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公开(公告)号：US08709376B2
公开(公告)日：2014-04-29
申请号：US12889045
申请日：2010-09-23
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
IPC分类号： C01B17/90 , C07C309/30 , C07C59/06 , C07C51/42
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。
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公开(公告)号：US08785686B2
公开(公告)日：2014-07-22
申请号：US13431335
申请日：2012-03-27
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/40 , B01J2231/321 , C07C51/12 , C07C51/48 , Y02P20/584 , C07C59/06
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde. Also disclosed is a process for the preparation of glycolic acid by the acid-catalyzed hydrocarboxylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。 还公开了通过酸催化的甲醛加氢制备乙醇酸的方法。
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公开(公告)号：US20120215027A1
公开(公告)日：2012-08-23
申请号：US13431335
申请日：2012-03-27
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie , Andrew James Vetter
IPC分类号： C07C51/12
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/40 , B01J2231/321 , C07C51/12 , C07C51/48 , Y02P20/584 , C07C59/06
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde. Also disclosed is a process for the preparation of glycolic acid by the acid-catalyzed hydrocarboxylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。 还公开了通过酸催化的甲醛加氢制备乙醇酸的方法。
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公开(公告)号：US20120078010A1
公开(公告)日：2012-03-29
申请号：US12889045
申请日：2010-09-23
申请人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
发明人： Scott Donald Barnicki , Stephen Neal Falling , Jeffrey Scott Kanel , Robert Sterling Kline , Peter Borden Mackenzie
IPC分类号： C07C51/10
CPC分类号： B01D11/0492 , B01J31/0225 , B01J31/0227 , B01J31/4092 , C07C51/48 , C07C303/44 , C07C315/06 , Y02P20/584 , C07C59/06 , C07C309/06 , C07C309/05 , C07C317/04
摘要： Disclosed is a process for the extractive recovery of an acid catalyst from an aqueous mixture of glycolic acid with an extraction solvent comprising a tertiary amine or an onium carboxylate compound, a modifier, and a diluent. The acid catalyst, which can comprise strong acids such as sulfuric acid, alkyl sulfonic acids, and fluoroalkyl sulfonic acids, can be recovered by back extraction with aqueous formaldehyde and recycled to a process for the preparation of glycolic acid by the acid-catalyzed carbonylation of formaldehyde.
摘要翻译： 公开了一种从乙醇酸的水性混合物与包含叔胺或羧酸铝化合物，改性剂和稀释剂的萃取溶剂萃取回收酸催化剂的方法。 可以包含强酸如硫酸，烷基磺酸和氟代烷基磺酸的酸催化剂可以通过用甲醛水溶液反萃取回收，并循环至通过酸催化的羰基化反应制备乙醇酸的方法 甲醛。
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公开(公告)号：US06444096B1
公开(公告)日：2002-09-03
申请号：US09639540
申请日：2000-08-16
申请人： Scott Donald Barnicki , Timothy Richard Nolen , Robert Sterling Kline , Dewey Wayne Fuller, Jr. , Mary Kathleen Foster , Stephen Neal Falling
发明人： Scott Donald Barnicki , Timothy Richard Nolen , Robert Sterling Kline , Dewey Wayne Fuller, Jr. , Mary Kathleen Foster , Stephen Neal Falling
IPC分类号： B01D334
摘要： A process for the recovery and purification of cyclobutanone from a crude product mixture obtained from an oxidation product mixture resulting from the oxidation of cyclobutanol to cyclobutanone in the presence of water. The process provides for the recovery of cyclobutanone in a purity of at least 90 weight percent by a combination of distillation steps.
摘要翻译： 从在水存在下由环丁醇氧化成环丁酮得到的氧化产物混合物得到的粗产物混合物回收和纯化环丁酮的方法。 该方法通过蒸馏步骤的组合提供纯度至少为90重量％的环丁酮。
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16.发明申请公开(公告)号：US20130310608A1
公开(公告)日：2013-11-21
申请号：US13474837
申请日：2012-05-18
摘要： Disclosed is a process for reducing the emission of volatile organic compounds that are produced during the ketonization of carboxylic acids to ketones. The ketonization of carboxylic acids produces a gaseous by-product stream containing carbon dioxide and volatile organic compounds. This gaseous by-product stream can be fed to a direct-fired furnace used to heat the ketonization reaction feed streams where the volatile organic compounds are destroyed by combustion in the furnace. The carbon dioxide stream further acts as a diluent for the fuel to the furnace.
摘要翻译： 公开了一种减少在将羧酸酮化成酮时产生的挥发性有机化合物的排放的方法。 羧酸的酮化产生含有二氧化碳和挥发性有机化合物的气态副产物流。 这种气态副产物流可以进料到用于加热酮化反应进料流的直接燃烧炉，其中挥发性有机化合物通过在炉中燃烧而被破坏。 二氧化碳流还充当用于燃料的炉的稀释剂。
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公开(公告)号：US20120184783A1
公开(公告)日：2012-07-19
申请号：US13431308
申请日：2012-03-27
IPC分类号： C07C29/86
CPC分类号： C07C29/86 , B01J31/2409 , B01J2531/0258 , B01J2531/821 , C07C29/149 , C07C29/80 , Y02P20/52 , C07C31/202 , C07C31/205 , C07C31/207
摘要： Disclosed is a process for the purification of a mixed diol stream. The mixed diol stream comprising two-, three-, and four-carbon diols is separated into component diols by extraction with a hydrophobic solvent mixture. The diols recovered in the extractant may be removed from the extractant stream by back extraction with water or by distillation with an azeotrope-forming agent present, preferably an azeotroping agent already present in the extractant mixture.
