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    Fluorene Derivative, Transition Metal Compound, Catalyst for Olefin Polymerization, and Process for Producing Olefin Polymer
    12.
    发明申请
    Fluorene Derivative, Transition Metal Compound, Catalyst for Olefin Polymerization, and Process for Producing Olefin Polymer 有权
    芴衍生物，过渡金属化合物，用于烯烃聚合的催化剂，以及生产烯烃聚合物的方法

    公开(公告)号：US20090253876A1

    公开(公告)日：2009-10-08

    申请号：US11920767

    申请日：2006-05-24

    申请人： Munehito Funaya ,  Koji Endo ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

    发明人： Munehito Funaya ,  Koji Endo ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

    IPC分类号： C08F2/00 ,  C07F7/02 ,  B01J31/12 ,  C08F4/42 ,  C07F7/00 ,  C07C25/24

    CPC分类号： C07C13/567 ,  C07F7/081 ,  C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/02 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/15 ,  C08F210/06 ,  C08F210/14

    摘要： Provided is a novel fluorene derivative which is useful as a catalyst component for olefin polymerization, a transition metal compound containing the fluorene derivative as a part of ligand, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing olefin polymer. The fluorene derivative is characterized by being represented by the following general formula [I]: wherein R1, R2, R3, R5, R6, R7, R8, R9, R10, R11, R12, and R14 are each selected from hydrogen, a hydrocarbon group, and a silicon-containing group, and may be the same as or different from each other, R4 and R13 are each selected from hydrogen, a hydrocarbon group, a silicon-containing group, a sulfur-containing group, an oxygen-containing group, a nitrogen-containing group, and a halogen-containing group, and may be the same as or different from each other, and adjacent substituents of R1 to R14 may be bonded to each other to form a ring, except that the case where R4 and R5, and R12 and R13 are each bonded to each other to form a vinylene group. Also provided is a bridged metallocene compound having both of the skeleton and a cyclopentadiene skeleton.

    摘要翻译： 提供了可用作烯烃聚合的催化剂组分的新型芴衍生物，含有芴衍生物作为配体的一部分的过渡金属化合物，含有过渡金属化合物的烯烃聚合用催化剂和烯烃聚合物的制造方法。 芴衍生物的特征在于由以下通式[I]表示：其中R1，R2，R3，R5，R6，R7，R8，R9，R10，R11，R12和R14各自选自氢，烃 基团和含硅基团，并且可以彼此相同或不同，R4和R13各自选自氢，烃基，含硅基团，含硫基团，含氧基团 基团，含氮基团和含卤素基团，可以相同或不同，R1〜R14的相邻取代基可以相互键合形成环，除了以下情况 R4和R5以及R12和R13各自彼此键合形成亚乙烯基。 还提供了具有骨架和环戊二烯骨架两者的桥连金属茂化合物。

    Transition Metal Compound, Catalyst for Olefin Polymerization, and Process for Producing Olefin Polymer
    13.
    发明申请
    Transition Metal Compound, Catalyst for Olefin Polymerization, and Process for Producing Olefin Polymer 审中-公开
    过渡金属化合物，用于烯烃聚合的催化剂，以及生产烯烃聚合物的方法

    公开(公告)号：US20090043057A1

    公开(公告)日：2009-02-12

    申请号：US11920779

    申请日：2006-05-24

    申请人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

    发明人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

    IPC分类号： C08F4/78 ,  C07F7/08 ,  C07F11/00 ,  C08F2/00 ,  B01J31/12

    CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F2500/15 ,  C08F2500/03 ,  C08F210/06 ,  C08F2500/17 ,  C08F4/65927

    摘要： Provided is a transition metal compound novel and useful as a catalyst component for olefin polymerization, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing an olefin polymer using the catalyst for polymerization. The transition metal is characterized by being represented by the following general formula [I]: wherein, R3 is hydrogen, R2 is selected from a hydrocarbon group or a silicon-containing group, R1 and R4 are selected from a hydrocarbon group having 2 to 20 carbon atoms and a silicon-containing group, each of R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14, which is selected from hydrogen, a hydrocarbon group and a silicon-containing group, may be same or different from each other, and adjacent groups from R5 to R14 may be bonded to each other to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q may be selected from halogen, a hydrocarbon group, an anionic ligand and a neutral ligand capable of coordinating with a lone electron pair, which may be selected in the same combination or different combination, and j is an integer of 1 to 4.

