摘要:
A process for producing proton-conducting membrane, the process comprising: mixing (i) 5% to 60% by volume of an electrically nonconductive inorganic powder having a good acid absorption capacity, the powder comprising essentially nanosize particles; (ii) 5% to 50% by volume of a polymeric binder that is chemically compatible with acid, oxygen and the fuel; and (iii) 10 to 90% by volume of an acid or aqueous acid solution, wherein the mixing is conducted at various rate steps, thereby producing a proton-conducting mixture; continuously casting the proton-conducting mixture on rolled paper, non-woven matrix or the like at ambient temperature; drying the casted proton-conducting mixture at a temperature of greater than 100° C. for approximately 5 to 30 minutes, thereby forming a dry film; and laminating a plurality of the dry films together under pressure, and thereafter extracting pore-former out of pores of the dry films, thereby forming the proton-conducting membrane having an average pore size of less than 30 nanometers.
摘要:
This disclosure relates to energy storage and generation systems, e.g., combination of flow battery and hydrogen fuel cell, that exhibit operational stability in harsh environments, e.g., both charging and discharging reactions in a regenerative fuel cell in the presence of a halogen ion or a mixture of halogen ions. This disclosure also relates to energy storage and generation systems that are capable of conducting both hydrogen evolution reactions (HERs) and hydrogen oxidation reactions (HORs) in the same system. This disclosure further relates to energy storage and generation systems having low cost, fast response time, and acceptable life and performance.
摘要:
A method of operating a fuel cell electrochemical system includes receiving at least one of a cost of electricity and a cost of fuel and adjusting at least one of an operating efficiency and throughput of the fuel cell based on the at least one of the received cost of electricity and the received cost of fuel.
摘要:
A method and apparatus for determining the state of charge (SOC) of a battery is discussed. The method involves measuring the terminal voltage across the battery and the current flowing through the battery at a plurality of different times and fitting a line equation with a slope and an intercept to the terminal voltage and current data. The open-circuit voltage (OCV) is calculated from the intercept of the linear equation and the SOC is determined from the OCV by reference to a lookup table.
摘要:
In one embodiment, an electrical power storage system using hydrogen includes a power generation unit generating power using hydrogen and oxidant gas and an electrolysis unit electrolyzing steam. The electrical power storage system includes a hydrogen storage unit storing hydrogen generated by the electrolysis and supplying the hydrogen to the power generation unit during power generation, a high-temperature heat storage unit storing high temperature heat generated accompanying the power generation and supplying the heat to the electrolysis unit during the electrolysis, and a low-temperature heat storage unit storing low-temperature heat, which is exchanged in the high-temperature heat storage unit and generating with this heat the steam supplied to the electrolysis unit.
摘要:
A start-up plating process for a flow cell battery is disclosed. Upon start-up of the flow-cell stack, catalysts may have deplated from the electrodes. The catalyst is replated to the electrode by application of currents to the stack prior to circulating electrolyte fluids.
摘要:
In accordance with one embodiment, an electrochemical cell includes a negative electrode including a form of lithium, a positive electrode spaced apart from the negative electrode and including an electron conducting matrix, a separator positioned between the negative electrode and the positive electrode, an electrolyte including a salt, and a charging redox couple located within the positive electrode, wherein the electrochemical cell is characterized by the transfer of electrons from a discharge product located in the positive electrode to the electron conducting matrix by the charging redox couple during a charge cycle.
摘要:
Redox flow battery systems having a supporting solution that contains Cl− ions can exhibit improved performance and characteristics. Furthermore, a supporting solution having mixed SO42− and Cl− ions can provide increased energy density and improved stability and solubility of one or more of the ionic species in the catholyte and/or anolyte. According to one example, a vanadium-based redox flow battery system is characterized by an anolyte having V2+ and V3+ in a supporting solution and a catholyte having V4+ and V5+ in a supporting solution. The supporting solution can contain Cl− ions or a mixture of SO42− and Cl− ions.
摘要:
A redox flow battery having a supporting solution that includes Cl− anions is characterized by an anolyte having V2+ and V3+ in the supporting solution, a catholyte having Fe2+ and Fe3+ in the supporting solution, and a membrane separating the anolyte and the catholyte. The anolyte and catholyte can have V cations and Fe cations, respectively, or the anolyte and catholyte can each contain both V and Fe cations in a mixture. Furthermore, the supporting solution can contain a mixture of SO42− and Cl− anions.
摘要:
This invention relates to a transportable electricity generation unit (30) suitable to supply electric power to an external load (51). Said electricity generation unit (30) comprises: a photovoltaic generation unit (1) and/or an aerogenerator generating a first electric power (P1), a water electrolyzer (4) connected to said photovoltaic generation unit (1) and/or aerogenerator, said electrolyzer being capable of producing hydrogen by electrolysis of water; a tank (3) to store the hydrogen deriving from said electrolysis of water; a fuel cell unit (2) fed with the hydrogen produced by said electrolyzer (4) or stored in said tank (3), said fuel cell (2) generating a second electric power (P2), a battery accumulator unit (5); an electronic power control device (8) comprising means for controlling the flow of said first electric power (P1) and said second and third electric power (P2, P3) to said external load (51), controlling the flow of said first electric power (P1) to said water electrolyzer (4), and for controlling production and storage of hydrogen.