Packed column vaporizer and vaporizing process
    13.
    发明授权
    Packed column vaporizer and vaporizing process 失效
    填充柱蒸发器和蒸发过程

    公开(公告)号:US5470441A

    公开(公告)日:1995-11-28

    申请号:US207435

    申请日:1994-03-07

    申请人: Ronald E. Brown

    发明人: Ronald E. Brown

    IPC分类号: B01D3/00 B01D3/14 B01D47/16

    摘要: An apparatus for vaporizing volatile liquids comprises a packed column, a gas inlet port (for introducing a hot entrainer gas), a feed tube (for introducing a volatile liquid), a feed distributor comprising a base plate equipped with orifices (through which the liquid flows downward into the packed column) and risers (through which the formed gaseous mixture of entrainer gas and vaporized liquid flows upward), and a gas outlet port. This apparatus can be used to vaporize volatile liquids, preferably volatile tin compounds, optionally in admixture with volatile silicon compounds, wherein steam is used as the entrainer gas.

    摘要翻译: 用于蒸发挥发性液体的装置包括填充塔,用于引入热夹带气体的进气口,用于引入挥发性液体的进料管(feed tube)),包括配有孔的基板的进料分配器 向下流入填充塔)和立管(所形成的夹带气体和汽化液体的气体混合物向上流动)和气体出口。 该装置可用于蒸发挥发性液体,优选挥发性锡化合物,任选地与挥发性硅化合物混合,其中蒸汽用作夹带剂气体。

    Injection of antifoulants into thermal cracking reactors
    14.
    发明授权
    Injection of antifoulants into thermal cracking reactors 失效
    将防污剂注入热裂解反应器

    公开(公告)号:US5284994A

    公开(公告)日:1994-02-08

    申请号:US4391

    申请日:1993-01-13

    IPC分类号: C07C4/04 C10G9/16 C23F11/02

    CPC分类号: C10G9/16 C07C4/04 Y10S585/95

    摘要: A liquid tin-containing antifoulant composition is injected into a metal-walled thermal cracking reactor tube, concurrently with the injection of a gaseous stream (preferably a steam-diluted C.sub.2 -C.sub.4 alkane stream), through a nozzle of an injection quill which is positioned in the center region of the reactor tube substantially parallel to the flow of the gaseous stream.A liquid tin-containing antifoulant is injected into a metal-walled thermal cracking reactor tube through a nozzle of an injection quill at a temperature of about 1000.degree.-1300.degree. F. while a gaseous stream (preferably a steam-diluted C.sub.2 -C.sub.4 alkane stream) flows through the reactor tube, followed by raising the temperature to about 1400.degree.-1800.degree. F. Preferably, the metal walls of the reactor tube are treated with steam after the antifoulant injection at about 1000.degree.-1300.degree. F. but before the antifoulant injection at about 1400.degree.-1800.degree. F.

    摘要翻译: 将含液体锡的防污剂组合物注入到金属壁热裂解反应器管中,同时注入气流(优选蒸汽稀释的C2-C4烷烃流),该注射套管位于 在反应器管的中心区域基本上平行于气流的流动。 将含液体锡的防污剂通过注射针筒的喷嘴在约1000-130华氏度的温度下注入金属壁热裂解反应器管中,同时气流(优选蒸汽稀释的C2-C4烷烃 流)流过反应器管,随后将温度升高至约1400-180°F。优选地,反应器管的金属壁在约1000-130华氏度之后的防污注射之后用蒸汽处理。 约1400度-1800华氏度的防污剂注射

    Monoolefin/paraffin separation by selective absorption
    15.
    发明授权
    Monoolefin/paraffin separation by selective absorption 失效
    通过选择性吸收单烯烃/石蜡分离

    公开(公告)号:US5202521A

    公开(公告)日:1993-04-13

    申请号:US893630

    申请日:1992-06-05

    IPC分类号: C07C7/156 C10G70/00

    CPC分类号: C10G70/004 C07C7/156

    摘要: A selective absorption process for separating C.sub.2 -C.sub.4 alkenes (in particular ethylene) from C.sub.1 -C.sub.5 alkanes with a liquid extractant comprising dissolved copper(I) compound(s), in particular dissolved Cu(I) hydrocarbonsulfonate(s), is carried out in a one-column operation, wherein an overhead product is withdrawn which contains alkene(s) at a lower concentration than the feed, a side product is withdrawn which contains alkene(s) at a higher concentration than the feed, and a bottoms stream is withdrawn which contains primarily the liquid extractant.

