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    Process for producing olefin polymer and solid titanium catalyst component
    12.
    发明授权
    Process for producing olefin polymer and solid titanium catalyst component 有权
    制备烯烃聚合物和固体钛催化剂组分的方法

    公开(公告)号：US07888437B2

    公开(公告)日：2011-02-15

    申请号：US11795505

    申请日：2006-01-19

    申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

    IPC分类号： C08F4/42

    CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

    摘要： The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1): wherein n is an integer of 5 to 10, R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, and a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, and an organometallic compound catalyst component (II), at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature. According to this process, an olefin polymer having a broad molecular weight distribution can be prepared.

    摘要翻译： 本发明的烯烃聚合物的制造方法的特征在于，在含有含有钛，镁的固体钛催化剂成分（I）的烯烃聚合催化剂存在下，聚合具有3个以上碳原子的烯烃 ，卤素和下述式（1）所示的环状酯化合物（a）：其中n为5〜10的整数，R2和R3各自独立地为COOR1或氢原子，R2和R3中的至少一个 是COOR1; 并且R 1各自独立地为具有1至20个碳原子的单价烃基，并且环状主链中的单键（不包括Ca-Ca键，在R3为氢原子的情况下为Ca-Cb键）可以被替换 （II），在聚合反应器的内压下，在聚合温度下为烯烃的饱和蒸气压的0.25倍以上。 根据该方法，可以制备具有宽分子量分布的烯烃聚合物。

    Solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process
    13.
    发明授权
    Solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process 有权
    固体钛催化剂组分，烯烃聚合催化剂和烯烃聚合方法

    公开(公告)号：US08742040B2

    公开(公告)日：2014-06-03

    申请号：US12744760

    申请日：2008-11-14

    申请人： Kazuhisa Matsunaga ,  Kazutaka Tsuru ,  Kazumitsu Kawakita ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Kazutaka Tsuru ,  Kazumitsu Kawakita ,  Tetsunori Shinozaki

    IPC分类号： C08F4/50

    CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/03 ,  C08F4/6465

    摘要： A solid titanium catalyst component (I) comprising titanium, magnesium, halogen, a specific cyclic ester compound (a) and a specific cyclic ester compound (b), an olefin polymerization catalyst containing this catalyst component (I), and an olefin polymerization process using this olefin polymerization catalyst are disclosed. According to the solid titanium catalyst component, the olefin polymerization catalyst and the process for preparing an olefin polymer of the invention, an olefin polymer having high stereoregularity and a wide molecular weight distribution can be prepared with high activity, preparation of an olefin polymer excellent not only in molding properties such as high-speed streatchability and high-speed moldability but also in rigidity becomes possible, and besides, production cost can be reduced.

    摘要翻译： 包含钛，镁，卤素，特定环状酯化合物（a）和特定环状酯化合物（b）的固体钛催化剂组分（I），含有该催化剂组分（I）的烯烃聚合催化剂和烯烃聚合方法 公开了使用该烯烃聚合催化剂。 根据固体钛催化剂组分，本发明的烯烃聚合催化剂和制备烯烃聚合物的方法可以制备具有高立构规整性和宽分子量分布的烯烃聚合物，其活性高，不能制备优异的烯烃聚合物 只有在高速可塑性和高速成型性等成型性能的同时，也能够实现刚性化，而且可以降低生产成本。

    SOLID TITANIUM CATALYST COMPONENT, CATALIST FOR OLEFIN POLYMERIZATION AND PROCESS FOR POLYMERIZING OLEFIN
    14.
    发明申请
    SOLID TITANIUM CATALYST COMPONENT, CATALIST FOR OLEFIN POLYMERIZATION AND PROCESS FOR POLYMERIZING OLEFIN 有权
    固体钛催化剂组分，用于烯烃聚合的催化剂和聚合烯烃的方法

    公开(公告)号：US20100227991A1

    公开(公告)日：2010-09-09

    申请号：US12734390

    申请日：2008-10-31

    申请人： Kazuhisa Matsunaga ,  Kazutaka Tsuru ,  Kazumitsu Kawakita ,  Takashi Jinnai ,  Tetsunori Shinozaki

    发明人： Kazuhisa Matsunaga ,  Kazutaka Tsuru ,  Kazumitsu Kawakita ,  Takashi Jinnai ,  Tetsunori Shinozaki

    IPC分类号： C08F4/16 ,  B01J31/04 ,  C08F4/60

    CPC分类号： C08F110/06 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/04

    摘要： The present invention provides an olefin polymerization catalyst, which is free of polyfunctional aromatic compounds and has a large particle diameter, and a solid titanium component (I) which forms the catalyst. The olefin polymerization catalyst comprises a solid titanium component (I), an organometallic compound (II) and optionally an electron donor (III) wherein the solid titanium component (I) comprising titanium, magnesium and halogen is obtainable by allowing a magnesium compound (A) having no reducing ability in a liquid state to contact with an ester compound (B) represented by the following formula (1) and a liquid titanium compound (C) in a specific order, wherein R2 and R3 are COOR1 or R, and at least one of R2 and R3 is COOR1, two or more R1 each are a monovalent hydrocarbon group having 1 to 20 carbon atoms, and two or more R are a hydrogen atom, or a hydrocarbon group having 1 to 20 carbon atoms, and at least two of Rs may be bonded each other to form a ring, and the skeleton of the ring formed may include a double bond or a hetero atom.

