FCC process with fines tolerant SCR reactor
    11.
    发明授权
    FCC process with fines tolerant SCR reactor 失效
    FCC工艺与细微的SCR反应堆

    公开(公告)号:US5413699A

    公开(公告)日:1995-05-09

    申请号:US136053

    申请日:1993-10-14

    申请人: Tai-Sheng Chou

    发明人: Tai-Sheng Chou

    IPC分类号: B01D53/86 C10G11/18 C10G11/00

    摘要: A process for reducing NOx emissions and an FCC process using same as a flue gas cleanup stage are disclosed. Gas containing NOx and entrained catalyst fines is passed up through a bed of catalyst at a sufficient velocity to expand and fluidize the catalyst bed. Particulates deposited on the catalyst are abraided or elutriated away by fluidization, preventing fouling of the DeNOx catalyst. A low pressure drop design, with vertical, perforate gas distributors covered by the bed is also disclosed.

    摘要翻译: 公开了一种用于减少NOx排放的方法和使用其与烟道气净化阶段相关的FCC方法。 含有NOx和夹带的催化剂细粒的气体以足够的速度向上通过催化剂床,以使催化剂床膨胀和流化。 沉积在催化剂上的颗粒通过流化被磨损或淘洗掉,防止DeNOx催化剂结垢。 还公开了一种低压降设计,其具有由床覆盖的垂直,穿孔气体分配器。

    Isomerization process
    12.
    发明授权
    Isomerization process 失效
    异构化过程

    公开(公告)号:US5227554A

    公开(公告)日:1993-07-13

    申请号:US799797

    申请日:1991-11-29

    申请人: Tai-Sheng Chou

    发明人: Tai-Sheng Chou

    IPC分类号: C07C5/22 C07C9/12

    摘要: A process for the isomerization of C.sub.4 and higher molecular weight hydrocarbons, preferably C.sub.4 to C.sub.6 paraffins with high C.sub.6 cyclics content. A C.sub.5 to C.sub.6 hydrocarbon stream is isomerized in a first isomerization reaction zone and a C.sub.4 hydrocarbon stream is isomerized in a second isomerization reaction zone. At least one or both of the effluent streams from the first and second isomerization zones are conveyed to a gas-liquid separator which separates a hydrogen-rich recycle stream. At least a portion of the hydrogen-rich recycle stream is conveyed to the C.sub.5 to C.sub.6 hydrocarbon feed stream and at least a portion of the hydrogen-rich recycle stream is conveyed to the C.sub.4 hydrocarbon feed stream whereby the hydrogen recycle stream is shared during both the C.sub.4 isomerization reaction and the C.sub.5 to C.sub.6 isomerization reaction. The product stream is conveyed to a shared stabilizer which removes the gaseous and volatile components. The product stream can be fractionated to recover the separate C.sub.4 to C.sub.6 isoparaffins and normal paraffins and naphthenic compounds.

    摘要翻译: C4和更高分子量烃异构化的方法,优选具有高C6环状含量的C4至C6链烷烃。 C5至C6烃流在第一异构化反应区中异构化,C4烃流在第二异构化反应区中异构化。 来自第一和第二异构化区域的至少一种或两种流出物流被输送到分离富氢循环流的气液分离器。 富氢循环流的至少一部分被输送到C5至C6烃进料流,并且至少一部分富氢循环流被输送到C 4烃进料流,由此氢再循环流在两者期​​间共享 C4异构化反应和C5至C6异构化反应。 产物流被输送到共同的稳定剂,其除去气体和挥发性组分。 可以将产物流分馏以回收分开的C4至C6异链烷烃和正链烷烃和环烷烃化合物。

    Heat balanced paraffin upgrading with co-fed oxygenate
    14.
    发明授权
    Heat balanced paraffin upgrading with co-fed oxygenate 失效
    用共同给药的含氧化合物进行热平衡链烷烃升级

    公开(公告)号:US5019663A

    公开(公告)日:1991-05-28

    申请号:US332185

    申请日:1989-04-03

    IPC分类号: C07C2/00

    摘要: The endothermic heat of reaction for zeolite-catalyzed paraffin aromatization is provided by a co-fed oxygenate stream. Advantageously, the addition of a dehydrogenation metal to the zeolite reduces the reaction temperature for paraffin aromatization to a range suitable for the exothermic conversion of an oxygenate to C.sub.5 + gasoline. Preferred paraffinic feedstreams include C.sub.3 -C.sub.4 LGP and the preferred oxygenate is methanol.

    摘要翻译: 沸石催化的链烷烃芳构化反应的吸热是通过共同供给的含氧化合物流来提供的。 有利的是,向沸石中加入脱氢金属使链烷烃芳构化反应的反应温度降低到适合于将含氧化合物向C5 +汽油的放热转化的范围。 优选的链烷烃进料流包括C3-C4LGP,优选的含氧化合物是甲醇。

    Catalytic cracking process with reduced pressure stripping
    15.
    发明授权
    Catalytic cracking process with reduced pressure stripping 失效
    催化裂化过程减压剥离

    公开(公告)号:US4921596A

    公开(公告)日:1990-05-01

    申请号:US301768

    申请日:1989-01-26

    IPC分类号: C10G11/16 C10G11/18

    CPC分类号: C10G11/16 C10G11/18

    摘要: The present invention describes improved FCC and TCC stripper operations by incorporating a stripper operated at a reduced pressure. The improved strippers of the invention will increase total liquid hydrocarbon yield while reducing the coke load on the regenerator. Novel porous TCC bead catalysts are disclosed wherein at least 1/3 of the pore volume of catalyst pores having a pore diameter of at least 3000 Angstroms. These macropores facilitate flash vaporization of hydrocarbons in a stripping zone of the spent catalyst upstream of a regeneration zone.

