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    METHOD OF CONVERTING FEEDS FROM RENEWABLE SOURCES IN CO-PROCESSING WITH A PETROLEUM FEED USING A CATALYST BASED ON NICKEL AND MOLYBDENUM
    11.
    发明申请
    METHOD OF CONVERTING FEEDS FROM RENEWABLE SOURCES IN CO-PROCESSING WITH A PETROLEUM FEED USING A CATALYST BASED ON NICKEL AND MOLYBDENUM 审中-公开
    使用基于镍和钼的催化剂与石油进料共同加工的可再生来源转化进料的方法

    公开(公告)号：US20120216450A1

    公开(公告)日：2012-08-30

    申请号：US13393050

    申请日：2010-07-27

    申请人： Nathalie Dupassieux ,  Antoine Daudin ,  Thierry Chapus

    发明人： Nathalie Dupassieux ,  Antoine Daudin ,  Thierry Chapus

    IPC分类号： C10L1/00

    CPC分类号： B01J23/88 ,  C10G3/44 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G3/54 ,  C10G45/04 ,  C10G45/08 ,  C10G45/50 ,  C10G65/04 ,  C10G65/08 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/202 ,  C10L1/04 ,  Y02P30/20

    摘要： The invention relates to a method of hydrotreatment in co-processing of petroleum feeds, in a mixture with at least one feed obtained from renewable sources, for producing fuel bases (kerosene and/or gas oil) having a sulphur content below 10 ppm, said method comprising the following stages: a) a first hydrotreatment stage in which said feed passes through at least one first fixed-bed catalytic zone comprising at least one bulk or supported catalyst comprising an active phase constituted by at least one group VIB element and at least one group VIII element, said elements being in the form of sulphide and the atomic ratio of the group VIII metal (or metals) to group VIB metal (or metals) being strictly greater than 0 and less than 0.095, b) a second hydrotreatment stage into which the effluent from the first hydrotreatment stage is sent directly, and in which said effluent passes through at least one second fixed-bed catalytic zone comprising at least one hydrotreatment catalyst.

    摘要翻译： 本发明涉及一种在与至少一种从可再生来源获得的进料的混合物中与石油进料共同加工中加氢处理的方法，用于生产具有低于10ppm的硫含量的燃料基质（煤油和/或瓦斯油），所述 方法包括以下阶段：a）第一加氢处理阶段，其中所述进料通过至少一个第一固定床催化区，所述至少一个第一固定床催化区包含至少一个本体或负载型催化剂，其包含由至少一组VIB元素构成的活性相和至少 一种VIII族元素，所述元素为硫化物形式，Ⅷ族金属（或金属）与VIB族金属（或金属）的原子比严格大于0且小于0.095，b）第二加氢处理阶段 来自第一加氢处理阶段的流出物直接送入其中，并且其中所述流出物通过包含至少一种加氢处理催化剂的至少一个第二固定床催化区。

    Process for the continuous hydrogenation of triglyceride containing raw materials using a nickel and molybdenum-based catalyst
    12.
    发明授权
    Process for the continuous hydrogenation of triglyceride containing raw materials using a nickel and molybdenum-based catalyst 有权
    使用镍和钼基催化剂连续氢化含甘油三酯的原料的方法

    公开(公告)号：US08962905B2

    公开(公告)日：2015-02-24

    申请号：US13226524

    申请日：2011-09-07

    申请人： Thierry Chapus ,  Nathalie Dupassieux ,  Antoine Daudin

    发明人： Thierry Chapus ,  Nathalie Dupassieux ,  Antoine Daudin

    IPC分类号： C10G3/00 ,  C10L1/08

    CPC分类号： C10G3/60 ,  C10G3/46 ,  C10G3/50 ,  C10G3/54 ,  C10G2300/1014 ,  C10G2300/4018 ,  C10G2300/802 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/08 ,  Y02E50/13 ,  Y02P30/20

    摘要： Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising at least one hydrogenation catalyst comprising an active phase constituted by a nickel and molybdenum element. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio.

