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公开(公告)号：US20160264879A1
公开(公告)日：2016-09-15
申请号：US15033927
申请日：2014-11-04
Applicant: SHELL OIL COMPANY
Inventor： Ferry WINTER , Jan Arend VAN WELSENES , Marcello Stefano RIGUTTO , Patricia Johanna Anne Maria GILTAY , Johannes Jacobus Maria VAN VLAANDEREN , Ali AZGHAY
CPC classification number: B01J27/19 , B01J21/04 , B01J23/883 , B01J31/0202 , B01J31/04 , B01J35/0006 , B01J35/0026 , B01J35/026 , B01J35/1019 , B01J35/1061 , B01J37/0018 , B01J37/0201 , B01J37/0203 , B01J37/0205 , B01J37/0207 , B01J37/0215 , B01J37/0236 , B01J37/024 , B01J37/08 , B01J37/086 , B01J37/088 , B01J37/20 , B01J37/28 , B01J2523/00 , C10G45/08 , B01J2523/31 , B01J2523/51 , B01J2523/68 , B01J2523/845 , B01J2523/847
Abstract: Process for preparing a hydrotreating catalyst comprising of from 5 wt % to 50 wt % of molybdenum, of from 0.5 wt % to 20 wt % of nickel and of from 0 to 5 wt % of phosphorus, all based on total dry weight of catalyst, which process comprises (a) treating alumina carrier with molybdenum and nickel and of from 1 to 60% wt of gluconic acid, based on weight of carrier, and op tionally phosphorus, (b) optionally drying the treated carrier at a temperature of from 40 to 200° C., and (c) calcining the treated and optionally dried carrier at a temperature of from 200 to 650° C. to obtain the calcined treated carrier.
Abstract translation: 制备加氢处理催化剂的方法，其包含5重量％至50重量％的钼，0.5重量％至20重量％的镍和0至5重量％的磷，均基于催化剂的总干重， 该方法包括（a）以钼和镍为原料处理氧化铝载体，以及基于载体的重量计，1至60重量％的葡萄糖酸，和磷酸作用，（b）任选地在40℃的温度下干燥经处理的载体 至200℃，和（c）在200-650℃的温度下煅烧经处理和任选干燥的载体以获得经煅烧处理的载体。
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Patent Agency Ranking
12.发明申请TITANIA-BOUND ZSM-12 ZEOLITE COMPOSITION AND METHOD OF MAKING AND USING SUCH COMPOSITION 审中-公开TITANIA-BOUND ZSM-12沸石组合物及其制备和使用这种组合物的方法公开(公告)号：US20130153463A1
公开(公告)日：2013-06-20
申请号：US13715192
申请日：2012-12-14
Applicant: Shell Oil Company
Inventor： Peter GEERINCK , Hermanus JONGKIND , Marcello Stefano RIGUTTO
IPC: B01J29/06
CPC classification number: B01J29/06 , B01J21/063 , B01J23/44 , B01J29/7034 , B01J29/7469 , B01J35/0006 , B01J35/0026 , B01J35/023 , B01J35/1014 , B01J35/1023 , B01J37/0009 , B01J37/0201 , B01J2229/16 , B01J2229/37 , B01J2229/42 , C10G47/20
Abstract: Presented is a composition useful in the catalytic dewaxing of a waxy hydrocarbon feedstock. The composition includes a mixture of ZSM-12 zeolite and titania and may further include a noble metal. The ZSM-12 zeolite preferably has a high silica-to-alumina ratio within its framework. The mixture may be dealuminated either by acid leaching using a fluorosilicate salt or by steam treating.
