Method for producing polymer
    11.
    发明授权

    公开(公告)号:US09738742B2

    公开(公告)日:2017-08-22

    申请号:US14761356

    申请日:2014-01-08

    摘要: A method for producing a polymer has: a polymerization step of polymerizing at least a conjugated diene monomer in a hydrocarbon solvent using an organolithium compound as a polymerization initiator, and obtaining a polymer; and, following steps (1) to (4), successively performing after the polymerization step: (1) a step of mixing an acid and water of 20 to 300 parts by mass into the solution containing the polymer of 100 parts by mass, (2) a step of adjusting an amount of the water to 10 parts by mass or less based on 100 parts by mass of the solution containing the polymer, (3) a step of adding a carbon oxide gas and/or a compound to be decarboxylated to the solution containing the polymer, and (4) a step of removing a solvent from the solution containing the polymer until a concentration of the polymer reaches 95 mass % or more.

    Method of manufacturing pourable pulverulent rubber-filler mixtures
starting with rubber solutions
    13.
    发明授权
    Method of manufacturing pourable pulverulent rubber-filler mixtures starting with rubber solutions 失效
    从橡胶溶液开始制造可倾倒的粉状橡胶填料混合物的方法

    公开(公告)号:US4912151A

    公开(公告)日:1990-03-27

    申请号:US302953

    申请日:1989-01-30

    申请人: Ralf Tappe

    发明人: Ralf Tappe

    CPC分类号: C08J3/215 C08J2321/00

    摘要: A method for manufacturing pourable pulverulent rubber-filler mixtures starting from rubber solutions is disclosed. In this method, the filler is dispersed in an organic solvent and then mixed with a rubber solution to obtain a stable rubber-containing filler dispersion. The dispersion is then introduced into hot water containing a dispersed filler and subjected to high shear forces, causing the organic solvent to simultaneously be largely distilled off. After the rubber-containing filler dispersion has been completely added, an aqueous filler dispersion is added, water is removed from the precipitated rubber-filler mixture, and the product mixture is dried under constant agitation.

    摘要翻译: 公开了从橡胶溶液开始制造可倾倒的粉状橡胶填料混合物的方法。 在该方法中,将填料分散在有机溶剂中,然后与橡胶溶液混合,得到稳定的含橡胶填料分散体。 然后将分散体引入含有分散填料的热水中并承受高剪切力,同时大量蒸馏出有机溶剂。 在完全加入含橡胶的填料分散体之后,加入水性填料分散体,从析出的橡胶填料混合物中除去水,并将产物混合物在恒定搅拌下干燥。

    Guayule rubber, resin and bagasse recovery and purification processes
    14.
    发明授权
    Guayule rubber, resin and bagasse recovery and purification processes 失效
    Guayule橡胶,树脂和甘蔗渣回收和纯化工艺

    公开(公告)号:US4804741A

    公开(公告)日:1989-02-14

    申请号:US861454

    申请日:1986-05-09

    IPC分类号: C08C2/06 C08C2/00

    CPC分类号: C08C2/06 Y10S528/933

    摘要: Processes are described for the recovery of natural rubber from solutions containing guayule rubber and resins. The resinous rubber is dissolved in a lipophilic solvent such as hexane. The rubber is recovered from the solution in high purity on a heated surface immersed in the solution.

    摘要翻译: 描述了从含有胶体橡胶和树脂的溶液中回收天然橡胶的方法。 将树脂橡胶溶解在亲脂性溶剂如己烷中。 将橡胶从沉淀在溶液中的加热表面上以高纯度从溶液中回收。

    Solvent fractionation of guayule rubber
    15.
    发明授权
    Solvent fractionation of guayule rubber 失效
    胶体橡胶的溶剂分馏

    公开(公告)号:US4623713A

    公开(公告)日:1986-11-18

    申请号:US754554

    申请日:1985-07-15

    IPC分类号: C08C2/00 C08C4/00

    CPC分类号: C08C2/00 Y10S528/933

    摘要: A method and composition are disclosed wherein guayule rubber is fractionated into desirable weight average molecular weight fractions by a desired solvent system. Oftentime, a plurality of fractionating steps is utilized wherein the desirable molecular weight rubber fraction is precipitated or extracted. High weight average molecular weight rubbers having usually less than 4% by weight of resin content therein are generally desirable because of their favorable physical properties.

    摘要翻译: 公开了一种方法和组合物,其中通过所需溶剂系统将瓜耳胶橡胶分级成所需的重均分子量级分。 通常,使用多个分馏步骤,其中所需的分子量橡胶级分沉淀或萃取。 通常由于其有利的物理性质,通常期望具有通常小于4重量%的树脂含量的高重均分子量橡胶。

    Method for preparing color-free, stabilized polymers of conjugated
dienes or vinyl aromatic hydrocarbons or copolymers of conjugated
dienes and vinyl aromatic hydrocarbons
    16.
    发明授权
    Method for preparing color-free, stabilized polymers of conjugated dienes or vinyl aromatic hydrocarbons or copolymers of conjugated dienes and vinyl aromatic hydrocarbons 失效
    共轭二烯或乙烯基芳烃的无色稳定聚合物或共轭二烯和乙烯基芳烃的共聚物的制备方法