    摘要翻译： 在具有串联排列的几个催化剂床的固定床反应器系统中连续氢化含甘油三酯的原料的方法，并包含至少一种包含由镍和钼元素构成的活性相的氢化催化剂。 原料进料，含氢气体和稀释剂在氢化条件下通过催化剂床一起通入。 将原料进料流以及含氢气流分成相等数量的不同部分流。 将它们分别传送到一个催化剂床，使得稀释剂与原料进料的重量比在所有催化剂床的入口处基本相同，不超过4:1。 要求保护的方法优选在低温下进行，并且由于低回收比而允许使用现有的单元。

    PROCESS FOR EBULLATED BED HYDROCONVERSION OF FEEDS OF BIO-RENEWABLE ORIGIN FOR THE PRODUCTION OF FUEL BASES
    14.
    发明申请
    PROCESS FOR EBULLATED BED HYDROCONVERSION OF FEEDS OF BIO-RENEWABLE ORIGIN FOR THE PRODUCTION OF FUEL BASES 有权
    用于生产燃料基础的生物可再生原料进料的EBULLED BED HYDROCONVERSION

    公开(公告)号：US20100325943A1

    公开(公告)日：2010-12-30

    申请号：US12282910

    申请日：2008-07-18

    申请人： Thierry Chapus ,  Alain Quignard ,  Nathalie Dupassieux ,  Antoine Daudin

    发明人： Thierry Chapus ,  Alain Quignard ,  Nathalie Dupassieux ,  Antoine Daudin

    IPC分类号： C10L1/19

    CPC分类号： C10G49/04 ,  C10G3/46 ,  C10G3/48 ,  C10G3/50 ,  C10G3/56 ,  C10G49/12 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/301 ,  C10G2300/4018 ,  C10G2400/06 ,  C10G2400/08 ,  Y02P30/20

    摘要： The invention concerns a process for hydrotreatment and/or hydroconversion of a feed of bio-renewable origin containing triglyceride and/or fatty acid structures and wherein the fatty chains contain in the range 8 to 25 carbon atoms, said process comprising the following steps: a) hydrotreatment and/or hydroconversion of said bio-renewable feed in an ebullated bed reactor in the presence of a granular catalyst comprising, on an amorphous support, at least one metal or compound of a metal having a hydrodehydrogenating function, to produce a first effluent; b) sending the effluent produced in step a) to a distillation zone from which a gaseous fraction and at least one distillate cut the end point of which is less than 400° C.

    摘要翻译： 本发明涉及含有甘油三酯和/或脂肪酸结构的生物可再生来源的进料的加氢处理和/或加氢转化的方法，其中所述脂肪链含有8至25个碳原子，所述方法包括以下步骤： ）在颗粒催化剂存在下在沸腾床反应器中加氢处理和/或加氢转化所述生物可再生进料，所述颗粒催化剂在无定形载体上包含至少一种具有脱氢功能的金属的金属或化合物，以产生第一流出物 ; b）将步骤a）中产生的流出物送到蒸馏区，蒸馏区中气态馏分和至少一个馏分切断其终点小于400℃。

    Process for the continuous hydrogenation of triglyceride containing raw materials
    15.
    发明授权
    Process for the continuous hydrogenation of triglyceride containing raw materials 有权
    含甘油三酯的原料连续氢化的方法

    公开(公告)号：US08197559B2

    公开(公告)日：2012-06-12

    申请号：US12717403

    申请日：2010-03-04

    申请人： Detlef Abe ,  Frank Eschenroder ,  David Laban ,  Hartmut Schutter ,  Laurent Bournay ,  Thierry Chapus ,  Nathalie Dupassieux

    发明人： Detlef Abe ,  Frank Eschenroder ,  David Laban ,  Hartmut Schutter ,  Laurent Bournay ,  Thierry Chapus ,  Nathalie Dupassieux

    IPC分类号： C10L1/19

    CPC分类号： C10G3/54 ,  C10G3/46 ,  C10G3/50 ,  C10G3/60 ,  C10G45/58 ,  C10G45/72 ,  C10G2300/1011 ,  C10G2300/4018 ,  C10G2300/802 ,  Y02P30/20

    摘要： Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising hydrogenation catalyst. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio. Further, a sufficient excess of hydrogen is used so that no valuable product is lost through decarb-reactions.

