公开(公告)号：US20080233279A1

公开(公告)日：2008-09-25

申请号：US11725703

申请日：2007-03-19

Applicant: Rebecca L. Smith ,  Richard Allen Hayes

Inventor： Rebecca L. Smith ,  Richard Allen Hayes

IPC: B41M5/00

CPC classification number: B41M7/0027 ,  B32B17/10 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10247 ,  B32B17/10761 ,  B32B17/10853 ,  B32B27/08 ,  B32B27/30 ,  B32B27/36 ,  B32B2367/00 ,  B41M1/34 ,  B41M3/00 ,  B41M5/0041 ,  B41M7/0072

Abstract: An image-bearing article comprises an opaque layer bearing an image which is coated on the image-bearing side and over the image with an adhesion promoter. A process of preparing an image-bearing article comprising a coated image-bearing white layer comprises the steps of providing an opaque layer; printing an image on the opaque layer so as to produce an image-bearing opaque layer containing an image-bearing side; and coating an adhesion promoter on the image-bearing side and over the image to produce a coated image-bearing opaque layer containing a coated image-bearing side.

Abstract translation: 图像承载制品包括不透明层，其具有涂覆在图像承载侧上的图像，并且具有粘合促进剂。 制备包含涂覆图像的白色层的图像承载制品的方法包括提供不透明层的步骤; 在不透明层上印刷图像以产生包含图像承载侧的图像承载不透明层; 并且在图像承载侧和图像上涂覆粘合促进剂以产生包含涂覆图像承载侧的涂布图像承载不透明层。

公开(公告)号：US20080206504A1

公开(公告)日：2008-08-28

申请号：US11712295

申请日：2007-02-28

Applicant: Richard Allen Hayes ,  Rebecca L. Smith

Inventor： Richard Allen Hayes ,  Rebecca L. Smith

IPC: B29C65/20 ,  B05D5/10

CPC classification number: B32B17/10036 ,  B32B17/10 ,  B32B17/10247 ,  B32B17/10266 ,  B32B17/10761 ,  B32B17/10788 ,  B32B2367/00

Abstract: An image-bearing article comprising a rigid sheet bearing an image which is coated on the image-bearing side and over the image with an adhesion promoter.A process of preparing an image-bearing article comprising a coated image-bearing rigid sheet: (a) providing a rigid sheet; (b) printing an image on the rigid sheet so as to produce an image-bearing rigid sheet containing an image-bearing side; and (c) coating an adhesion promoter on the image-bearing side and over the image to produce a coated image-bearing rigid sheet containing a coated image-bearing side.

Abstract translation: 一种图像承载制品，其包含刚性片材，该刚性片材具有涂覆在图像承载侧上并且具有粘合促进剂的图像上的图像。 一种制备包含涂覆图像的刚性片的图像承载制品的方法：（a）提供刚性片; （b）在刚性片材上印刷图像以产生包含图像承载侧的图像承载刚性片材; 和（c）在图像承载侧和图像上涂覆粘合促进剂以产生包含涂覆图像承载侧的涂布图像承载刚性片。

公开(公告)号：US20080199690A1

公开(公告)日：2008-08-21

申请号：US12012843

申请日：2008-02-06

Applicant: Richard Allen Hayes ,  Sam Louis Samuels ,  Matthew Scott Hall

Inventor： Richard Allen Hayes ,  Sam Louis Samuels ,  Matthew Scott Hall

IPC: B32B27/00 ,  C08F18/00

CPC classification number: H01L31/18 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10697 ,  B32B17/10743 ,  B32B17/10853 ,  B32B27/308 ,  B32B2367/00 ,  C09D123/0876 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T156/10 ,  Y10T428/24975 ,  Y10T428/269 ,  Y10T428/31507 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31645 ,  Y10T428/31855

Abstract: A polymeric film or sheet comprising an ionomeric composition comprising ionomeric copolymer of an alpha olefin and about 1 to about 30 wt % of alpha,beta-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the ionomeric copolymer, wherein the carboxylic acid is neutralized to a level of 1 to 100 mol %, with one or more metal ions, based on the total number of moles of carboxylate groups in the ionomeric copolymer, and wherein the ionomeric copolymer has a Melt Index of about 20 to about 300 g/10 min. The ionomeric composition preferably comprises an additive selected from the group consisting of silane coupling agent, organic peroxide, and combinations thereof. In addition, an article comprising an interlayer formed of the polymeric film or sheet and an additional layer selected from the group consisting of glass, other polymeric interlayer sheets, polymeric film layers, and metal films or sheets. Examples of articles include safety windows and solar cells.

