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11.发明授权Method for the preparation of stable aqueous dispersions of polymer beads and the use of these dispersions in photographic elements 失效用于制备聚合物珠的稳定水分散体的方法以及这些分散体在照相元件中的应用
公开(公告)号：US4614708A
公开(公告)日：1986-09-30
申请号：US580272
申请日：1984-02-16
IPC分类号： G03C1/32 , C08F2/00 , C08F2/16 , C08F2/18 , C08F257/02 , C08F267/02 , C08F291/00 , G03C1/825 , G03C1/89 , G03C1/95 , G03C1/84 , G03C1/02
CPC分类号： C08F257/02 , C08F267/02 , G03C1/825 , G03C1/89 , G03C1/95 , Y10S430/132 , Y10S430/151 , Y10S430/162
摘要： Method for the preparation of stable aqueous dispersions of finely divided solid spherical polymer beads having an average particle size between about 0.5 and about 5 .mu.m and having a glass transition temperature of at least 40.degree. C. by dissolving in an aqueous solvent mixture at least one .alpha.,.beta.-ethylenically unsaturated monomer capable of forming a polymer that is soluble in the monomer(s) present in said aqueous solvent mixture but which is insoluble in said aqueous solvent mixture, a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution to a temperature from 50.degree. C. to the reflux temperature thereof with stirring so as to form said polymer beads. The polymer beads can be used in an antifriction surface layer, an antihalation surface layer, an antistatic surface layer, or in a protective surface layer of a photographic element or in a top layer of a drafting film containing a photosensitive layer.
摘要翻译： 制备平均粒径为约0.5至约5μm的玻璃化转变温度为至少40℃的细分固体球形聚合物珠粒的稳定水分散体的方法，通过将至少 能够形成可溶于所述水性溶剂混合物中存在但不溶于所述水性溶剂混合物中的单体的聚合物的一种α，β-烯属不饱和单体，自由基形成聚合引发剂和接枝 - 含有亲水基团的可聚合聚合物，在搅拌下将溶液加热至50℃至其回流温度，以形成所述聚合物珠粒。 聚合物珠可以用于减摩表面层，防光晕表面层，抗静电表面层，或照相元件的保护表面层或含有感光层的牵伸膜的顶层中。
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12.发明授权
公开(公告)号：US4186010A
公开(公告)日：1980-01-29
申请号：US567109
申请日：1975-04-11
IPC分类号： G03C1/34 , C08F246/00 , G03C1/053 , G03C5/30 , G03C1/72
CPC分类号： G03C1/053 , Y10S430/164
摘要： A photographic element is described comprising an emulsion layer of low gelatin to silver halide ratio, the emulsion comprising a polymeric compound containing recurring units with ketoiminoguanidinium groups in the side chain to reduce formation of pressure marks.
摘要翻译： 描述了一种照相元件，其包含低明胶与卤化银比例的乳剂层，该乳液包含在侧链中含有酮亚胺基团的重复单元的聚合物，以减少形成压痕。
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13.发明授权
公开(公告)号：US5273951A
公开(公告)日：1993-12-28
申请号：US899855
申请日：1992-06-17
CPC分类号： B41M5/44 , B41M2205/02 , B41M2205/30 , B41M5/443 , Y10S428/913 , Y10S428/914 , Y10T428/31663
摘要： Dye-donor element for use according to thermal dye sublimation transfer comprising a support having on one side a dye layer and on the other side a slipping layer, characterized in that said slipping layer comprises the cured product of a moisture-curable binder composition prepared by mixing the following components (A) and (B):(A) 30 to 99 parts by weight of at least one copolymer of olefinically unsaturated compounds having a weight-average molecular weight [Mw] of at least 1500 and containing chemically incorporated moieties capable of undergoing an addition reaction with amino groups, and(B) 1 to 70 parts by weight of organic substances containing blocked amino groups from which substances under the influence of moisture compounds having free primary and/or secondary amino groups are formed,wherein i) the copolymers of component (A) contain intramolecularly bound carboxylic anhydride moieties, with the anhydride equivalent weight of the copolymers being from 196 to 9800 and ii) the binder composition contains from 0.25 to 10 anhydride moieties for each blocked amino group.