    摘要翻译： 在具有串联排列并包含氢化催化剂的几个催化剂床的固定床反应器系统中连续氢化含甘油三酯的原料的方法。 原料进料，含氢气体和稀释剂在氢化条件下通过催化剂床一起通入。 将原料进料流以及含氢气流分成相等数量的不同部分流。 将它们分别传送到一个催化剂床，使得稀释剂与原料进料的重量比在所有催化剂床的入口处基本相同，不超过4:1。 要求保护的方法优选在低温下进行，并且由于低回收比而允许使用现有的单元。 此外，使用足够过量的氢气，使得通过脱碳反应不会损失有价值的产物。

    PROCESS FOR THE CONTINUOUS HYDROGENATION OF TRIGLYCERIDE CONTAINING RAW MATERIALS
    16.
    发明申请
    PROCESS FOR THE CONTINUOUS HYDROGENATION OF TRIGLYCERIDE CONTAINING RAW MATERIALS 有权
    用于连续加氢含有原料的TRIGLYCERIDE的方法

    公开(公告)号：US20100242349A1

    公开(公告)日：2010-09-30

    申请号：US12717403

    申请日：2010-03-04

    申请人： Detlef Abe ,  Frank Eschenroder ,  David Laban ,  Hartmut Schutter ,  Laurent Bournay ,  Thierry Chapus ,  Nathalie Dupassieux

    发明人： Detlef Abe ,  Frank Eschenroder ,  David Laban ,  Hartmut Schutter ,  Laurent Bournay ,  Thierry Chapus ,  Nathalie Dupassieux

    IPC分类号： C10L1/19

    CPC分类号： C10G3/54 ,  C10G3/46 ,  C10G3/50 ,  C10G3/60 ,  C10G45/58 ,  C10G45/72 ,  C10G2300/1011 ,  C10G2300/4018 ,  C10G2300/802 ,  Y02P30/20

    摘要： Process for the continuous hydrogenation of triglyceride containing raw materials in a fixed bed reactor system having several catalyst beds arranged in series and comprising hydrogenation catalyst. The raw material feed, hydrogen containing gas and diluting agent are passed together through the catalyst beds at hydrogenation conditions. The raw material feed stream as well as the stream of hydrogen containing gas are divided into an equal number of different partial streams. These are each passed to one catalyst bed in such a manner that the weight ratio of diluting agent to raw material feed is essentially the same at the entrance of all catalyst beds and does not exceed 4:1. The claimed process is preferably conducted at low temperatures and allows the utilization of existing units due to the low recycle ratio. Further, a sufficient excess of hydrogen is used so that no valuable product is lost through decarb-reactions.

    摘要翻译： 在具有串联排列并包含氢化催化剂的几个催化剂床的固定床反应器系统中连续氢化含甘油三酯的原料的方法。 原料进料，含氢气体和稀释剂在氢化条件下通过催化剂床一起通入。 原料进料流以及含氢气流被分成等量的不同的部分流。 将它们分别传送到一个催化剂床，使得稀释剂与原料进料的重量比在所有催化剂床的入口处基本相同，不超过4:1。 要求保护的方法优选在低温下进行，并且由于低回收比而允许使用现有的单元。 此外，使用足够过量的氢气，使得通过脱碳反应不会损失有价值的产物。

    Process and apparatus employing a plurality of catalytic beds in series for the production of low sulphur gas oil
    17.
    发明授权
    Process and apparatus employing a plurality of catalytic beds in series for the production of low sulphur gas oil 失效
    使用多个催化床串联制备低硫瓦斯油的方法和装置