Abstract translation: 一种聚合物膜或片，其包含基于所述离聚物共聚物的总重量的包含α-烯烃和约1至约30重量％的具有3至8个碳的α，β-烯键式不饱和羧酸的离聚物共聚物的离聚物组合物， 基于离聚物共聚物中的羧酸酯基团的总摩尔数，羧酸被中和至1至100摩尔％的水平，其中一种或多种金属离子，其中离聚物共聚物的熔体指数为约20至 约300g / 10min。 离聚物组合物优选包含选自硅烷偶联剂，有机过氧化物及其组合的添加剂。 此外，包括由聚合物膜或片材形成的中间层和选自玻璃，其它聚合物中间层片，聚合物膜层和金属膜或片材的附加层的制品。 文章的例子包括安全窗和太阳能电池。

公开(公告)号：US07193029B2

公开(公告)日：2007-03-20

申请号：US10888046

申请日：2004-07-09

Applicant: Richard Allen Hayes

Inventor： Richard Allen Hayes

IPC: C08G63/02 ,  C08G63/688 ,  C08G63/18 ,  C08G63/66 ,  C08F20/00 ,  C08K3/00 ,  B65B53/00 ,  B29D29/00 ,  B32B1/08 ,  B32B27/00

CPC classification number: C08L67/025 ,  B32B27/36 ,  C08G63/60 ,  C08G63/688 ,  C08K3/013 ,  C08L3/02 ,  C08L67/00 ,  C08L2201/06 ,  C09D167/025 ,  D01F6/86 ,  Y10T428/1328 ,  Y10T428/1372 ,  Y10T428/1376 ,  Y10T428/249921 ,  Y10T428/2913 ,  Y10T428/31786 ,  Y10T428/31794 ,  C08L2666/26 ,  C08L2666/20 ,  C08L2666/02 ,  C08L2666/18

Abstract: The present invention provides certain sulfonated copolyetherester compositions containing hydroxyalkanoic acids and processes for producing such sulfonated aromatic copolyetheresters. The invention further provides shaped articles, preferably in the shape of films, coatings and laminates, having improved thermal properties, wherein the shaped articles are produced from the certain sulfonated copolyetherester compositions. Some of these materials are also biocompostable. The sulfonated copolyetheresters are produced from a mixture of an aromatic dicarboxylic acid component, hydroxyalkanoic acid component, a sulfonate component, a poly(alkylene ether) glycol component, a glycol component, an optional other glycol component, an optional branching agent, and an optional color reducing agent.

Abstract translation: 本发明提供了含有羟基链烷酸的某些磺化共聚醚酯组合物和制备这种磺化芳族共聚醚酯的方法。 本发明进一步提供成形制品，优选具有改进的热性能的薄膜，涂层和层压材料的形状，其中成型制品由某些磺化共聚醚酯组合物制成。 这些材料中的一些也是可生物相容的。 磺化共聚醚酯由芳族二羧酸组分，羟基链烷酸组分，磺酸盐组分，聚（亚烷基醚）二醇组分，二醇组分，任选的其它二醇组分，任选的支化剂和任选的 减色剂

公开(公告)号：US06787245B1

公开(公告)日：2004-09-07

申请号：US10459189

申请日：2003-06-11

Applicant: Richard Allen Hayes

Inventor： Richard Allen Hayes

IPC: B32B2736

CPC classification number: D01F8/14 ,  B32B27/36 ,  C08G63/6886 ,  C08K3/013 ,  C08K13/04 ,  C08L67/02 ,  D01F6/84 ,  D21H19/28 ,  D21H19/62 ,  D21H27/10 ,  Y10T428/249921 ,  Y10T428/2949 ,  Y10T428/31786 ,  C08L2666/02

Abstract: Sulfonated aliphatic-aromatic copolyesters are provided. The copolyesters are produced from a mixture of aromatic dicarboxylic acids, aliphatic dicarboxylic acids, ethylene glycol, other glycols, and components containing alkali metal or alkaline earth metal sulfo groups, such as a metal 5-sulfoisophthalic acid derivative. The copolyesters have lower sulfonation than known sulfonated polyesters, and provide advantageous thermal properties for some end uses. The sulfonated aliphatic-aromatic copolyesters are useful in forming coatings or films on various substrates, and in packaging. Some compositions comprising the sulfonated aliphatic-aromatic copolyesters are biodegradable, as are some of the sulfonated aromatic-aromatic copolyesters.

