摘要:
PROCESS FOR THE PREPARATION OF METHYL 3,4-HYDROCARBYL3-BUTENOATES BY REACTION OF AN ALYLHALIDE
RR''C=CR"-CH2X
WHEREIN R, R'' AND R" REPRESENT HYDROGEN OR A HYDROCARBYL HAVING FROM 1 TO 10 CARBON ATOMS AND X IS A HALIDE SELECTED FROM C1, BR, I, WITH CARBO MONOXIDE AND METHANOL. ONE OPERATES IN A METHANOL SOLUTION IN THE PRESENCE OF NCKEL-CARBONYL AND THIOUREA, AT ATMOSPHERIC PRESSURE, AT A TEMPERATURE BETWEEN 15* AND 35* C., MAINTAINING A PH RANGIN FROM 5.5 TO 9, AND PREFERABLY FROM 7.5 TO 8.
摘要:
According to an example aspect of the present invention, there is provided a use of molar mass controlled cellulose in injection molding, extrusion and three dimensional printing applications.
摘要:
The present disclosure generally relates to a process for manufacturing a processable dried cellulose nanomaterial using a co-solvent of tert-butyl alcohol (TBA), of which unique physical/chemical properties enable facile modification/derivatization. This present disclosure also relates to materials and process of generating of superhydrophobic surface coating using hydrophobic carboxylic acid modified cellulose nanofibers. Both the processes and the products thereof are within the scope of this disclosure.
摘要:
An all-solid-state secondary battery includes a positive electrode active substance layer; a negative electrode active substance layer; and an inorganic solid electrolyte layer, in which at least one of the positive electrode active substance layer, the negative electrode active substance layer, or the inorganic solid electrolyte layer contains an inorganic solid electrolyte having conductivity of ions of metal belonging to Group 1 or 2 of the periodic table and a cellulose polymer.
摘要:
A superhydrophilic amphiphilic copolymer and process for making the superhydrophilic amphiphilic copolymer includes a low molecular weight polysaccharide modified with a hydrophobic reagent, such as substituted succinic anhydride. The superhydrophilic amphiphilic copolymer system generates stable foam for use in applications, such as healthcare formulations, with low irritation of the eyes and skin.
摘要:
The present invention describes methods of treating cellulosic materials with a composition that provides increased hydrophobicity to such materials without sacrificing the biodegradability thereof. The methods as disclosed provide for esterification of available hydroxyl groups on cellulosic materials, where such hydroxyl groups are “masked” by bulky organic chains, including that the disclosure provides products made by such methods. The materials thus treated display higher hydrophobicity, barrier function, and mechanical properties, and may be used in any application where such features are desired.
摘要:
A process for producing a cellulose derivative, including reacting a reactant and a cellulose or a derivative thereof in a solid-liquid heterogeneous system to form a cellulose derivative containing a long-chain organic group having 5 or more carbon atoms introduced therein, in a swollen state, and performing solid-liquid separation to obtain the cellulose derivative containing a long-chain organic group introduced therein.
摘要:
This invention concerns the first environmentally benign heterogeneous modification of polysaccharide-based material in native solid state by thiol-ene “click chemistry”. The direct reaction of a thiol with an un-activated double or triple bond by thiol-ene and thiol-enyne click modification is thermally or photochemically catalyzed and is completely metal-free and allows for a highly modular approach to modifications of fibers and fiber-based materials.