    摘要翻译: 本发明通过结合在减压下操作的汽提器来描述改进的FCC和TCC汽提器操作。 本发明的改进的脱模剂将增加总的液体烃产率,同时减少再生器上的焦炭负荷。 公开了新型多孔TCC珠粒催化剂,其中至少1/3的孔体积的孔体积至少为3000埃。 这些大孔促进在再生区上游的废催化剂的汽提区中烃的闪蒸。

    Feed mixing technique for fluidized catalytic cracking of hydrocarbon oil
    17.
    发明授权
    Feed mixing technique for fluidized catalytic cracking of hydrocarbon oil 失效
    烃油流化催化裂化的进料混合技术

    公开(公告)号:US4578183A

    公开(公告)日:1986-03-25

    申请号:US676967

    申请日:1984-11-30

    IPC分类号: B01J8/08 C10G11/18 C10G35/14

    CPC分类号: B01J8/085 C10G11/18

    摘要: An improved Fluid Catalytic Cracking (FCC) Process wherein vaporization of oil feed is optimized prior to catalytic cracking. A draft tube mixer placed in the lower reactor riser splits the hot regenerated catalyst flow into two streams resulting in improved riser mixing of catalyst and oil.

    摘要翻译: 改进的流体催化裂化(FCC)方法,其中在进料催化裂化之前,油进料的蒸发被优化。 放置在下反应器提升管中的引流管混合器将热再生的催化剂流分成两股流,从而改进催化剂和油的提升管混合。

    Processing of hydrocarbons in fixed catalyst bed with redistribution
means
    18.
    发明授权
    Processing of hydrocarbons in fixed catalyst bed with redistribution means 失效
    用再分配装置处理固定催化剂床中的烃

    公开(公告)号:US4481105A

    公开(公告)日:1984-11-06

    申请号:US411142

    申请日:1982-08-25

    申请人: Tai-Sheng Chou

    发明人: Tai-Sheng Chou

    IPC分类号: B01J8/04 C10G49/00 C10G11/10

    CPC分类号: B01J8/0492 C10G49/002

    摘要: Hydrocarbons are processed in a co-current flow packed catalyst bed reactor containing one or more redistribution means, e.g., redistribution screens, in the packed catalyst bed. If more than one redistribution means are used, they are spaced within the bed of catalyst over a predetermined distance. Optionally, the surface area of the redistribution means is less than the cross-sectional surface area of the reactor bed to allow for packing of a relatively smaller size solid particles, as compared to the rest of the catalyst in the bed, in the area between the edge of the redistribution means and the inner wall of the reactor means. The use of the redistribution means prevents channeling of the reactants near the reactor wall region, and assures uniform distribution of the reactants throughout the packed catalyst bed. The invention is applicable to relatively low velocity systems operating at liquid linear velocity of 0.3 cm/sec. or less.

    摘要翻译: 在包含催化剂床中的一个或多个再分布装置(例如再分配筛网)的同流流动填充催化剂床反应器中处理碳氢化合物。 如果使用多于一个再分配装置,则它们在预定距离内在催化剂床内间隔开。 任选地,再分布装置的表面积小于反应器床的横截面表面积,以允许与床中的催化剂的其余部分相对较小尺寸的固体颗粒填充,在 再分配装置的边缘和反应堆装置的内壁。 使用再分配装置可防止反应器壁区域附近的反应物通道,并确保反应物在整个填料催化剂床上的均匀分布。 本发明适用于以0.3厘米/秒的液体线速度运行的相对低速系统。 或更少。

    System for concentrating a spent caustic stream
    20.
    发明授权
    System for concentrating a spent caustic stream 失效
    用于浓缩废碱流的系统

    公开(公告)号:US5209828A

    公开(公告)日:1993-05-11

    申请号:US812313

    申请日:1991-12-23

    IPC分类号: B01D3/06 B01D3/10 C10G19/08

    摘要: A system and method of concentrating spent caustic at a refinery has a multi-stage flash drum for separating a spent caustic stream into an overhead output stream including vaporized water and volatile organic compounds, and a concentrated spent caustic output stream. The system also has a condenser for condensing the overhead output stream, and a separator for separating the condensed overhead output stream into a volatile organic compound stream, a liquid hydrocarbon stream and a water stream. The system further has an ejector for applying a vacuum to the flash drum to vaporize the spent caustic stream at a reduced temperature, and to the separator to remove the volatile organic compound stream. The volatile organic compounds are removed from the overhead of the separator through the ejector to a burner of a fired heater.

    摘要翻译: 在炼油厂浓缩废碱的系统和方法具有多级闪蒸鼓,用于将废碱流分离成包括蒸发的水和挥发性有机化合物的塔顶输出流,以及浓缩的废碱输出流。 该系统还具有用于冷凝塔顶输出流的冷凝器和用于将冷凝塔顶输出流分离成挥发性有机化合物流,液体烃流和水流的分离器。 该系统还具有用于向闪蒸鼓施加真空以在降低的温度下蒸发废碱流的喷射器,以及用于去除挥发性有机化合物流的喷射器。 挥发性有机化合物通过喷射器从分离器的顶部除去到燃烧加热器的燃烧器。