    摘要翻译: 使用包含溶解的铜(I)化合物,特别是溶解的Cu(I)烃磺酸盐的液体萃取剂从C 1 -C 5烷烃分离C 2 -C 4烯烃(特别是乙烯)的选择性吸收方法进行 在一列操作中,其中取出含有比进料低的浓度的烯烃的塔顶产物,取出含有比进料浓度更高的烯烃的副产物,以及底部料流 被取出,主要含有液体萃取剂。

    Separation of ethylbenzene from xylenes by extractive distillation
    17.
    发明授权
    Separation of ethylbenzene from xylenes by extractive distillation 失效
    通过萃取蒸馏从二甲苯中分离乙苯

    公开(公告)号:US5135620A

    公开(公告)日:1992-08-04

    申请号:US754867

    申请日:1991-09-04

    申请人: Ronald E. Brown

    发明人: Ronald E. Brown

    IPC分类号: C07C7/08

    CPC分类号: C07C7/08

    摘要: Ethylbenzene is separated from xylene(s) by extractive distillation employing at least one copper(I) salt of a hydrocarbonsulfonic acid as extractant(s).

    摘要翻译: 使用至少一种作为萃取剂的烃磺酸的铜(I)盐,通过萃取蒸馏将乙苯与二甲苯分离。

    Polymerization of olefinic hydrocarbons and complex-initiator therefor
    18.
    发明授权
    Polymerization of olefinic hydrocarbons and complex-initiator therefor 失效
    烯烃的聚合和其引发剂

    公开(公告)号:US4713424A

    公开(公告)日:1987-12-15

    申请号:US668070

    申请日:1984-11-05

    申请人: Ronald E. Brown

    发明人: Ronald E. Brown

    IPC分类号: C07C2/88 C08F36/04 C07C2/00

    CPC分类号: C07C2/88 C08F36/04 Y02P20/582

    摘要: A continuous, liquid phase method for producing a polymer having a predetermined number of conjugated diene units per molecule in which (a) a first monomer stream is contacted with an organo-lithium compound, in a manner to intimately mix increments of monomer, containing the predetermined number of moles of conjugated diene, with each mole of organo-lithium and continuously mix and move the mixture through a first, elongated reaction zone to react the predetermined number of moles of conjugated diene with one mole of organo-lithium, (b) mixing the effluent from (a) with an alkyl-substituted aromatic hydrocarbon, an organo-alkali metal of potassium, rubidium or cesium and a tertiary amine to form a complex-initiator of the aromatic hydrocarbon, the alkali metal and the amine, (c) mixing the effluent from (b) with a second stream of monomer, in a manner to intimately mix increments of monomer, containing the predetermined number of moles of conjugated diene, with each mole of complex-initiator and continuously mix and move the mixture through a second, elongated reaction zone and (d) mixing the effluent of (c) to produce to form a polymer comprising the predetermined number of conjugated diene units and the aromatic hydrocarbon. Preferably, a portion of the effluent from (d), containing complex-initiator, is cooled and recycled to (c) to cool the reaction and supply complex-initiator.

    摘要翻译: 一种用于制备每分子具有预定数目的共轭二烯单元的聚合物的连续液相方法,其中(a)使第一单体流与有机锂化合物接触,以便使包含 共轭二烯的预定摩尔数,每摩尔有机锂,并连续混合并移动混合物通过第一细长的反应区,使预定数量的共轭二烯与1摩尔的有机锂反应,(b) 将来自(a)的流出物与烷基取代的芳烃,钾,铷或铯的有机碱金属和叔胺混合以形成芳族烃,碱金属和胺的复合引发剂(c )将来自(b)的流出物与第二个单体流混合,以将含有预定数量的共轭二烯的单体的增量与每摩尔的络合物密切混合 并且将混合物连续地混合并移动通过第二细长反应区,和(d)混合(c)的流出物以产生包含预定数量的共轭二烯单元和芳族烃的聚合物。 优选地,将含有络合物 - 引发剂的来自(d)的一部分流出物冷却并循环至(c)以冷却反应并供应复合物引发剂。