Abstract translation: 提出了可用于蜡质烃原料的催化脱蜡的组合物。 组合物包括ZSM-12沸石和二氧化钛的混合物，并且还可以包括贵金属。 在其框架内，ZSM-12沸石优选具有高的二氧化硅与氧化铝的比例。 混合物可以通过使用氟硅酸盐的酸浸或通过蒸汽处理脱铝。
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公开(公告)号：US20230372922A1
公开(公告)日：2023-11-23
申请号：US18248707
申请日：2021-11-11
Applicant: SHELL OIL COMPANY
Inventor： Johan Peter DEN BREEJEN , Cornelis OUWEHAND , Marcello Stefano RIGUTTO
CPC classification number: B01J37/0201 , B01J29/126 , B01J37/088 , B01J35/1061 , C10G47/20
Abstract: The present invention provides a method of preparing a supported catalyst, preferably a hydrocracking catalyst, the method at least comprising the steps of: a) providing a zeolite Y having a bulk silica to alumina molar ratio (SAR) of at least 10; b) contacting the zeolite Y provided in step a) with a base and a surfactant, thereby obtaining a zeolite Y with increased mesoporosity; c) shaping the zeolite Y with increased mesoporosity as obtained in step b) thereby obtaining a shaped 10 catalyst carrier; d) calcining the shaped catalyst carrier as obtained in step c) in the presence of the surfactant of step b), thereby obtaining a calcined catalyst carrier; e) impregnating the catalyst carrier calcined in step d) with a noble metal component thereby obtaining a supported catalyst.
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公开(公告)号：US20210053040A1
公开(公告)日：2021-02-25
申请号：US17091789
申请日：2020-11-06
Applicant: SHELL OIL COMPANY
Inventor： László DOMOKOS , Laurent Georges HUVE , Hermanus JONGKIND , Aan Hendrik KLAZINGA , Marcello Stefano RIGUTTO
IPC: B01J29/74 , B01J29/78 , B01J29/76 , B01J29/72 , B01J37/30 , B01J37/00 , B01J29/70 , B01J35/10 , B01J29/80 , B01J37/02 , B01J23/755 , C10G49/08 , B01J23/44 , C10G35/06 , C10G45/64 , B01J23/42 , C10G50/00 , C10G45/62 , C10G65/04 , C10G47/16 , C10G47/18 , C10G47/20 , C10G65/12
Abstract: A hydrocarbon conversion catalyst composition which comprises ZSM-48 and/or EU-2 zeolite particles and refractory oxide binder essentially free of alumina in which the average aluminium concentration of the ZSM-48 and/or EU-2 zeolite particles is at least 1.3 times the aluminium concentration at the surface of the particles, processes for preparing such catalyst compositions and processes for converting hydrocarbon feedstock with the help of such compositions.
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公开(公告)号：US20200094231A1
公开(公告)日：2020-03-26
申请号：US16469433
申请日：2017-12-13
Applicant: SHELL OIL COMPANY
Inventor： Hermanus JONGKIND , Marcello Stefano RIGUTTO
Abstract: A catalyst system for dewaxing of a hydrocarbon feedstock comprising at least two catalytic sections, the first section comprising a first dewaxing catalyst and a subsequent section comprising a second dewaxing catalyst, wherein the first dewaxing catalyst is a ZSM-12 zeolite based catalyst and the second dewaxing catalyst is a EU-2 and/or ZSM-48 zeolite based catalyst. The catalyst system displays enhanced performance when compared to systems containing either ony ZSM-12 based catalyst or EU-2/ZSM-48 based catalyst only.
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16.发明申请公开(公告)号：US20190151830A1
公开(公告)日：2019-05-23
申请号：US16316684
申请日：2016-07-13
Applicant: SHELL OIL COMPANY
Inventor： Robin KOLVENBACH , Marcello Stefano RIGUTTO , Thomas WEBER , Lennart VAN HAANDEL
IPC: B01J27/051 , B01J21/06 , B01J35/00 , B01J37/03 , C07C1/32
Abstract: The invention relates to a process for the preparation of nanoparticles of MoS2 supported on TiO2 wherein the preparation is performed by reductive coprecipitation using aqueous solutions containing Ti and Mo precursor salts, and wherein MoS2 may be non-promoted or Co-promoted. Further, the invention relates to the use of said nanoparticles as hydrodesulfurization catalysts.
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