摘要:
The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.
摘要翻译:本发明涉及具有重复单元A,B和D的线性官能聚合物。单元A表示-CH 2 - ,单元B表示,单元D表示其中R 1表示极性官能团。 每个B单元,每个D单元和每个B和D单元分开至少四个A单元。 值y表示B个单位的总数,并且是大于或等于1的整数.D单位的总数由h表示,并且是大于或等于0的整数。x表示A的总数 单位,并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数: < 数学溢出=“滚动”> mi> j mi> = mo> y mi> + mo > h mi> mrow> x mi> + mo> y mi> + mo> mrow> mrow> mrow> mrow> mrow> mrow> mrow> 本发明还涉及通过共聚第一极性取代单体和第二非极性未取代单体来制备这种线性官能聚合物的方法。
摘要:
The invention is directed towards substantially linear copolymers formed using a metal complex having the formula LMX1X2. L is a bidentate nitrogen-containing ligand with more than 2 nitrogens. M is copper, silver, or gold. X1 and X2 are independently selected from the group consisting of halogens, hydride, triflate, acetate, trifluoroacetate, perfluorotetraphenylborate, tetrafluoroborate, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, and any other moiety into which a monomer can insert. Such metal complexes have a tetrahedral or pseudo-tetrahedral structure and may be used with an activating cocatalyst. The invention is derived from polymers and copolymers using such catalyst compositions, especially copolymers having segments formed from olefinic monomers and monomers having at least one hydrocarbyl polar functional group.
摘要翻译:本发明涉及使用具有式LMX1X2的金属络合物形成的基本上线性的共聚物。 L是具有超过2个氮的二齿含氮配体。 M是铜,银或金。 X 1和X 2独立地选自卤素,氢化物,三氟甲磺酸酯,乙酸酯,三氟乙酸酯,全氟四苯基硼酸盐,四氟硼酸盐,C1至C12烷基,C1至C12烷氧基,C3至C12环烷基,C3至C12环烷氧基,芳基和任何其他 单体可以插入的部分。 这种金属络合物具有四面体或假四面体结构,并且可以与活化助催化剂一起使用。 本发明来自使用这种催化剂组合物的聚合物和共聚物,特别是具有由烯属单体形成的链段和具有至少一个烃基极性官能团的单体的共聚物。
摘要:
The present invention relates to homopolymers and copolymers of N-(4-sulfoalkyl)N-methyldiallyl ammonium betaines which are useful as aqueous viscosification agents.
摘要:
The present invention relates to a process for the formation of water soluble copolymers of acrylamide and alkyl poly(etheroxy)acrylate which are finished by a dialysis process and are excellent viscosification agents. Wherein the process includes the free radical copolymerization of acrylamide monomer and alkyl poly(etheroxy)acrylate monomer in an aqueous medium under nitrogen conditions in the presence of free radical initiator at a sufficient temperature and for a sufficient time to effect copolymerization.
摘要:
The present invention relates to materials which reduce the filtration of fluid into permeable earth formations during cementing processes in the drilling and completing of subterranean wells, particularly wells for the recovery of petroleum resources.Petroleum well cementing is the process of mixing a slurry of cement, water, and other additives and pumping it down through steel casing to critical points in the oil well annulus around the casing or in the open hole below the casing string. The primary functions of the cementing process are to restrict fluid movement between geological formations and to bond and support the casing. In addition the cement aids in protecting the casing from corrosion, preventing blowouts by quickly sealing formations, protecting the casing from shock loads in drilling deeper wells, and sealing off lost circulation or thief zones.A common problem in petroleum well cementing is the flow of liquid from the cement slurry into porous earth formations in contact with the cement. This fluid loss is undesirable since it can result in dehydration of the cement slurry, and it causes thick filter cakes of cement solids which can plug the well bore. The fluid lost can damage sensitive formations. Cement fluid loss is particularly a problem in the process known as squeeze cementing.There is a requirement, therefore, for materials which, when added to the cement formulation, reduce the loss of fluid from the slurry to porous formations.
