摘要:
Mesityl oxide, a simple condensation product of acetone, is oxidatively dehydrogenated and dehydrocyclized in the presence of oxygen and a halogen promoter to give dimethylfuran, a high octane gasoline blending component. By adding or subtracting lower alkyl groups from the starting materials, corresponding mono-, poly-lower alkyl furans can be produced.
摘要:
New derivatives of 4-chloro-5-sulfamoyl-anthranilic acid. In the new derivatives the 5-sulfamoyl group is substituted by R1XCH2, where X is oxygen or sulfur and R1 is a straight or branchedchain lower alkyl radical of up to 10 carbon atoms which may be substituted by a hydroxy or alkoxy group or several such groups, a cycloalkyl radical, an alkenyl or alkinyl radical, an aralkyl or heteroarylalkyl radical. The novel compounds are valuable diuretics and saluretics and they are prepared from corresponding free sulfamoyl compounds by reaction with formaldehyde or paraformaldehyde and a compound R1-XH where R1 and X have the same meaning as above.
WHEREIN PROPENYL GROUP ON THE CYCLOPROPANE RING IS CIS OR TRANS CONFIGURATION REGARDING THE DOUBLE BOND, AND R1 IS A C1-C3 ALKYL, ALLYL, PROPARGLY, BENZYL, THENYL, FURYLMETHYL, PHENOXY OR LOWER ALKYL-SUBSTITUTED BENZYL, THENYL, FURYLMETHYL OR PHENOXY, R2 AND R3 ARE HYDROGEN OR METHYL RESPECTIVELY, OR R1 AND R2 ARE BONDED AT RESPECTIVE ENDS OF THE ADJACENT TWO GROUPS TO FORM A C3-C4 POLYMETHYLENE GROUP, R4 IS HYDROGEN, LOWER ALKYL, LOWER ALKENYL OR LOWER ALKINYL.
摘要:
WHERE X is a substituent selected from the group consisting of ethyl, allyl, isobutenyl, hexyl, ethoxy, pentoxy, allyloxy, chloro, bromo and nitro; n is a whole number between 1 and 3 inclusive, to methods of manufacturing said esters to insecticides containing said esters as their active ingredient and to methods of killing noxious insects by means of such insecticides. The present invention relates to insecticide compositions containing the substituted furfurylesters of chrysanthemumic acid expressed by the following general formula
摘要:
5-Lower alkynyl-furylmethyl 2,2,3,3-tetramethyl-cyclopropane-1carboxylates, which are harmless to mammals and inexpensive, and insecticidal compositions containing the same. The said carboxylates are prepared by the esterification of 5-lower alkynyl-furylmethyl alcohols or reactive derivatives thereof with 2,2,3,3-tetramethyl-cyclopropane-1-carboxylic acid or reactive derivatives thereof.