Abstract:
A method for repairing and restoring the functionality of equipment subjected to internal corrosion during its operation at high or medium pressure in a plant for the synthesis of urea. The method includes the cleaning of the corroded area, the formation of suitable supporting and/or holding surfaces for the placement of a new metallic lining, the formation of a new anticorrosive sealed off lining, obtained by positioning and welding flat elements and metallic plates which are suitably shaped and placed next to each other to become adapted to the internal profile of the equipment. The spaces and interstices below this new lining all communicate with at least one weep-hole present in the pressure resistant body. The entire repair is carried out through the manhole of the equipment and enables the restoring of its functionality for times similar to the normal duration of corresponding newly constructed equipment.
Abstract:
Catalytic system for dehydrogenating ethylbenzene to styrene, containing chromium oxide, tin oxide, at least one oxide of an alkaline metal (M) and an alumina carrier, in delta or theta phase or in a mixture of delta+theta or theta+alpha or delta+theta+alpha phases, modified with silica, and characterized in that:the chromium, expressed as Cr.sub.2 O.sub.3, is in a quantity of between 6 and 30% by weight;the tin, expressed as SnO, is in a quantity of between 0.1 and 3.5% by weight;the alkaline metal, expressed as M.sub.2 O, is in a quantity of between 0.4 and 3% by weight,the silica is in a quantity of between 0.08 and 3% by weight, the complement to 100 being alumina.
Abstract translation:用于将乙苯脱氢为含有氧化铬,氧化锡,至少一种碱金属(M)和氧化铝载体的氧化物的苯乙烯在δ或θ相中或在δ+θ或θ+α或δ的混合物中的催化体系 +θ+α相,用二氧化硅改性,其特征在于:以Cr 2 O 3表示的铬的量为6至30重量%; 以SnO表示的锡的量为0.1至3.5重量%; 以M 2 O表示的碱金属的量为0.4-3重量%,二氧化硅的量为0.08-3重量%,补体为100为氧化铝。
Abstract:
Improved yield process for urea synthesis by starting from ammonia and carbon dioxide, comprising a reaction zone under high pressure and temperature conditions, a section wherein a portion of unreacted ammonia and carbon dioxide are stripped and recycled to the reactor, which section operates under substantially the same reactor pressure, and a subsequent section, operating under medium and/or low pressure conditions, for urea purification and simultaneous recovery of residual carbon dioxide and a portion of residual ammonia contained in the effluent stream from the stripping section, as an aqueous solution of ammonium carbamate, in which said aqueous ammonium carbamate solution is either totally or partially fed to said stripping section. Said process makes it possible a conversion of carbon dioxide into urea to be obtained in the reactor which is higher than 70%.
Abstract:
An integrated process for the simultaneous production of alkyl tert-butyl ethers and 1-butene, comprising feeding a C.sub.4 hydrocarbon stream to an etherification unit and recycling the remaining stream to the same unit after possible separation of the 1-butene and treatment in an isomerization section to convert the remaining butenes into isobutene, a molecular sieve separation unit operating with the hydrocarbons in the vapour phase being incorporated into the cycle.
Abstract:
Mono-alkadienyl alkyl ethers and di-alkadienyl alkyl ethers are prepared by telomerization of a conjugated diene, by causing said conjugated diene to react with an aliphatic alcohol or an aliphatic diol respectively, by operating in an aqueous/organic biphasic liquid system, in the presence of a catalytic system formed by:(a) a palladium salt or complex;(b) an alkyl-, alkylcycloalkyl-, or alkylarylphosphine ligand, bearing an acidic or neutral hydrophylic moiety, having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, x and y are as defined in the disclosure; and(c) an either inorganic or organic base.
Abstract:
The process for activating a catalytic composition for paraffin dehydrogenation containing gallium, alumina, possibly silica and/or one or more alkaline or alkaline-earth metals, comprises thermal activation in air followed by post-activation effected by the following stages:oxidation with air and/or oxygen or a mixture containing oxygen and inert gas;purging with inert gas;reduction with hydrogen or a mixture of hydrogen and an inert or reducing gas.The catalytic composition activated by said process contains gallium, alumina, silica and possibly one or more alkaline or alkaline-earth metals, the alumina being in .delta. or .theta. phase or in .delta.+.theta. or .delta.+.theta.+.alpha. phase mixture.
Abstract:
A crystalline, porous, synthetic material is disclosed, together with its related preparation process.Such a material of zeolitic character, containing silicon, titanium and aluminum oxides, corresponds, in its calcined and anhydrous state, to the following empirical formula:p HAlO.sub.2.q TiO.sub.2.SiO.sub.2wherein p has a value greater than zero and lower than or equal to 0.050, q has a value greater than zero and lower than or equal to 0.025, and the H.sup.+ of HAlO.sub.2 can be at least partly replaceable or replaced by cations.
Abstract:
A catalyst system for the selective production of isoprenylalkylethers from isoprene is described, characterized by satisfying the following empirical formulaPdLxL.sup.' ywhereL is a phosphorated binder in the form of an organic derivative of trivalent phosphorus of type R3P or R2P[CH(R)]zPR2, in which the substituents R, which can be identical or different, are either hydrogen atoms or alkyl, cycloalkyl, aryl, alkoxy, aryloxy, arylthio or arylalkyl groups, and in which z is a whole number between 1 and 5;L.sup.' is an easily displaceable binder chosen from dienes, olefins, anhydrides, diketones and nitriles;x is a whole number between 0 and 4 and y is a whole number between 0 and 3,in which system excess phosphorated compounds of R3P or R2P[CH(R)]zPR2 type may or may not be present.
Abstract:
A special system is described and illustrated for supporting and easily maneuvering, without the danger of breakage, a set of graphite anodes used for extracting the lead from the electrolyte in electrochemical processes for recovering the metals contained in spent accumulators.
Abstract:
A device for continuously delivering a proportionately constant fire-fighting solution which comprises an extinguisher foam mixed with variable flow rates of fire fighting water. The device comprises a motor, which is a volumetric screw pump driven in reverse by the hydraulic pressure of the fire fighting water network. This hydraulic motor is mechanically connected to one or more volumetric pumps which proportionally meter the fire fighting foam extinguisher liquid into the network water.