摘要:
Specific catalyst modifiers, namely unsaturated diazobicyclo compounds in association with anionic initiators such as organo-lithium compounds are utilized during the polymerization of conjugated diene monomers and comonomers therewith to unexpectantly yield polymers or copolymers having a broad molecular weight distribution, a significant vinyl microstructure, and good processability.
摘要:
Polyphosphazene polymers are prepared which contain units represented by the formulas: ##STR1## wherein X is ##STR2## in which R is alkylene radical containing from 0 to 10 carbon atoms, R' is hydrogen or alkyl containing from 1 to 10 carbon atoms and n is an integer of from 0 to 10; wherein X' is X or is selected from the group consisting of substituted or unsubstituted alkoxy, aryloxy, amino and mercapto groups and wherein 20.ltoreq. (a+b+c).ltoreq.50,000 per polymer.The polymers of the invention can be utilized to form films and may also be utilized in applications such as moldings, coatings, foams and the like.
摘要翻译:制备含有由下式表示的单元的聚磷腈聚合物:其中X为其中R为含有0至10个碳原子的亚烷基,R'为氢或含有1至10个碳原子的烷基和n 是从0到10的整数; 其中X'是X或选自取代或未取代的烷氧基,芳氧基,氨基和巯基,并且其中每个聚合物20(a + b + c)= 50,000。 本发明的聚合物可用于形成薄膜,也可用于诸如模制品,涂料,泡沫等的应用中。
摘要:
The process and catalyst system disclosed herein comprises the polymerization of a conjugated diene such as 1,3-butadiene in hydrocarbon solution in the presence of a new catalyst composition comprising:(a) a dihydrocarbyl magnesium compound of 1-10 carbon atoms, preferably a dialkyl magnesium having 3-8 carbon atoms in each alkyl group, and(b) an alkali metal compound of the formula R(SM).sub.n, R'.sub.2 NM, R'NHM or RC.tbd.CM, wherein R is a hydrocarbyl radical of 1-10 carbon atoms, preferably alkyl, n is 1, 2 or 3, M is Li, Na or K, and R' is a hydrocarbyl radical of 1-10 carbon atoms or an acyl radical of 1-10 carbon atoms.This process is particularly advantageous in that the polymer product can be controlled to have only a relatively small amount of 1,2 structure in accordance with the polymerization temperature. For example, at 125.degree. C. with Li compounds, the product generally has a 1,2 content of 12.6% or less; at 50.degree. C., 10.6% or less; and at 25.degree. C., 7% or less. Where 1,2 contents of 17-25% are desired, these may be obtained by using the Na compounds, and when 1,2 contents of 37-54% are desired, these may be obtained by using K compounds. Where even higher 1,2 contents are desired, they may be obtained by using an amine, such as tetramethylethylenediamine, as an additional catalyst component.
摘要:
The graft copolymer is the reaction of a backbone polymer having allylic chloride groups therein and monomers forming a pendant graft polymer in the presence of a coinitiator. The monomers have the formula ##STR1## wherein R is an alkyl group having from 1 to 15 carbon atoms, a cycloalkyl group having from 4 to 15 carbon atoms, an aryl group having from 6 to 15 carbon atoms, combinations thereof, or hydrogen. The amount of the pendant graft polymer portion by weight ranges from about 0.5 percent to about 90 percent based upon the total weight of the total graft copolymer with the pendant graft polymer being substituted on the polymer backbone in lieu of the chlorine atom of the allylic chloride group. The backbone polymer is selected from the class consisting of poly(vinyl chloride),polychloroprene, and unsaturated elastomers, the unsaturated elastomers being selected from the class consisting of chlorinated polydienes having repeating units containing from 4 to 12 carbon atoms, polychloroprene, chlorinated butyl rubber, chlorinated EPDM, chlorinated natural rubber, chlorinated styrenebutadiene rubber, and blends thereof.