摘要:
A treatment fluid for a well includes: (a) a water-soluble polymer, wherein the water-soluble polymer comprises a polymer of at least one non-acidic ethylenically unsaturated polar monomer; (b) an organic crosslinker comprising amine groups, wherein the organic crosslinker is capable of crosslinking the water-soluble polymer; (c) a weak organic acid; and (d) water; wherein the treatment fluid is a crosslinkable polymer composition.
摘要:
Cement compositions comprising carboxylated inulin and methods of using the same to cement a workspace. In one embodiment, a method of cementing includes providing a cement composition comprising a carboxylated inulin, for example, in a subterranean formation. The method further includes allowing the cement composition to set. In some embodiments, the cement composition has a thickening time of from about 2 hours to about 11 hours. In other embodiments, the cement composition has a viscosity that is about constant for a period of time after the cement composition is placed.
摘要:
Methods comprising providing a relative permeability modifier that comprises a hydrophilic polymer backbone with a hydrophobic modification and incorporating at least one cationic compound onto the hydrophilic polymer backbone. The hydrophilic polymer is one or more of: a polyacrylamide; a polyvinylamine; a poly(vinylamine/vinyl alcohol); an alkyl acrylate polymer; cellulose; chitosan; a polyamide; a polyetheramine; a polyhydroxyetheramine; a polylysine; a polysulfone; a gum; or a starch. The hydrophobic modification is achieved either by reacting the hydrophilic polymer with a hydrophobic compound or by a polymerization reaction product of a hydrophilic monomer and a hydrophobically modified hydrophilic monomer. The hydrophobic compound has an alkyl chain length from 4 to 22 carbons and is one or more of: an alkyl acrylate; an alkyl methacrylate; an alkyl acrylamide; an alkyl methacrylamide; or an alkyl dimethylammoniumethyl methacrylate halide.
摘要:
Methods and compositions that comprise sub-micron alumina for accelerating setting of a cement composition. An embodiment includes a method of cementing in a subterranean formation. The method may comprise introducing a cement composition into the subterranean formation, wherein the cement composition comprises hydraulic cement, sub-micron alumina, and water. The method further may comprise allowing the cement composition to set in the subterranean formation. Another embodiment includes a cement composition that may comprise hydraulic cement, sub-micron alumina, and water.
摘要:
An embodiment of the present invention includes a method comprising introducing a cyclodextrin modifier into a well bore penetrating a subterranean formation. Another embodiment of the present invention includes a method of reducing viscosity of a treatment fluid comprising contacting a treatment fluid comprising a base fluid and a viscosifying agent with at least a cyclodextrin modifier wherein the cyclodextrin modifier interacts with the viscosifying agent to reduce viscosity of the treatment fluid. Another embodiment of the present invention includes a method of increasing viscosity of an aqueous fluid comprising contacting at least a hydrophobically modified polymer and a cyclodextrin modifier in the presence of at least the aqueous fluid, wherein the cyclodextrin modifier interacts with the hydrophobically modified polymer to viscosify the aqueous fluid. Another embodiment of the present invention includes a subterranean treatment fluid comprising a base fluid and a cyclodextrin modifier.
摘要:
A method having the following steps: running a circulation valve comprising a reactive material into the well bore on the casing; reverse-circulating an activator material in the well bore until the activator material contacts the reactive material of the circulation valve; reconfiguring the circulation valve by contact of the activator material with the reactive material; and reverse-circulating a cement composition in the well bore until the reconfigured circulation valve decreases flow of the cement composition. A circulation valve for cementing casing in a well bore, the valve having: a valve housing connected to the casing and comprising a reactive material; a plurality of holes in the housing, wherein the plurality of holes allow fluid communication between an inner diameter of the housing and an exterior of the housing, wherein the reactive material is expandable to close the plurality of holes.
摘要:
A method of servicing a wellbore in contact with a subterranean formation comprising placing a wellbore servicing fluid comprising a polyuronide polymer within the wellbore, contacting the wellbore servicing fluid with a divalent ion source, and allowing the wellbore servicing fluid to form a gel within the wellbore wherein the divalent ion source is located within the wellbore. A method of servicing a wellbore in contact with a subterranean formation comprising (a) placing a wellbore servicing fluid comprising a polyuronide polymer into the wellbore wherein the wellbore servicing fluid contacts a calcium ion source, (b) shutting the wellbore and allowing the servicing fluid to set into place for a period of time, and (c) repeating steps (a) and (b) until the permeability of a structure within the wellbore is reduced by about 50%.
摘要:
The present invention relates to well bore stabilization and, more particularly, to treatment fluids that may reduce the tendency of shales to swell and associated methods. In some embodiments, the present invention provides a method of stabilizing a subterranean formation that comprises a shale, the method comprising contacting the subterranean formation that comprises the shale with a treatment fluid, the treatment fluid comprising a base fluid, and a hydrophobically modified polymer. In other embodiments, the treatment fluids comprise a base fluid and a hydrophilically modified polymer. In yet other embodiments, the present invention provides shale-inhibiting components, treatment fluids, and methods of reducing the tendency of shale to swell when exposed to a treatment fluid.
摘要:
A method having the following steps: running a circulation valve comprising a reactive material into the well bore on the casing; reverse-circulating an activator material in the well bore until the activator material contacts the reactive material of the circulation valve; reconfiguring the circulation valve by contact of the activator material with the reactive material; and reverse-circulating a cement composition in the well bore until the reconfigured circulation valve decreases flow of the cement composition. A circulation valve for cementing casing in a well bore, the valve having: a valve housing connected to the casing and comprising a reactive material; a plurality of holes in the housing, wherein the plurality of holes allow fluid communication between an inner diameter of the housing and an exterior of the housing, wherein the reactive material is expandable to close the plurality of holes.
摘要:
The present invention relates to subterranean treatment fluids, and more particularly, the present invention relates to subterranean treatment fluids comprising relative permeability modifiers and methods for using such subterranean treatment fluids in subterranean operations to reduce the production of water from and stimulate hydrocarbon production in a subterranean formation. In certain embodiments, the methods of the present invention generally comprise the steps of providing a permeability-modifying aqueous treatment fluid comprising a relative permeability modifier and contacting a subterranean formation with the permeability-modifying aqueous treatment fluid. Optionally, the permeability-modifying aqueous treatment fluid may be injected in the subterranean formation at a pressure sufficient to create or enhance at least one fracture therein. In another embodiment, the relative permeability modifier may be provided by appropriate reaction in situ.