation material, including the above-described silica aerogel and fibers.
Abstract:
A heat insulation sheet includes, as a substrate, a silica aerogel with low heat conductivity and high mechanical strength In a hydrophobization reaction of a hydrogel, a silane coupling agent having a reactive organic functional group is used to conduct hydrophobization, and, after volatilization of a solvent in a drying step, the temperature is elevated to 100° C. or higher that is a reaction-starting temperature, thereby reacting and bonding the reactive functional group and a fiber to each other. This allows prevention of detachment or loss of fine particles of silica xerogel from the unwoven fabric fiber.
Abstract:
A manufacturing method of a heat insulating sheet of the present disclosure includes a composite generating step of impregnating a nonwoven fiber with a basic sol prepared to generate a composite of a hydrogel-nonwoven fiber, the basic sol being prepared by adding carbonate ester to a water glass composition; and a drying step of drying a liquid contained in the composite at a temperature lower than a critical temperature of the liquid and a pressure lower than a critical pressure of the liquid to remove the liquid from the composite. A heat insulating sheet according to the present disclosure includes an aerogel and a nonwoven fiber, and has a compression rate at 0.30 MPa to 5.0 MPa of 40% or less. In an electronic device of the present disclosure, the heat insulating sheet is disposed between an electronic component and a housing. In a battery unit of the present disclosure, the heat insulating sheet is disposed between batteries. This provides a heat insulating sheet that can be used under a high load and a manufacturing method thereof, and an electronic device and a battery unit including the same.
Abstract:
In a method for manufacturing an aerogel, an acid is added to a first aqueous high-molar-ratio silicate solution that includes silica particles having a mean particle diameter of from 1 nm to 10 nm and that is alkaline, to produce a gel. The gel is subjected to a dehydration condensation to obtain a hydrogel. The hydrogel is converted into a hydrophobized gel. Then, the hydrophobized gel is dried. According to the method, an aerogel having a pore volume of from 3.00 cc/g to 10 cc/g, a mean pore diameter of from 10 nm to 68 nm, and a specific surface area of from 200 m2/g to 475 m2/g can be prepared.
Abstract:
A hydrophobic treatment method is used in which at least one sheet filled with a gelled silicic acid is tilted at least two degrees with respect to a horizontal direction in a hydrophobizing solution, and the gelled silicic acid is hydrophobized. A manufacturing method for a sheet-like member is also used. The manufacturing method includes: a sol preparing step of adjusting the pH of a water glass aqueous solution to obtain a sol solution of silicic acid; an adding step of adding the sol solution to a fiber; a gel step of polymerizing and gelling the sol solution; a hydrophobic treatment step of hydrophobizing the gel with the hydrophobic treatment method; and a drying step of drying the hydrophobized gel.
Abstract:
Disclosed is an aerogel, having, on the surface of the aerogel, at least one type of dialkyldisiloxane bond serving as a hydrophobic group, and/or at least one type of crosslinked disiloxane bond serving as a hydrophobic group. Further disclosed is a material serving as at least one material selected from among a heat-insulation material, a sound-absorbing material, a water-repellant material, and an adsorption material, and this material includes the above-mentioned aerogel. Yet further disclosed is a method for producing the above-mentioned aerogel.
Abstract:
A composite sheet includes a graphite layer, a heat insulation layer including a fiber and a heat insulation material and a fiber layer located between the graphite layer and the heat insulation layer, wherein the fiber layer comprises the fiber. An electronic apparatus includes an electronic component that involves heat generation, a housing and the composite sheet, wherein the composite sheet is placed between the electronic component and the housing.