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    Polymeric ammonium compounds with a silica-type backbone, processes for their preparation and use
    11.
    发明授权
    Polymeric ammonium compounds with a silica-type backbone, processes for their preparation and use 失效
    具有二氧化硅型骨架的聚合铵化合物，其制备和使用方法

    公开(公告)号：US4410669A

    公开(公告)日：1983-10-18

    申请号：US376881

    申请日：1982-05-10

    Applicant: Peter Panster ,  Peter Kleinschmit

    Inventor： Peter Panster ,  Peter Kleinschmit

    IPC: B01J41/12 ,  B01J31/00 ,  B01J41/08 ,  C07F7/08 ,  C07F7/18 ,  C08G77/00 ,  C08G77/26 ,  C08G77/28 ,  C08G77/38 ,  C08G77/48 ,  C08G77/58 ,  C08F283/00

    CPC classification number: B01J41/08 ,  C07F7/0838 ,  C07F7/0889 ,  C07F7/1836 ,  C08G77/26 ,  C08G77/38 ,  C08G77/48

    Abstract: Polymeric ammonium compounds are disclosed which have a silica-type backbone, comprised of units having the formula: ##STR1## in which R.sup.1 and R.sup.2 represent a group ##STR2## in which R.sup.5 is an alkylene grouping and the free valencies of the oxygen atoms are saturated by silicon atoms of further groups (2), if appropriate with incroporation of crosslinking agents, R.sup.3 and R.sup.4 have the meaning of R.sup.1 and R.sup.2 or represent hydrogen, an alkyl group, cycloalkyl group or the benzyl group, X represents a 1- to 3-valent anion of a protonic acid which forms stable salts with amine bases and x can be a number from 1 to 3. Also disclosed are processes for preparing the polymeric ammonium compounds and to the use of these materials as ion exchange materials.

    Abstract translation: 公开了具有二氧化硅型主链的聚合铵化合物，其由具有下式的单元组成：其中R 1和R 2表示基团，其中R 5是亚烷基，而自由基 氧原子的价态由另外的基团（2）的硅原子饱和，如果合适的话，R3和R4具有R1和R2的意义，或代表氢，烷基，环烷基或苄基， X表示与胺碱形成稳定盐的质子酸的1至3价阴离子，x可以是1至3的数。还公开了制备聚合铵化合物的方法以及将这些材料用作 离子交换材料。

    Magnesium aluminate anion exchangers
    13.
    发明授权
    Magnesium aluminate anion exchangers 失效
    铝酸镁阴离子交换剂

    公开(公告)号：US4392979A

    公开(公告)日：1983-07-12

    申请号：US360716

    申请日：1982-03-22

    Applicant: John M. Lee ,  William C. Bauman

    Inventor： John M. Lee ,  William C. Bauman

    IPC: B01J41/08 ,  B01J47/00 ,  C01B25/45 ,  C01D3/14 ,  C01F7/00 ,  C01G37/14 ,  B01J41/02 ,  C01F7/02

    CPC classification number: C01B25/45 ,  B01J41/08 ,  B01J47/006 ,  C01D3/145 ,  C01F7/002 ,  C01G37/14 ,  C01P2002/22

    Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 Owhere A and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2,with (va)+(vb) equal to 2, andwith m being a value of zero or more.

    Abstract translation: 显示了新型结晶铝酸盐的制备和用途，其通常符合经验式MgAavZbv.nAl（OH）3·6H2O，其中A和Z代表负价离子或选自羟基，卤化物，无机酸和有机物的基团 酸，n为约1至约2的值，v为1,2或3的负数，a和b各自具有0至2的值，其中（va）+（vb）等于2 ，m为0以上。

    Magnesium aluminate anion exchangers
    14.
    发明授权
    Magnesium aluminate anion exchangers 失效
    铝酸镁阴离子交换剂

    公开(公告)号：US4392961A

    公开(公告)日：1983-07-12

    申请号：US360717

    申请日：1982-03-22

    Applicant: John M. Lee ,  William C. Bauman

    Inventor： John M. Lee ,  William C. Bauman

    IPC: B01J41/08 ,  B01J47/00 ,  C01B25/45 ,  C01D3/14 ,  C01F7/00 ,  C01G37/14 ,  B01J41/02

    CPC classification number: C01F7/002 ,  B01J41/08 ,  B01J47/006 ,  C01B25/45 ,  C01D3/145 ,  C01G37/14 ,  C01P2002/22

    Abstract: Preparations and uses are shown for novel crystalline aluminates which conform generally to the empirical formulaMgA.sub.a.sup.v Z.sub.b.sup.v.nAl(OH).sub.3.mH.sub.2 OwhereinA and Z represent negative-valence ions or radicals selected from the group comprising hydroxyl, halide, inorganic acid, and organic acid,n is a value of from about 1 to about 2,v is a negative valence of 1, 2, or 3,a and b each have values of from zero to 2, with (va)+(vb) equal to 2, and withm being a value of zero or more.

    Abstract translation: 显示了新型结晶铝酸盐的制备和用途，其通常符合经验式MgAavZbv.nAl（OH）3·mH2O，其中A和Z表示负价离子或选自羟基，卤化物，无机酸和有机物的基团 酸，n为约1至约2的值，v为1,2或3的负数，a和b各自具有0至2的值，其中（va）+（vb）等于2 ，m为0以上。

    Composition for recovery of MG.sup.++ from brines
    16.
    发明授权
    Composition for recovery of MG.sup.++ from brines 失效
    从盐水中回收MG ++的组成

    公开(公告)号：US4243555A

    公开(公告)日：1981-01-06

    申请号：US071920

    申请日：1979-08-31

    Applicant: John M. Lee ,  William C. Bauman

    Inventor： John M. Lee ,  William C. Bauman

    IPC: B01J41/08 ,  B01J47/00 ,  C01D3/14 ,  C01F7/00 ,  C01B9/00

    CPC classification number: B01J47/006 ,  B01J41/08 ,  C01D3/145 ,  C01F7/002

    Abstract: Magnesium values are selectively recovered from salt brines, even salt brines which contain competing ions such as Li.sup.+, Ca.sup.++, and Sr.sup.++, by contacting the brine with an anion exchange resin which has dispersed therein a microcrystalline structure of the formula MgX.sub.2.2Al(OH).sub.3, where X is a halide.

    Abstract translation: 通过使盐水与分散有式MgX2.2Al（OH）的微晶结构的阴离子交换树脂接触，从盐盐水，甚至含有竞争离子的盐盐，即Li +，Ca ++和Sr ++的盐水中选择性地回收镁值， 3，其中X是卤化物。

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