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公开(公告)号：US5270354A
公开(公告)日：1993-12-14
申请号：US783350
申请日：1991-10-28
IPC分类号： C08J3/05 , C08J3/12 , C08J3/215 , G03C1/005 , G03C1/04 , G03C1/835 , G03F7/027 , G03F7/038 , C08J3/02 , C08K3/20 , C08L23/00
摘要： Method of making aqueous dispersions of hydrophobic polymer particles loaded with at least one hydrophobic compound, comprising the consecutive steps of dissolving said at least one hydrophobic compound in a water-immiscible organic solvent medium, dispersing the solution obtained in water or in an aqueous medium to form a dispersed phase having an average droplet size lower than 5 .mu.m, mixing the resulting dispersion with a dispersion of hydrophobic polymer particles in water or in an aqueous medium, said hydrophobic polymer particles being swellable in said water-immiscible solvent medium and having an average particle diameter ranging from 0.02 to 5.0 .mu.m, stirring the mixture obtained to allow said hydrophobic compound to associate with said hydrophobic polymer particles, and removing said water-immiscible organic solvent medium by evaporation.
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公开(公告)号：US5252445A
公开(公告)日：1993-10-12
申请号：US730479
申请日：1991-07-16
CPC分类号： C08F8/14 , C08F291/00 , G03C1/89 , G03C1/95 , C08F2810/20 , Y10S428/913 , Y10S430/151 , Y10T428/31786 , Y10T428/31797
摘要： Method of preparing solvent-resistant polymer beads sizing 0.5-5 pm and having a glass transition temperature of at least 40.degree. C. by dissolving in a solvent mixture of water and water-miscible polar organic solvent an Alpha, Beta-ethylenically unsaturated monomer (1) capable of forming a polymer that is soluble in the monomer(s) present in said solvent mixture but which is insoluble in said solvent mixture, a monomer (2) carrying COOH group(s), a monomer (3) carrying halogen atom(s), a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution obtained to a temperature from 50.degree. C. to the reflux temperature thereof with stirring to form said beads, converting said COOH group(s) by reaction with a hydroxide into a carboxylic acid salt group, and causing said carboxylic acid salt group to react with said halogen atom to form ester cross-linkages. The beads can be used as spacing agents in a sheet or web material.
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公开(公告)号：US4828927A
公开(公告)日：1989-05-09
申请号：US40822
申请日：1987-04-21
CPC分类号： G03C1/895 , C09K3/16 , Y10S428/913 , Y10T428/31786 , Y10T428/31797
摘要： A sheet or web comprising a substrate which is composed of or coated with a hydrophobic resin and carries an antistatic layer, characterized in that the antistatic layer consists essentially of a blockcopolyetherester of dibasic carboxylic acid(s) esterified with ethylene glycol and with a polyoxyethylene glycol having an average molecular weight in the range 1,000 to 10,000, at least 20% by weight of such blockcopolyetherester being constituted by polyoxyethylene-ester chain parts.
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17.发明授权Type of polymer latex and its use as plasticizer in a photographic material 失效聚合物胶乳的类型及其在照相材料中的增塑剂的用途
公开(公告)号：US5478710A
公开(公告)日：1995-12-26
申请号：US289638
申请日：1994-08-12
CPC分类号： G03C1/053
摘要： New types of polymer latices and their use in photographic materials are disclosed. They are obtained by subjecting to radical emulsion polymerisation one or more radical-polymerisable monomers, whose emulsifier-free homopolymers or copolymers possess a glass transition temperature below 65.degree. C., preferably below 30.degree. C., in the presence of a water-soluble polymer of a particular chemical formula.These new types of latices are preferably used in graphic arts contact materials, e.g. daylight materials. They can be used in relative high amounts thus improving dimensional stability without deteriorating the scratch resistance too strongly.A preferred radical-polymerisable monomer mixture comprises n.-butyl acrylate, methyl methacrylate and acrylic acid.