    公开(公告)号:US4415695A

    公开(公告)日:1983-11-15

    申请号:US362175

    申请日:1982-03-25

    申请人: Sunil B. Sarkar

    发明人: Sunil B. Sarkar

    CPC分类号: C08C2/00

    摘要: A method for preparing essentially color-free, stabilized polymers of conjugated dienes or vinyl aromatic hydrocarbons or copolymers of conjugated dienes and vinyl aromatic hydrocarbons involves a first stage in which a living polymer of a conjugated diene or vinyl aromatic hydrocarbon or copolymer of a conjugated diene and a vinyl aromatic hydrocarbon is prepared by anionically polymerizing the conjugated diene or vinyl aromatic hydrocarbon, or copolymerizing the conjugated diene and the vinyl aromatic hydrocarbon using a lithium-based catalyst and an inert hydrocarbon diluent. Then, the living polymer or copolymer is terminated by the addition of a suitable terminating agent. Following the termination procedure, boric acid is added to the polymer of copolymer in a sufficient amount to prevent or substantially reduce color formation. Then, stabilizing agents are added to the polymer or copolymer and the polymer or copolymer is recovered from the diluent.

    摘要翻译: 用于制备基本上无色,稳定的共轭二烯或乙烯基芳族烃的共聚物或共轭二烯和乙烯基芳烃的共聚物的方法涉及第一阶段,其中共轭二烯或乙烯基芳族烃的活性聚合物或共轭二烯的共聚物 通过使共轭二烯或乙烯基芳族烃阴离子聚合或使用锂基催化剂和惰性烃稀释剂共轭共轭二烯和乙烯基芳烃来制备乙烯基芳族烃。 然后,通过加入合适的终止剂终止活性聚合物或共聚物。 在终止方法之后,将硼酸以足够的量加入到共聚物的聚合物中以防止或基本上减少颜色形成。 然后,将稳定剂加入到聚合物或共聚物中,并从稀释剂中回收聚合物或共聚物。

    Reactive cyclobutanone-containing polymers and method for preparing same
    17.
    发明授权
    Reactive cyclobutanone-containing polymers and method for preparing same 失效
    含反应性环丁酮的聚合物及其制备方法

    公开(公告)号:US4302563A

    公开(公告)日:1981-11-24

    申请号:US137087

    申请日:1980-04-03

    申请人: Walter L. Vaughn

    发明人: Walter L. Vaughn

    IPC分类号: C08C19/00 C08C2/00

    CPC分类号: C08C19/00

    摘要: Synthetic polymers containing at least one cyclobutanone group of the formula ##STR1## wherein R.sup.1 to R.sup.4 are selected from the class consisting of alkyl, aryl, halogen, and hydrogen radicals are prepared by reacting in an inert organic solvent a conjugated diene polymer having unsaturated bonds in the main or side chain with a ketone of the formula ##STR2## Such polymers are useful as adhesives and flexibilizers, and they can be readily cross-linked to form elastomeric coatings with good solvent resistance.

    摘要翻译: 含有至少一种下式的其中R 1至R 4选自烷基,芳基,卤素和氢原子的式I的环丁酮基团的合成聚合物是通过在惰性有机溶剂中使具有不饱和键的共轭二烯聚合物 主链或侧链与下式的酮结合。这种聚合物可用作粘合剂和增韧剂,并且它们可以容易地交联以形成具有良好耐溶剂性的弹性体涂料。

    Method for manufacturing polymer latex

    公开(公告)号:US11034799B2

    公开(公告)日:2021-06-15

    申请号:US16077612

    申请日:2017-02-16

    申请人: ZEON CORPORATION

    摘要: A method for producing a polymer latex, including an emulsification step of mixing a polymer solution obtained by dissolution of synthetic polyisoprene and/or a styrene-isoprene-styrene block copolymer in an organic solvent, with an aqueous solution including 0.1 to 30 parts by weight of a rosinate based on 100 parts by weight in total of the synthetic polyisoprene and the styrene-isoprene-styrene block copolymer, and emulsifying the resultant in water to thereby obtain an emulsified liquid, a solvent removal step of removing the organic solvent in the emulsified liquid, and a concentration step of concentrating the emulsified liquid from which the organic solvent is removed, and also adjusting the content rate of the rosinate in the emulsified liquid after concentration, in the range of 0.1 to 3 parts by weight based on 100 parts by weight in total of the synthetic polyisoprene and the styrene-isoprene-styrene block copolymer in the emulsified liquid.

    Process for the removal of the solvent from a polymeric solution
    20.
    发明授权
    Process for the removal of the solvent from a polymeric solution 有权
    从聚合物溶液中除去溶剂的方法

    公开(公告)号:US09090746B2

    公开(公告)日:2015-07-28

    申请号:US14357585

    申请日:2012-11-23

    申请人: VERSALIS S.P.A.

    摘要: A process for the removal of solvent from a polymeric solution including at least one elastomeric polymer. The polymeric solution is subjected to a stripping step by means of water vapor, in the presence of a dispersant system including: from 0.005% by weight to 1% by weight, with respect to the total weight of the dry elastomeric polymer, of at least one lamellar material; from 0.0005% by weight to 1% by weight, with respect to the total weight of the dry elastomeric polymer, of at least one cationic surfactant.

    摘要翻译: 用于从包含至少一种弹性体聚合物的聚合物溶液中除去溶剂的方法。 在分散剂体系存在下,通过水蒸汽对聚合物溶液进行汽提步骤,包括:相对于干弹性体聚合物的总重量为0.005重量%至1重量%,至少 一层薄片材料 至少一种阳离子表面活性剂,相对于干燥的弹性体聚合物的总重量为0.0005重量%至1重量%。