Abstract translation: 提供磺化的脂族 - 芳族共聚酯。 共聚酯由芳族二羧酸，脂肪族二羧酸，乙二醇，其它二元醇和含有碱金属或碱土金属磺基的成分如金属5-磺基间苯二甲酸衍生物的混合物制成。 共聚酯具有比已知磺化聚酯低的磺化，并为一些最终用途提供有利的热性能。 磺化的脂族 - 芳族共聚酯可用于在各种基材和包装中形成涂层或膜。 包含磺化脂族 - 芳族共聚酯的一些组合物是可生物降解的，一些磺化芳族 - 芳族共聚酯也是可生物降解的。

公开(公告)号：US06610795B2

公开(公告)日：2003-08-26

申请号：US09927653

申请日：2001-08-10

Applicant: Richard Allen Hayes

Inventor： Richard Allen Hayes

IPC: C08F2000

CPC classification number: C08G63/672 ,  C08G63/80

Abstract: A process for producing a polyester that comprises 1 to 90 wt. % poly(alkylene ether) glycol. The process comprises the step of copolymerizing (i) a preformed polyester polymer having an inherent viscosity of at least 0.4 dL/g, (ii) a poly(alkylene ether) glycol, and (iii) a dicarboxylic acid or anhydride, to obtain a polyester comprising 1 to 90 wt. % poly(alkylene ether glycol).

公开(公告)号：US09085123B2

公开(公告)日：2015-07-21

申请号：US13407858

申请日：2012-02-29

Applicant: Elliott Echt ,  Richard Allen Hayes

Inventor： Elliott Echt ,  Richard Allen Hayes

IPC: B05D3/02 ,  B32B27/10

CPC classification number: C09D129/04 ,  B32B27/10 ,  Y02P20/582 ,  Y10T428/249921 ,  Y10T428/249992 ,  Y10T428/31688 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/31895 ,  C08L29/04 ,  C08L23/0876

Abstract: Disclosed are methods to form coatings on a substrate, the coatings comprising a blend of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by (i) a hydrolysis level of from about 85 to about 93 mol % and a 4 weight % aqueous viscosity of 15 centipoise (cp) or less; or (ii) a hydrolysis level of about 95 mol % to 100%; and an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium cations, sodium cations or combinations thereof. Multilayer structures comprising the blend composition on a substrate are also disclosed.

Abstract translation: 公开了在基材上形成涂层的方法，该涂层包含聚（乙烯醇）组合物的混合物，其包含聚（乙烯醇），其特征在于（i）水解度为约85-约93摩尔％，和4 重量％水溶液粘度为15厘泊（cp）或更低; 或（ii）约95mol％至100％的水解度; 和包含乙烯和约18至约30重量％的丙烯酸或甲基丙烯酸的母体酸共聚物的离聚物，所述酸共聚物的熔体流动速率为约200至约1000g / 10min，其中约50％ 约70％的共聚物的羧酸基团被中和到包含钾阳离子，钠阳离子或其组合的羧酸盐中。 还公开了在衬底上包含共混组合物的多层结构。

公开(公告)号：US08772624B2

公开(公告)日：2014-07-08

申请号：US11495249

申请日：2006-07-28

Applicant: Richard Allen Hayes ,  Geraldine M. Lenges ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

Inventor： Richard Allen Hayes ,  Geraldine M. Lenges ,  Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith

IPC: H01L31/0203

CPC classification number: B32B17/10788 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  B32B2327/12 ,  H01L31/0488 ,  Y02E10/50

Abstract: The present invention provides a solar cell module comprising at least one encapsulant layer which has 1) a total thickness of from about 0.1 to about 20 mils and 2) at least one surface layer made of ionomers containing a finite amount of polymerized residues of α-olefins and from about 18 to about 25 wt % of polymerized residues of α,β-ethylenically unsaturated carboxylic acids. The present invention also provides a process of manufacturing the solar cell module.

