Abstract:
An optical fiber capable of achieving both of the ZSA property and the rapid curability is provided. The optical fiber includes a glass optical fiber 13, a primary coating layer 16 that coats an outer periphery of the glass optical fiber 13, and a secondary optical fiber 17 that coats an outer periphery of the primary coating layer 16. Young's modulus of the primary coating layer 16 is 1.2 MPa or less and Young's modulus of the secondary coating layer 17 is 800 MPa or more. Sulfur content of the surface of the glass optical fiber 13 is 0.2% by atom or more. Sulfur is not present in the vicinity of the outer periphery of the primary coating layer 16.
Abstract:
Embodiments generally relate to devices and methods for production of fibers and threads for use in electronic device manufacturing. Described here, fibers can be produced and manipulated using a dual-surfaced sizing material. The dual-surfaced sizing material has a surface which binds a fiber and a surface which binds a resin. Thus, the dual-surfaced sizing material can be left attached to the fibers without adversely affecting the resin binding in later production steps.
Abstract:
In an embodiment of the present invention, provided is an optical fiber including a glass core, and a polymer cladding formed around the glass core, the polymer cladding containing a mixture of a polymerizable composition and a silane coupling agent, and a fluorine-based ultraviolet curable resin. The mixture contains 5 to 95 parts by weight of the silane coupling agent based on 100 parts by weight of the total weight of the mixture. The fluorine-based ultraviolet curable resin alone has a refractive index in a range of 1.350 to 1.420 after ultraviolet curing. A component originated from the silane coupling agent is concentrated within a range of 20 μm or less in the polymer cladding from an interface between the glass core and the polymer cladding.
Abstract:
The present invention features ionomer compositions containing nanozirconia fillers. The compositions can be used in a variety of dental and orthodontic applications, for example, as adhesives, cements, restoratives, coatings and sealants.
Abstract:
An aqueous alcoholic fluoroalkyl functional group containing organopolysiloxane- composition, comprising: organopolysiloxanes of formula I: RO�Si(A)(CH.sub.3).sub.z (OR).sub.1-z O!.sub.a �Si(B)(R.sup.2).sub.y (OR).sub.1-y O!.sub.b �Si(C)(CH.sub.3)O!.sub.c �Si(D)(OR)O!.sub.d R.multidot.(HX)(I) wherein A is an aminoalkyl radical derived from the compound of formula II:H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II) wherein 0.ltoreq.f.ltoreq.6, 9=0 if f=0 and g=1 if f>0, 0.ltoreq.h.ltoreq.6 and 0.ltoreq.z.ltoreq.1, and B is a fluoroalkyl radical derived from the compound of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2)y(OR).sub.3-y (III) wherein R.sup.1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH.sub.2, O or S group, R.sub.2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0.ltoreq.y.ltoreq.1, and C is an alkyl radical derived from the compound of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV) and D is also an alkyl radical derived from the compound of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R.sup.3 in the preceding formulae is in each case identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms, R in the preceding formulae is in each case identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group, and HX is an acid, in which X is an inorganic or organic acid radical, and 0.ltoreq.y.ltoreq.1, 0.ltoreq.z.ltoreq.1, a>0, b>0, c>0, d>0, e>0 and (a+b+c+d).gtoreq.2.
Abstract translation:含有有机聚硅氧烷组合物的含水醇的氟代烷基官能团包括:式I的有机聚硅氧烷:RO [Si(A)(CH3)z(OR)1-zO] a [Si(B)(R2)y(OR) yO] b [Si(C)(CH3)O] c [Si(D)(OR)O] dRx(HX)(I)其中A是衍生自式II化合物的氨基烷基:H 2 N(CH 2)f (NH)g(CH 2)h Si(OR)3-z(CH 3)z(II)其中0 0,则g = R =(Y) - (CH 2)2 Si(R 2)y(OR)3-y (III)其中R1是具有1-9个C原子的单,低聚或全氟烷基或单,低聚或全氟化的芳基,Y是CH 2,O或S基团,R 2是直链,支链 或具有1-8个碳原子或芳基且0≤y≤1的环状烷基,C是衍生自式IV化合物的烷基:R3-Si(CH3)(OR)2( IV),D也是衍生自式V化合物的烷基:R 3 -Si(OR)3(V)其中前述通式中的R 3在每种情况下相同 或者不同的是具有1-8个C原子的直链,支链或环状的烷基,前述式中的R各自相同或不同,为具有1-8个C原子的直链,支链或环状的烷基或 芳基,HX是酸,其中X是无机或有机酸基,且0≤z≤1,a> 0,b> 0, c> 0,d> 0,e> 0和(a + b + c + d)> / = 2。
Abstract:
A stable aqueous solution of a silane/titanium chelate is prepared by (a) forming a mixture in alcoholic solution of bis-hydroxyethylaminopropyltriethoxysilane and a titanium chelate selected from the group consisting of titanium acetylacetonate, triethanolamine titanate and butyltitanate monomer; (b) adding water to the mixture of step (a) in a quantity sufficient to effect the hydrolysis of the silane; (c) completing the silane hydrolysis reaction; and (d) removing the alcohol from the solution. The end product can be diluted further with water to provide a commercial formulation that is substantially free of VOC and has a shelf like of at least six months. The aqueous solution of the silane/titanium chelate can also include an organofunctional silane.
Abstract:
The coupling agent is comprised of a pyrrolidyl group capable of being incorporated in the chain of an electroconducting polymer, and a silane group --Si(OR.sup.1).sub.3 which may be chemically bound to a glass substrate in order to form an adherent coating of said polymer. It is obtained by an addition reaction implementing an epoxide function and a primary or secondary amine function.
Abstract:
The invention provides a silane-oligomer (A) of the following formula: (R.sup.3)--X--(R.sup.1.sub.x)--Y--Si(R.sup.2).sub.3 ( 1) wherein R.sup.3 is a group having a functionality that can be polymerized through actinic radiation, R.sup.1.sub.x is a backbone-oligomer having a molecular weight of more than about 200, R.sup.2 is a hydrolyzable group, and X and Y are coupling groups. The invention also provides a glass coating composition containing the silane-oligomer.
Abstract:
A class of organosilanes of the general formula ##STR1## wherein Ar is a divalent aromatic radical; R.sub.f is a defined fluoroalkyl or perfluoroalkyl ether group; X is methyl, R.sub.f Ar as defined above, a halogen other than fluorine, or an alkoxy group; and each one of Y and Z is a halogen other than fluorine or an alkoxy group. These organosilanes are very useful as precursors to polysiloxane coupling agents for bonding fluoropolymers to glass fibers which can withstand the usual fluoropolymer melt-processing temperatures without decomposition.