摘要翻译： 公开了一种纯化混合二醇流的方法。 包含二，三和四碳二醇的混合二醇料流通过用疏水溶剂混合物萃取分离成组分二醇。 在萃取剂中回收的二醇可以通过用水反萃取或用存在的共沸物形成剂，优选已经存在于萃取剂混合物中的共沸剂进行蒸馏，从萃取剂流中除去。
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公开(公告)号：US20120046500A1
公开(公告)日：2012-02-23
申请号：US12889065
申请日：2010-09-23
IPC分类号： C07C29/147
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
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公开(公告)号：US20120046481A1
公开(公告)日：2012-02-23
申请号：US13208399
申请日：2011-08-12
申请人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, JR. , Eduardo Gallas Cervo
发明人： Scott Donald Barnicki , Jeffrey Scott Kanel , Kenneth Wayne Hampton, JR. , Eduardo Gallas Cervo
IPC分类号： C07F19/00
CPC分类号： B01J31/24 , B01J31/2409 , B01J31/4053 , B01J2531/0238 , B01J2531/821 , C07C29/149 , C07C29/86 , Y02P20/52 , Y02P20/582 , Y02P20/584 , C07C31/202
摘要： Disclosed is a process for the extractive recovery of a homogeneous ruthenium catalyst from the reaction product of the hydrogenation of glycolic acid, glycolate esters, and/or glycolic acid oligomers with an extractant comprising a hydrophobic solvent and an optional hydrophilic solvent. The ruthenium catalyst, which can include 1,1,1-tris(diaryl- or dialkylphosphinomethyl)alkane ligands, can be recovered from the hydrophobic extract phase by back extraction with a hydrophilic solvent and recycled to a process for the preparation of ethylene glycol by the hydrogenation of glycolic acid and glycolic acid derivatives.
摘要翻译： 公开了从乙醇酸，乙醇酸酯和/或乙醇酸低聚物的氢化与包含疏水性溶剂和任选的亲水性溶剂的萃取剂的反应产物中提取回收均相钌催化剂的方法。 可以通过用亲水溶剂反萃取从疏水萃取相中回收可以包括1,1,1-三（二芳基 - 或二烷基膦基甲基）烷烃配体的钌催化剂，并循环到制备乙二醇的方法中 乙醇酸和乙醇酸衍生物的氢化。
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公开(公告)号：US07736403B2
公开(公告)日：2010-06-15
申请号：US12360125
申请日：2009-01-27
IPC分类号： C01B3/36 , C10J3/46 , C10J3/54 , B01J7/00 , H01M8/06 , F02B43/00 , F02G3/00 , F02C6/18 , B01D47/06
CPC分类号： C10J3/00 , C01B3/34 , C01B2203/0233 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/068 , C01B2203/0877 , C01B2203/0883 , C01B2203/84 , C10J3/723 , C10J2300/093 , C10J2300/0959 , C10J2300/0969 , C10J2300/0973 , C10J2300/1618 , C10J2300/165 , C10J2300/1659 , C10J2300/1665 , C10J2300/1668 , C10J2300/1671 , C10K1/002 , C10K1/004 , C10K1/005 , C10K1/007 , C10K1/04 , C10K1/101 , C10K1/12 , C10K1/122 , C10K1/143 , C10K1/16 , C10K1/20 , C10K1/32 , C10K3/04 , C10K3/06 , Y02E20/14 , Y02E20/16 , Y02E20/18 , Y02E50/11 , Y02E50/32 , Y02P20/129
摘要： Disclosed is a process for humidifying syngas to achieve a water to carbon monoxide molar ratio in the product syngas within a desired range and in which the molar ratio which can be varied over time in response to changes in downstream syngas requirements. The raw syngas is produced by reacting a carbonaceous material with oxygen, water, or carbon dioxide and can be combined with a diluent to produce a diluted syngas stream which can be cooled and contacted with liquid water to give a humidified syngas. The H2O:CO molar ratio of the humidified syngas may be adjusted in response to time-varying downstream syngas requirements by changing the amount and/or temperature of the diluent that is combined with the raw syngas stream, by adjusting quench and heat exchange conditions, or a combination thereof. The application of the process to the coproduction of chemicals and power are also disclosed.
摘要翻译： 公开了一种用于加湿合成气以在产物合成气中达到所需范围内的水与一氧化碳摩尔比的方法，其中响应于下游合成气需求的变化可随时间变化的摩尔比。 原料合成气通过使碳质材料与氧气，水或二氧化碳反应而生成，并且可与稀释剂组合以产生稀释的合成气流，其可冷却并与液态水接触以产生加湿的合成气。 通过改变与原料合成气流合并的稀释剂的量和/或温度，可以通过调节骤冷和热交换条件来调节加湿合成气的H 2 O:CO摩尔比，以响应随时间变化的下游合成气需求， 或其组合。 还公开了该方法在化学品和电力的共同生产中的应用。
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