    公开(公告)号：US06855246B2

    公开(公告)日：2005-02-15

    申请号：US09780418

    申请日：2001-02-12

    申请人： Thierry Chapus ,  Frédéric Morel

    发明人： Thierry Chapus ,  Frédéric Morel

    IPC分类号： C10G45/08 ,  C10G65/04 ,  C10G67/02 ,  C10G45/04

    CPC分类号： C10G65/04

    摘要： A process for hydrotreating gas oil comprises: a first gas oil desulfurization step carried out in a first catalytic zone comprising a desulfurization catalyst; at least partial elimination of the hydrogen sulphide formed at the end of the first gas oil desulfurization step; one or more additional desulfurization steps carried out in one or more catalytic zones comprising a desulfurization catalyst. The distribution of the catalyst in the different zones can be selected so as to maximise the catalytic activity, and thus minimize the volume of catalyst required for a unit of a given capacity operating at fixed operating temperature and pressure, so as to obtain an intensely desulfurized gas oil.

    摘要翻译： 一种加氢处理瓦斯油的方法包括：在包含脱硫催化剂的第一催化区中进行的第一瓦斯油脱硫步骤; 至少部分消除在第一瓦斯油脱硫步骤结束时形成的硫化氢; 在包含脱硫催化剂的一个或多个催化区中进行一个或多个另外的脱硫步骤。 可以选择催化剂在不同区域中的分布，以使催化活性最大化，从而最小化在固定操作温度和压力下操作的给定容量单位所需的催化剂体积，从而获得强烈脱硫 瓦斯油。

    Process for the production of catalytic cracking gasoline with a low sulphur content
    18.
    发明授权
    Process for the production of catalytic cracking gasoline with a low sulphur content 失效
    用于生产硫含量低的催化裂化汽油的方法

    公开(公告)号：US6007704A

    公开(公告)日：1999-12-28

    申请号：US936101

    申请日：1997-09-23

    申请人： Thierry Chapus ,  Blaise Didillon ,  Christian Marcilly ,  Charles Cameron

    发明人： Thierry Chapus ,  Blaise Didillon ,  Christian Marcilly ,  Charles Cameron

    IPC分类号： B01J23/42 ,  B01J23/85 ,  B01J31/12 ,  C10G27/00 ,  C10G29/06 ,  C10G45/06 ,  C10G45/10 ,  C10G45/40 ,  C10G65/00 ,  C10G65/06 ,  C10G67/00 ,  C10G67/04 ,  C10G67/12 ,  C10G67/16

    CPC分类号： C10G65/00 ,  C10G2400/02

    摘要： Catalytic cracking gaseolines are treated by: (a) fractionating the raw gasoline cut into two cuts; (b) optional selective diene hydrodenation of the light cut, then mild hydrotreatment and stripping; (c) sweetening the light cut which is conducted before the mild hydrotreatment step by contact with a supported catalyst containing 0.1-1% by weight of palladium, or after the mild hydrotreatment step and which is then an extractive sweetening step, or with a catalyst having an alkaline base optionally incorporated and also an oxidizing agent. The heavy gaseoline fraction is optionally desilphurized in a hydrotreatment unit. The desulpurized and sweetened light gaesoline can be added to the gasoline pool either directly or mixed with the desulphurized heavy gaseoline cut.

    摘要翻译： 催化裂化球菌是通过以下方式处理的：（a）将原油汽油分馏成两个馏分; （b）轻馏分选择性二烯烃加氢反应，然后轻度加氢处理和汽提; （c）通过与含有0.1-1重量％钯的负载催化剂接触，或在轻度加氢处理步骤之后，然后进行萃取甜化步骤，或用催化剂，使在温和加氢处理步骤之前进行的轻馏分变甜 具有任选地并入的碱性碱，还有氧化剂。 任选地在加氢处理装置中将沉淀的gaseoline馏分去溶解。 脱硫和甜化的光泽石可以直接添加到汽油池中或与脱硫的重质gaseoline切割混合。