    摘要翻译： 提供了一种新颖可用作烯烃聚合催化剂组分的过渡金属化合物，含有过渡金属化合物的烯烃聚合催化剂，以及使用聚合催化剂生产烯烃聚合物的方法。 过渡金属的特征在于由以下通式[I]表示：其中，R3是氢，R2选自烃基或含硅基团，R1和R4选自具有2〜20个碳原子的烃基 碳原子和含硅基团，选自氢，烃基和含硅基团的R5，R6，R7，R8，R9，R10，R11，R12，R13和R14各自可以相同 或彼此不同，并且R 5至R 14的相邻基团可以彼此键合形成环。 M是第4族过渡金属，Y是碳原子，Q可以选自卤素，烃基，阴离子配体和能够与单个电子对配位的中性配体，其可以以相同的组合或 不同的组合，j为1〜4的整数。

    TRANSITION METAL COMPOUND, CATALYST FOR OLEFIN POLYMERIZATION, AND PROCESS FOR PRODUCING OLEFIN POLYMER
    15.
    发明申请
    TRANSITION METAL COMPOUND, CATALYST FOR OLEFIN POLYMERIZATION, AND PROCESS FOR PRODUCING OLEFIN POLYMER 审中-公开
    过渡金属化合物，烯烃聚合催化剂和生产烯烃聚合物的方法

    公开(公告)号：US20100190941A1

    公开(公告)日：2010-07-29

    申请号：US12753647

    申请日：2010-04-02

    申请人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

    发明人： Munehito Funaya ,  Naritoshi Hirota ,  Yuichi Yamamura ,  Koji Kawai

    IPC分类号： C08F2/00

    CPC分类号： C07F17/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F2500/15 ,  C08F2500/03 ,  C08F210/06 ,  C08F2500/17 ,  C08F4/65927

    摘要： Provided is a transition metal compound novel and useful as a catalyst component for olefin polymerization, a catalyst for olefin polymerization containing the transition metal compound, and a process for producing an olefin polymer using the catalyst for polymerization. The transition metal is characterized by being represented by the following general formula [I]: wherein, R3 is hydrogen, R2 is selected from a hydrocarbon group or a silicon-containing group, R1 and R4 are selected from a hydrocarbon group having 2 to 20 carbon atoms and a silicon-containing group, each of R5, R6, R7, R8, R9, R10, R11, R12, R13 and R14, which is selected from hydrogen, a hydrocarbon group and a silicon-containing group, may be same or different from each other, and adjacent groups from R5 to R14 may be bonded to each other to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q may be selected from halogen, a hydrocarbon group, an anionic ligand and a neutral ligand capable of coordinating with a lone electron pair, which may be selected in the same combination or different combination, and j is an integer of 1 to 4.

    摘要翻译： 提供了一种新颖可用作烯烃聚合催化剂组分的过渡金属化合物，含有过渡金属化合物的烯烃聚合催化剂，以及使用聚合催化剂生产烯烃聚合物的方法。 过渡金属的特征在于由以下通式[I]表示：其中，R3是氢，R2选自烃基或含硅基团，R1和R4选自具有2〜20个碳原子的烃基 碳原子和含硅基团，选自氢，烃基和含硅基团的R5，R6，R7，R8，R9，R10，R11，R12，R13和R14各自可以相同 或彼此不同，并且R 5至R 14的相邻基团可以彼此键合形成环。 M是第4族过渡金属，Y是碳原子，Q可以选自卤素，烃基，阴离子配体和能够与单个电子对配位的中性配体，其可以以相同的组合或 不同的组合，j为1〜4的整数。

    Propylene Random Block Copolymer, Resin Composition Containing the Copolymer and Molded Article Made Thereof
    18.
    发明申请
    Propylene Random Block Copolymer, Resin Composition Containing the Copolymer and Molded Article Made Thereof 审中-公开
    丙烯无规嵌段共聚物，含有共聚物的树脂组合物及其制成的模制品

