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    Certain triacylglycerols as crystallization depressants
    11.
    发明授权
    Certain triacylglycerols as crystallization depressants 有权

    公开(公告)号：US10047313B2

    公开(公告)日：2018-08-14

    申请号：US15337500

    申请日：2016-10-28

    Applicant: TRENT UNIVERSITY

    Inventor： Suresh Narine ,  Laziz Bouzidi ,  Athira Mohanan

    IPC: C10L10/14 ,  C10L1/02 ,  C10L1/19

    Abstract: This application relates to the polymorphism and microstructure of certain triacylglycerols and fatty acid methyl esters, including 1,2-dioleoyl-3-stearoyl glycerol and methyl stearate, and how the properties of these individual components in a biodiesel fuel, as well as their combined mixtures, helps understand the fundamental mechanisms of their crystallization so as to design biodiesel fuels with improved low temperature characteristics.

    RENEWABLY DERIVED THERMOPLASTIC POLYESTER-BASED URETHANES AND METHODS OF MAKING AND USING THE SAME
    20.
    发明申请
    RENEWABLY DERIVED THERMOPLASTIC POLYESTER-BASED URETHANES AND METHODS OF MAKING AND USING THE SAME 审中-公开

    公开(公告)号：US20170145145A1

    公开(公告)日：2017-05-25

    申请号：US15361174

    申请日：2016-11-25

    Applicant: Trent University

    Inventor： Suresh Narine ,  Shegufta Shetranjiwalla ,  Shaojun Li ,  Laziz Bouzidi

    IPC: C08G18/10 ,  C08G18/42 ,  C08G18/32 ,  C08G18/73

    CPC classification number: C08G18/10 ,  C08G18/244 ,  C08G18/3206 ,  C08G18/4236 ,  C08G18/4238 ,  C08G18/73 ,  C08G18/8016 ,  C08G2230/00

    Abstract: The disclosure generally provides high-molecular-weight thermoplastic polyester-based urethanes (TPEUs). In some embodiments, the component monomers of the TPEUs are entirely derived from renewable sources. The disclosure also provides methods of making high-molecular-weight TPEUs, and, in particular, methods for achieving such high molecular weights. The disclosure also provides certain uses of such TPEUs. Entirely lipid-derived segmented thermoplastic TPEU elastomers with rubber-like properties such as low modulus and high elongation were produced by incorporating 1,9-nonanediol (ND) as chain extender with oleic acid derived polyester diols (PEDs) and 1,7-heptamethylene diisocyanate (HPMDI). Enhanced elastomeric properties were achieved by optimizing hydrogen bond density and phase separation of the TPEU via customized polymerization protocols. The novel TPEUs showed extensive degradation under hydrothermal ageing in water at 80° C. and achieved a tensile half-life in one day of immersion. For the first time, entirely lipid-derived TPEU elastomers with thermal and mechanical properties comparable to commercially available petroleum-based analogues and a controlled life-cycle were achieved, demonstrating the viability of potential alternatives to petroleum-derived elastomers and credible potential in biomedical applications especially as bio-resorbable implants or tissue scaffolds.

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