    摘要翻译： 本发明提供一种不含多官能芳族化合物并具有大粒径的烯烃聚合催化剂和形成催化剂的固体钛组分（I）。 烯烃聚合催化剂包括固体钛组分（I），有机金属化合物（II）和任选的电子给体（III），其中包含钛，镁和卤素的固体钛组分（I）可通过使镁化合物（A ），其中R2和R3分别为COOR1或R，并且在特定的顺序与液态钛化合物（C）以下列通式（1）表示的酯化合物（B）和液态钛化合物（C） R2和R3中的至少一个是COOR1，两个或更多个R1各自是具有1至20个碳原子的一价烃基，并且两个或更多个R是氢原子或具有1至20个碳原子的烃基，并且至少 R 2中的两个可以彼此键合形成环，所形成的环的骨架可以包括双键或杂原子。

    Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition
    15.
    发明授权
    Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition 失效
    丙烯聚合物，丙烯嵌段共聚物，制备所述聚合物和所述嵌段共聚物的方法以及丙烯聚合物组合物

    公开(公告)号：US06630559B2

    公开(公告)日：2003-10-07

    申请号：US09899135

    申请日：2001-07-06

    申请人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

    发明人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

    IPC分类号： C08F4642

    CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F297/06 ,  C08F2500/15 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/26

    摘要： Disclosed are a propylene polymer having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain (continuous propylene units wherein directions of {acute over (&agr;)}-methyl carbons are the same as each other), and a process for preparing said polymer. Further disclosed is a propylene polymer composition comprising the above propylene polymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer a metallic salt of higher aliphatic acid. The propylene block polymer of the invention is well-balanced between rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, filament, injection molded product, blow molded product, etc. The propylene polymer composition of the invention has excellent properties of the propylene polymer of or the propylene block copolymer, and moreover is excellent in heat stability during the molding stage, long-term heat stability and weathering resistance. The propylene polymer composition can be favorably used for sheet, film, filament, injection mold product, blow molded product, etc.

    摘要翻译： 公开了具有高沸点庚烷不溶性组分的高结晶度丙烯聚合物，高立构规整性和极长的分散信号（其中α-甲基碳的方向彼此相同的连续丙烯单元），以及 制备所述聚合物。 还公开了包含上述丙烯聚合物和至少一种选自酚类稳定剂，有机亚磷酸酯型稳定剂，硫醚型稳定剂，受阻胺型稳定剂，高级脂肪酸金属盐的稳定剂的丙烯聚合物组合物。 本发明的丙烯嵌段聚合物在刚性，耐热性和耐湿性之间的平衡性良好，可有利地用于片材，长丝，注塑产品，吹塑产品等。本发明的丙烯聚合物组合物具有优异的性能 丙烯嵌段共聚物的丙烯聚合物，而且在成型阶段的热稳定性，长期的热稳定性和耐候性优异。 丙烯聚合物组合物可有利地用于片，膜，丝，注塑产品，吹塑产品等。

    Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymers
    16.
    发明授权
    Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymers 失效
    烯烃聚合催化剂和制备聚丙烯和丙烯嵌段共聚物的方法

    公开(公告)号：US06271166B1

    公开(公告)日：2001-08-07

    申请号：US08730930

    申请日：1996-10-16

    申请人： Tetsunori Shinozaki ,  Mamoru Kioka

    发明人： Tetsunori Shinozaki ,  Mamoru Kioka

    IPC分类号： B01J3102

    CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/52 ,  Y10S526/904 ,  C08F4/6492 ,  C08F4/6494 ,  C08F4/6465 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/18 ,  C08F210/16

    摘要： Olefin polymerization catalysts are formed from: (I-1) a contact product obtained by contacting (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (C) a specific organosilicon compound, (II-1) (D) a specific polyether compound and, optionally, (III) an organometallic compound catalyst component; or (I-2) a contact product obtained by contacting (A) a solid titanium catalyst component, (B) an organometallic compound catalyst component, and (D) a specific polyether compounds, (II-2) (C) a specific organosilicon compound, and, optionally, (III) an organometallic compound catalyst component; or the contact product (I-1) or (I-2) may be replaced by one which is obtained by prepolymerizing an olefin of 2 or more carbon atoms in the presence of the catalyst components for the contact product (I-1) or (I-2).