    公开(公告)号：US20090069523A1

    公开(公告)日：2009-03-12

    申请号：US12225689

    申请日：2007-03-27

    申请人： Keita Itakura ,  Satoshi Hashizume ,  Kunihiko Takesue ,  Munehito Funaya

    发明人： Keita Itakura ,  Satoshi Hashizume ,  Kunihiko Takesue ,  Munehito Funaya

    IPC分类号： C08F210/00

    CPC分类号： C08F297/083 ,  C08L23/142 ,  C08L2207/02 ,  C08L23/16

    摘要： The invention provides a propylene random block copolymer (A) that has a melt flow rate from 0.1 to 100 g/10 min and a melting point from 100 to 155° C. and includes 90 to 60% by weight of a portion insoluble (Dinsol) in n-decane at room temperature and 10 to 40% by weight of a portion soluble (Dsol) in n-decane at room temperature, wherein the Dinsol satisfies the following requirements (1) through (3) and the Dsol satisfies the following requirements (4) through (6). The invention further provides molded articles such as sheets, films, injection molded articles, hollow molded articles, injection blow molded articles and fibers, which are formed of the propylene random block copolymer (A) or a propylene resin composition containing the propylene random block copolymer (A). (1) The molecular weight distribution (Mw/Mn) obtained by GPC of the Dinsol is from 1.0 to 3.5, (2) the content of skeletons derived from ethylene in the Dinsol is from 0.5 to 13% by mole, (3) the total amount of 2,1- and 1,3-propylene units in the Dinsol is 0.2% by mole or less, (4) the molecular weight distribution (Mw/Mn) obtained by GPC of the Dsol is from 1.0 to 3.5, (5) the intrinsic viscosity [η] in decalin at 135° C. of the Dsol is from 1.5 to 4 dl/g and (6) the content of skeletons derived from ethylene in the Dsol is from 15 to 35% by mole.

    摘要翻译： 本发明提供一种丙烯无规嵌段共聚物（A），其熔体流动速率为0.1-100g / 10min，熔点为100-155℃，包括90-60wt％的不溶物（Dinsol ）和室温下正癸烷中可溶解部分（Dsol）的10〜40重量％，其中，D insol为（1）〜（3），Dsol满足下述式 要求（4）至（6）。 本发明还提供了由丙烯无规嵌段共聚物（A）形成的成型制品，例如片材，薄膜，注塑制品，中空成型制品，注塑吹塑制品和纤维，或含丙烯无规嵌段共聚物 （一个）。 （1）由Dinsol得到的分子量分布（Mw / Mn）为1.0〜3.5，（2）由Dinsol得到的乙烯的骨架含量为0.5〜13摩尔％，（3） D insol中的2,1-和1,3-丙烯单元的总量为0.2摩尔％以下，（4）通过Dsol的GPC得到的分子量分布（Mw / Mn）为1.0〜3.5（ 5）Dsol的135℃萘烷中的特性粘度η为1.5〜4dl / g，（6）Dsol中衍生自乙烯的骨架含量为15〜35摩尔％。

    Thiourethane-based optical material
    20.
    发明申请
    Thiourethane-based optical material 有权
    硫代氨基甲酸酯类光学材料

    公开(公告)号：US20050131203A1

    公开(公告)日：2005-06-16

    申请号：US10509765

    申请日：2003-12-12

    申请人： Mamoru Tanaka ,  Shigetoshi Kuma ,  Munehito Funaya ,  Seiichi Kobayashi

    发明人： Mamoru Tanaka ,  Shigetoshi Kuma ,  Munehito Funaya ,  Seiichi Kobayashi

    IPC分类号： C08G18/38 ,  C08G18/76 ,  G02B1/04 ,  C08G75/00

    CPC分类号： C08G18/7642 ,  C08G18/3876 ,  G02B1/04 ,  C08L75/04 ,  C08L81/00

    摘要： A composition for making a high-refractive-index resin contains a polythiol compound and a compound containing at least two iso(thio)cyanato groups, the polythiol compound having a dithioacetal, dithioketal, orthotrithioformic ester, or orthotetrathiocarbonic ester skeleton. The molar ratio of the mercapto group to the iso(thio)cyanato group in the composition is greater than 1.0 but not more than 3.0. A method for making a resin by curing the composition, a resin prepared by curing the composition, an optical element made from the resin, and a lens made from the optical element are also provided.

    摘要翻译： 用于制备高折射率树脂的组合物含有多硫醇化合物和含有至少两个异（硫）氰酸基的化合物，多硫醇化合物具有二硫缩醛，二硫缩酮，邻二硫代甲酸酯或邻四硫代碳酸酯骨架。 组合物中巯基与异（硫）氰酸基的摩尔比大于1.0但不大于3.0。 通过固化组合物制备树脂的方法，通过固化组合物制备的树脂，由树脂制成的光学元件和由光学元件制成的透镜也被提供。