Abstract translation: 本发明提供了一种太阳能电池模块，其包括至少一个密封层，其具有1）总厚度为约0.1至约20密耳，以及2）至少一个由离聚物制成的表面层，该表面层含有有限量的α- 烯烃和约18至约25重量％的α，β-烯键式不饱和羧酸的聚合残余物。 本发明还提供一种制造太阳能电池模块的方法。

公开(公告)号：US08691372B2

公开(公告)日：2014-04-08

申请号：US12012843

申请日：2008-02-06

Applicant: Richard Allen Hayes ,  Sam Louis Samuels ,  Matthew Scott Hall

Inventor： Richard Allen Hayes ,  Sam Louis Samuels ,  Matthew Scott Hall

IPC: B32B27/00 ,  C08F18/00

CPC classification number: H01L31/18 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10697 ,  B32B17/10743 ,  B32B17/10853 ,  B32B27/308 ,  B32B2367/00 ,  C09D123/0876 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T156/10 ,  Y10T428/24975 ,  Y10T428/269 ,  Y10T428/31507 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31645 ,  Y10T428/31855

Abstract: A polymeric film or sheet comprising an ionomeric composition comprising ionomeric copolymer of an alpha olefin and about 1 to about 30 wt % of alpha,beta-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the ionomeric copolymer, wherein the carboxylic acid is neutralized to a level of 1 to 100 mol %, with one or more metal ions, based on the total number of moles of carboxylate groups in the ionomeric copolymer, and wherein the ionomeric copolymer has a Melt Index of about 20 to about 300 g/10 min. The ionomeric composition preferably comprises an additive selected from the group consisting of silane coupling agent, organic peroxide, and combinations thereof. In addition, an article comprising an interlayer formed of the polymeric film or sheet and an additional layer selected from the group consisting of glass, other polymeric interlayer sheets, polymeric film layers, and metal films or sheets. Examples of articles include safety windows and solar cells.

Abstract translation: 一种聚合物膜或片，其包含基于所述离聚物共聚物的总重量的包含α-烯烃和约1至约30重量％的具有3至8个碳的α，β-烯键式不饱和羧酸的离聚物共聚物的离聚物组合物， 基于离聚物共聚物中的羧酸酯基团的总摩尔数，羧酸被中和至1至100摩尔％的水平，其中一种或多种金属离子，其中离聚物共聚物的熔体指数为约20至 约300g / 10min。 离聚物组合物优选包含选自硅烷偶联剂，有机过氧化物及其组合的添加剂。 此外，包括由聚合物膜或片材形成的中间层和选自玻璃，其它聚合物中间层片，聚合物膜层和金属膜或片材的附加层的制品。 文章的例子包括安全窗和太阳能电池。

公开(公告)号：US20130225021A1

公开(公告)日：2013-08-29

申请号：US13407927

申请日：2012-02-29

Applicant: Elliott Echt ,  Richard Allen Hayes

Inventor： Elliott Echt ,  Richard Allen Hayes

IPC: B32B27/30 ,  B32B5/02 ,  B32B3/26 ,  B32B15/082 ,  B32B37/14 ,  B05D3/00 ,  B32B37/06 ,  B32B37/08 ,  B32B37/10 ,  C09D129/04 ,  B05D7/00

CPC classification number: C09D129/04 ,  B32B27/306 ,  B32B27/308 ,  B32B2270/00 ,  Y10T156/10 ,  Y10T428/249976 ,  Y10T428/249991 ,  Y10T428/31692 ,  Y10T428/31895 ,  Y10T442/20 ,  C08L23/0876

Abstract: Disclosed are methods to form coatings on a substrate, the coatings comprising a blend of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by a hydrolysis level of from about 85 to about 93 mole % and a 4 weight % aqueous viscosity at 20° C. of about 16 to about 75 centipoise; and an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium cations, sodium cations or combinations thereof. Multilayer structures comprising the blend composition on a substrate are also disclosed.

Abstract translation: 公开了在基材上形成涂层的方法，该涂层包括聚（乙烯醇）组合物的共混物，该组合物包含聚（乙烯醇），其特征在于水解度为约85-约93摩尔％，和4重量％ 在20℃下的粘度为约16至约75厘泊; 和包含乙烯和约18至约30重量％的丙烯酸或甲基丙烯酸的母体酸共聚物的离聚物，所述酸共聚物的熔体流动速率为约200至约1000g / 10min，其中约50％ 约70％的共聚物的羧酸基团被中和到包含钾阳离子，钠阳离子或其组合的羧酸盐中。 还公开了包含基底上的共混组合物的多层结构。