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    Dendrimer solid acid and polymer electrolyte membrane including the same
    11.
    发明授权
    Dendrimer solid acid and polymer electrolyte membrane including the same 有权
    树枝状聚合物固体酸和聚合物电解质膜包括相同的

    公开(公告)号：US08119833B2

    公开(公告)日：2012-02-21

    申请号：US13176699

    申请日：2011-07-05

    Applicant: Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    Inventor： Myung-sup Jung ,  Jin-gyu Lee ,  Sang-kook Mah ,  Jae-jun Lee

    IPC: C07C309/32 ,  C07C309/42 ,  C07C309/33 ,  C07C309/44 ,  H01M8/22

    CPC classification number: C08J5/2256 ,  C08J5/2275 ,  C08J2300/00 ,  C08J2300/202 ,  C08J2379/08

    Abstract: Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.

    Abstract translation: 提供了树枝状聚合物固体酸和使用其的聚合物电解质膜。 聚合物电解质膜包括其表面具有离子导电性端基的树枝状聚合物固体酸的高分子和离子传导所需的离子导电性端基的最小量，因此抑制了树枝状聚合物固体酸的均匀分布，从而 提高离子电导率。 由于聚合物电解质膜中的离子导电性端基的数量被最小化，并且使用抑制了溶胀的聚合物基体，所以甲基交联和体积大的流出困难可能降低，并且树枝状聚合物固体酸的高分子 其表面上的离子导电性端基均匀分布。 因此，离子电导率高，因此即使在非加湿条件下，高分子电解质膜也具有良好的离子传导性。

    Preparation of 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids
    16.
    发明授权
    Preparation of 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids 失效
    4-烷基-2-羟基苯并噻吩-5-磺酸的制备

    公开(公告)号：US5072034A

    公开(公告)日：1991-12-10

    申请号：US627895

    申请日：1990-12-13

    Applicant: Peter Neumann ,  Heinz Eilingsfeld ,  Alexander Aumueller

    Inventor： Peter Neumann ,  Heinz Eilingsfeld ,  Alexander Aumueller

    IPC: C07C309/42 ,  C07C303/08 ,  C07C309/44 ,  C07C309/59

    CPC classification number: C07C303/08

    Abstract: 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by halogen, cyanao, hydroxyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.2 -C.sub.20 -alkoxycarbonyl, acyloxy and/or phenyl which is unsubstituted or substituted by C.sub.1 -c.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, R.sup.2 and R.sup.3 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.4 -C.sub.12 -cycloalkylalkyl, cyano, hydroxyl or hydroxyethyl or are each phenoxy, C.sub.7 -C.sub.10 -phenalkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, and R.sup.4 is hydrogen or sulfo, are prepared by reacting a 4-alkoxy-2-hydroxybenzophenone of the general formula II ##STR2## with chlorosulfonic acid at from -20.degree. to +100.degree. C., by a novel and improved process in which the reaction is carried out in an aliphatic, cycloaliphatic and/or aromatic carboxylate as solvent.

    Abstract translation: 其中R 1是未被取代或被卤素，氰基，羟基，C 1 -C 20烷氧基，C 2 -C 20烷氧基取代的C 1 -C 20烷基的4-烷氧基-2-羟基二苯甲酮-5-磺酸 -C 20 - 烷氧基羰基，未被取代或被C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基和/或卤素取代的酰氧基和/或苯基，R 2和R 3彼此独立地为氢，卤素，C 1 -C 12 - 烷基 C 1 -C 12烷氧基，C 1 -C 4卤代烷基，C 3 -C 8环烷基，C 4 -C 12环烷基烷基，氰基，羟基或羟乙基，或各自为苯氧基，未取代或被C1- C4-烷基，C1-C4-烷氧基和/或卤素，R4是氢或磺基，是通过使通式II的4-烷氧基-2-羟基二苯甲酮与（II）的4-磺酰基-2- 通过一种新的改进的方法，其中反应在脂族，脂环族和/或芳族羧酸酯作为溶剂中进行。

    Process for the preparation of alkali metal and alkaline earth salts of benzaldehyde-2,4-di-sulfonic acid
    17.
    发明授权
    Process for the preparation of alkali metal and alkaline earth salts of benzaldehyde-2,4-di-sulfonic acid 失效
    制备苯甲醛-2,4-二磺酸的碱金属和碱土金属盐的方法

    公开(公告)号：US4710322A

    公开(公告)日：1987-12-01

    申请号：US21622

    申请日：1987-03-02

    Applicant: Hans J. Metz

    Inventor： Hans J. Metz

    IPC: C07C309/44 ,  C07C67/00 ,  C07C301/00 ,  C07C303/00 ,  C07C303/02 ,  C07C303/20 ,  C07C303/32 ,  C07C309/28 ,  C07C143/38

    CPC classification number: C07C309/00

    Abstract: The invention consists in an improved process for the preparation of salts of benzaldehyde-2,4-disulfonic acid from 2,4-dichlorobenzaldehyde. In the process 2,4-di-chlorobenzaldehyde is reacted with an aqueous solution of an alkali metal or alkaline earth sulfite and/or hydrogensulfite for a reaction time of less than 7 hours at 140.degree.-180.degree. C. to form the corresponding salt of benzaldehyde-2,4-disulfonic acid with high yield. The product has application in the electroplating industry and in the preparation triphenylmethane dyestuffs.

    Abstract translation: 本发明是从2,4-二氯苯甲醛制备苯甲醛-2,4-二磺酸的盐的改进方法。 在该方法中，2,4-二氯苯甲醛与碱金属或碱土金属亚硫酸盐和/或亚硫酸氢钠的水溶液反应，反应时间在140-180℃下反应时间小于7小时，形成相应的盐 的苯甲醛-2,4-二磺酸，产率高。 该产品已应用于电镀工业和制备三苯甲烷染料。

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