    摘要翻译： 烯化聚合催化剂由以下物质形成：（I-1）通过使（A）固体钛催化剂组分，（B）有机金属化合物催化剂组分和（C）特定的有机硅化合物（II-1） （D）特定的聚醚化合物和任选的（III）有机金属化合物催化剂组分; 或（I-2）与（A）固体钛催化剂组分（B）有机金属化合物催化剂组分和（D）特定聚醚化合物（II-2）（C））接触的接触产物， 化合物和任选的（III）有机金属化合物催化剂组分; 或者接触产物（I-1）或（I-2）可以由在接触产物（I-1）或（I-1）或（I-2）的催化剂组分存在下预聚合2个或更多个碳原子的烯烃 I-2）。

    Olefin polymer composition
    17.
    发明授权
    Olefin polymer composition 失效
    烯烃聚合物组成

    公开(公告)号：US5438100A

    公开(公告)日：1995-08-01

    申请号：US182403

    申请日：1994-01-18

    申请人： Tetsunori Shinozaki ,  Mamoru Kioka

    发明人： Tetsunori Shinozaki ,  Mamoru Kioka

    IPC分类号： C08F4/607 ,  C08F210/02 ,  C08F210/06 ,  C08F210/18 ,  C08F297/06 ,  C08L23/02 ,  C08L23/04 ,  C08L23/10 ,  C08L23/16 ,  C08L47/00

    CPC分类号： C08L23/02 ,  C08F210/18 ,  C08F297/06 ,  C08L23/10 ,  C08L23/16 ,  C08F210/02 ,  C08F210/06 ,  C08L23/04 ,  C08L2308/00

    摘要： The olefin polymer composition according to the invention comprises [I] an .alpha.-olefin/polyene copolymer-containing polymer in an amount of 0.005 to 99 by weight, said .alpha.-olefin/polyene copolymer-containing polymer comprising (i) an .alpha.-olefin/polyene copolymer and (ii) a polypropylene, and [II] a polymer of .alpha.-olefin having 3 or more carbon atoms in an amount of 1 to 99.995% by weight. The olefin polymer composition comprising the .alpha.-olefin/polyene copolymer-containing polymer [I] and the olefin polymer [II] has a high melt tension and an excellent moldability in an inflation molding, and further it can be molded into a large sized container, etc. by means of a blow molding or the like.

    摘要翻译： 根据本发明的烯烃聚合物组合物包含[I]含量为0.005至99重量％的含α-烯烃/多烯共聚物的聚合物，所述α-烯烃/含多烯共聚物的聚合物包含（i）α-烯烃 /多烯共聚物和（ii）聚丙烯，[II] 1〜99.995重量％的碳原子数3以上的α-烯烃的聚合物。 包含含α-烯烃/多烯共聚物的聚合物[I]和烯烃聚合物[II]的烯烃聚合物组合物在吹塑成型中具有高熔体张力和优异的成型性，并且还可以将其模塑成大尺寸的容器 等，通过吹塑成型等。

    Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition
    20.
    发明授权
    Propylene polymer, propylene block copolymer, process for preparing said polymer and said block copolymer, and propylene polymer composition 失效
    丙烯聚合物，丙烯嵌段共聚物，制备所述聚合物和所述嵌段共聚物的方法以及丙烯聚合物组合物

    公开(公告)号：US06274678B1

    公开(公告)日：2001-08-14

    申请号：US08351548

    申请日：1994-12-07

    申请人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

    发明人： Tetsunori Shinozaki ,  Kazumitsu Kawakita ,  Mamoru Kioka

    IPC分类号： C08F1006

    CPC分类号： C08F297/083 ,  C08F10/06 ,  C08F110/06 ,  C08F297/06 ,  C08F2500/15 ,  C08F2500/09 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/26

    摘要： Disclosed are a propylene block copolymer containing a crystalline polypropylene portion having a high crystallinity of a boiled heptane-insoluble component contained therein, a high stereoregularity and an extremely long mesochain, and a process for preparing said copolymer. Further disclosed is a propylene polymer composition comprising the above propylene block copolymer and at least one stabilizer selected from a phenol type stabilizer, an organophosphite type stabilizer, a thioether type stabilizer, a hindered amine type stabilizer and a metallic salt of higher aliphatic acid. The propylene block polymer of the invention is well-balanced between rigidity, heat resistance and moisture resistance, and can be favorably used for sheet, filament, injection molded product, blow molded product, etc. The propylene polymer composition of the invention has excellent properties of the propylene polymer or the propylene block copolymer, and moreover is excellent in heat stability during the molding stage, long-term heat stability and weathering resistance.

    摘要翻译： 公开了含有其中含有沸腾庚烷不溶性组分的高结晶度的结晶聚丙烯部分，高立体规则性和极长的间时针的丙烯嵌段共聚物以及制备所述共聚物的方法。 进一步公开的是包含上述丙烯嵌段共聚物和至少一种选自酚型稳定剂，有机亚磷酸酯型稳定剂，硫醚型稳定剂，受阻胺型稳定剂和高级脂肪酸的金属盐的稳定剂的丙烯聚合物组合物。 本发明的丙烯嵌段聚合物在刚性，耐热性和耐湿性之间的平衡性良好，可有利地用于片材，长丝，注塑产品，吹塑产品等。本发明的丙烯聚合物组合物具有优异的性能 的丙烯聚合物或丙烯嵌段共聚物，而且在成型阶段的热稳定性，长期的热稳定性和耐候性也优异。