摘要翻译： 公开了新型聚合物胶乳及其在照相材料中的用途。 它们是通过使自由基乳液聚合一种或多种可自由基聚合的单体获得的，其中无乳化剂的均聚物或共聚物的玻璃化转变温度低于65℃，优选低于30℃，在水溶性 具体化学式的聚合物。 这些新类型的胶乳优选用于图形艺术接触材料，例如。 日光材料。 它们可以以相对高的量使用，从而提高尺寸稳定性，而不会太强烈地劣化耐擦伤性。 优选的可自由基聚合的单体混合物包括丙烯酸正丁酯，甲基丙烯酸甲酯和丙烯酸。
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18.发明授权Dye-image receiving element for use according to thermal dye sublimation transfer 失效根据热染料升华转印使用的染料图像接收元件
公开(公告)号：US5418110A
公开(公告)日：1995-05-23
申请号：US926288
申请日：1992-08-10
CPC分类号： B41M5/5254
摘要： Dye-image receiving element for use according to thermal dye sublimation transfer comprising a support having thereon a dye-image receiving layer and optionally a toplayer wherein the dye-image receiving layer or the toplayer comprises the cured product of a moisture-curable binder composition prepared by mixing the following components (A) and (B):(A) 30 to 99 parts by weight of at least one copolymer of olefinically unsaturated compounds having a weight-average molecular weight [Mw] of at least 1500 and containing chemically incorporated moieties capable of undergoing an addition reaction with amino groups, and(B) 1 to 70 parts by weight of organic substances containing blocked amino groups from which substances under the influence of moisture compounds having free primary and/or secondary amino groups are formed,wherein i) the copolymers of component (A) contain intramolecularly bound carboxylic anhydride moieties, with the anhydride equivalent weight of the copolymers being from 196 to 9800 and ii) the binder composition contains from 0.25 to 10 anhydride moieties for each blocked amino group.
摘要翻译： 根据热染料升华转印使用的染料图像接收元件，包括其上具有染料影像接收层的支持物和任选的游play者，其中染料影像接收层或对峙者包含制备的湿气固化性粘合剂组合物的固化产物 通过混合以下组分（A）和（B）：（A）30至99重量份的至少一种重均分子量[Mw]至少为1500的烯属不饱和化合物的共聚物，并含有化学结合的部分 能够与氨基进行加成反应，和（B）1〜70重量份含有封闭氨基的有机物质，其中形成具有游离的伯和/或仲氨基的水分化合物影响的物质，其中i ）组分（A）的共聚物含有分子内结合的羧酸酐部分，共聚物的酸酐当量为 196至9800，和ii）粘合剂组合物每个封闭的氨基含有0.25至10个酸酐部分。
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公开(公告)号：US5364752A
公开(公告)日：1994-11-15
申请号：US9731
申请日：1993-08-19
CPC分类号： G03C1/89
摘要： A recording material comprising a sheet, ribbon or web support and a hydrophilic colloid binder layer incorporating an ionic copolymer in the form of dispersed particulate material providing to said material an antistatic character, characterized in that said ionic copolymer is a cross-linked addition copolymer wherein at least 30 mole % of its recurring units are recurrring units containing a sulphonic acid salt group that has been obtained via a reaction of propane sultone or butane sultone with carboxylate salt groups present originally in recurring units of said copolymer.
摘要翻译： 一种记录材料，包括片材，带或网状物载体和亲水胶体粘合剂层，其中以分散的颗粒材料形式提供离子共聚物形式提供抗静电特性，其特征在于所述离子共聚物是交联加成共聚物，其中 其重复单元的至少30摩尔％是含有通过丙磺酸内酯或丁烷磺内酯与原本以所述共聚物的重复单元存在的羧酸盐基团反应获得的磺酸盐基团的复制单元。
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20.发明授权Method for the preparation of stable aqueous dispersions of polymer beads and the use of these dispersions in photographic elements 失效用于制备聚合物珠的稳定水分散体的方法以及这些分散体在照相元件中的用途
公开(公告)号：US4861818A
公开(公告)日：1989-08-29
申请号：US911465
申请日：1986-09-25
IPC分类号： G03C1/32 , C08F2/00 , C08F2/16 , C08F2/18 , C08F257/02 , C08F267/02 , C08F291/00 , G03C1/825 , G03C1/89 , G03C1/95
CPC分类号： C08F257/02 , C08F267/02 , G03C1/825 , G03C1/89 , G03C1/95 , Y10S430/132 , Y10S430/151 , Y10S430/162
摘要： Method for the preparation of stable aqueous dispersions of finely divided solid spherical polymer beads having an average particle size between about 0.5 and about 5 .mu.m and having a glass transition temperature of at least 40.degree. C. by dissolving in an aqueous solvent mixture at least one .alpha.,.beta.-ethylenically unsaturated monomer capable of forming a polymer that is soluble in the monomer(s) present in said aqueous solvent mixture but which is insoluble in said aqueous solvent mixture, a free radical-forming polymerization initiator, and a graft-polymerizable polymer containing hydrophilic groups, heating the solution to a temperature from 50.degree. C. to the reflux temperature thereof with stirring so as to form said polymer beads. The polymer beads can be used in an antifriction surface layer, an antihalation surface layer, an antistatic surface layer, or in a protective surface layer of a photographic element or in a top layer of a drafting film containing a photosensitive layer.
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