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    Oligomerization catalyst system and method of making and method of using such catalyst system in the oligomerization of olefins
    191.
    发明授权
    Oligomerization catalyst system and method of making and method of using such catalyst system in the oligomerization of olefins 失效

    公开(公告)号：US06228797B1

    公开(公告)日：2001-05-08

    申请号：US09210039

    申请日：1998-12-11

    Applicant: G. J. Greenwood ,  Bruce B. Randolph

    Inventor： G. J. Greenwood ,  Bruce B. Randolph

    IPC: B01J3100

    CPC classification number: B01J31/0227 ,  B01J21/08 ,  B01J31/0225 ,  B01J37/036 ,  B01J2231/20 ,  C10G50/00

    Abstract: A method of preparing a catalyst system which comprises mixing a first solid material comprising at least one perfluoroalkylsulfonic acid salt with a second solid material comprising at least one silanol comprising hydroxy groups and silicon to form a gel comprising silica and the at least one perfluororalkylsulfonic acid salt, and contacting the gel with an acidic solution to convert at least a portion of the at least one perfluoroalkylsulfonic acid salt to at least one perfluoroalkylsulfonic acid is disclosed. Alternatively, a method of preparing a catalyst system which comprises mixing at least one perfluoroalkylsulfonic acid salt with silica gel to form a gel comprising silica and at least one perfluororalkylsulfonic acid salt, and contacting the gel with an acidic solution to convert at least a portion of the at least one perfluororalkylsulfonic acid salt to at least one perfluororalkylsulfonic acid is disclosed. The thus-obtained catalyst systems are employed as catalysts in the oligomerization of a hydrocarbon feedstock comprising unsaturated hydrocarbons.

    Solid catalyst component for olefin polymerization and catalyst
    192.
    发明授权
    Solid catalyst component for olefin polymerization and catalyst 失效
    用于烯烃聚合和催化剂的固体催化剂组分

    公开(公告)号：US06228793B1

    公开(公告)日：2001-05-08

    申请号：US09297055

    申请日：1999-04-28

    Applicant: Motoki Hosaka ,  Isa Nishiyama

    Inventor： Motoki Hosaka ,  Isa Nishiyama

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/6548 ,  C08F4/654 ,  C08F4/6465 ,  C08F4/651 ,  C08F2500/12 ,  C08F2500/18

    Abstract: The present invention provides a solid catalyst component for polymerization of olefins prepared by allowing a magnesium compound, a titanium compound and an electron donor compound to come in contact with each other, and having a value that a parameter of S1/S2 determined by Raman spectroscopic analysis is not less than 0.5 and not more than 10, wherein S1 and S2 are the values determined by Raman spectroscopic analysis, and S1 is a value of peak area of the strongest peak appeared in the range from 360 to 520 cm−1 and S2 is a value of peak area of the strongest peak appeared in the range from 160 to 340 cm−1. A catalyst comprising the solid catalyst component, an organic aluminum compound and an organic silicon compound is superior in hydrogen response and can produce a polymer of olefins having a high stereoregularity in a high yield.

    Abstract translation: 本发明提供了通过使镁化合物，钛化合物和电子给体化合物相互接触而制备的烯烃聚合用固体催化剂成分，具有通过拉曼光谱法测定的S1 / S2的参数 分析不小于0.5且不大于10，其中S1和S2是通过拉曼光谱分析确定的值，S1是最强峰的峰面积的值出现在360至520cm -1和S2的范围内 是最强峰峰值的值出现在160〜340厘米-1的范围内。 包含固体催化剂组分，有机铝化合物和有机硅化合物的催化剂具有优异的氢气响应性，并且可以以高产率生产具有高立构规整性的烯烃聚合物。

    Process for preparing catalyst supports and supported polyolefin catalysts and also their use for the preparation of polyolefins
    193.
    发明授权
    Process for preparing catalyst supports and supported polyolefin catalysts and also their use for the preparation of polyolefins 失效
    制备催化剂载体和负载型聚烯烃催化剂的方法及其在制备聚烯烃中的用途

    公开(公告)号：US06225252B1

    公开(公告)日：2001-05-01

    申请号：US09246139

    申请日：1999-02-08

    Applicant: Eberhard Ernst ,  Jens Reussner

    Inventor： Eberhard Ernst ,  Jens Reussner

    IPC: B01J3100

    CPC classification number: C08F10/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65922 ,  C08F4/65927 ,  C08F110/06 ,  Y10S526/943 ,  C08F2500/24 ,  C08F2500/03

    Abstract: A process for preparing a catalyst support in which a hydrophilic inorganic oxide of an element of main groups 2, 13 or 14 or transition group 4 of the Periodic Table or a mixture or mixed oxide thereof is dried at from 110 to 800° C., subsequently reacted, if desired, with alumioxanes or aluminum alkyls and subsequently reacted simultaneously with aluminoxanes and bisphenol A as a polyfunctional organic crosslinker. In a further stage, the catalyst support can be brought into contact with a polyolefin catalyst, giving a supported polyolefin catalyst which is used, in particular, for the polymerization of olefins.

    Abstract translation: 制备催化剂载体的方法，其中将元素周期表中的主要基团2,13或14或过渡基团4的元素的亲水性无机氧化物或其混合物或混合氧化物在110至800℃下干燥， 随后如果需要与铝氧烷或烷基铝反应，随后与铝氧烷和双酚A作为多官能有机交联剂同时反应。 在另一阶段，催化剂载体可以与聚烯烃催化剂接触，得到负载型聚烯烃催化剂，特别是用于烯烃聚合。

    Method of preparing a catalyst for polymerization and copolymerization of ethylene
    197.
    发明授权
    Method of preparing a catalyst for polymerization and copolymerization of ethylene 有权
    制备乙烯聚合和共聚合催化剂的方法

    公开(公告)号：US06831033B2

    公开(公告)日：2004-12-14

    申请号：US10171084

    申请日：2002-06-12

    Applicant: Chun-Byung Yang ,  Sang-Yull Kim ,  Weon Lee

    Inventor： Chun-Byung Yang ,  Sang-Yull Kim ,  Weon Lee

    IPC: B01J3100

    CPC classification number: C08F110/02 ,  C08F4/651 ,  C08F4/6565 ,  C08F2500/18 ,  C08F2500/12

    Abstract: A solid titanium complex catalyst for polymerization and copolymerization of ethylene is prepared by the process that includes: (1) preparing a magnesium solution by reacting a halogenated magnesium compound with an alcohol; (2) reacting the magnesium solution with an ester compound having at least one hydroxyl group and a silicon compound having an alkoxy group to produce a magnesium composition; and (3) producing a solid titanium catalyst by reacting the magnesium composition solution with a mixture of a titanium compound and a haloalkane compound; and optionally reacting the solid titanium catalyst with an additional titanium compound.

    Abstract translation: 一种用于乙烯聚合和共聚合成的固体钛络合物催化剂是通过以下方法制备的：（1）通过使卤代镁化合物与醇反应制备镁溶液; （2）使镁溶液与具有至少一个羟基的酯化合物和具有烷氧基的硅化合物反应以产生镁组合物; 和（3）通过使镁组合物溶液与钛化合物和卤代烷烃化合物的混合物反应制备固体钛催化剂; 并且任选地使固体钛催化剂与另外的钛化合物反应。

    Supported catalyst for producing syndiotactic styrenic polymer with high productivity and significantly reduced reactor fouling
    198.
    发明授权
    Supported catalyst for producing syndiotactic styrenic polymer with high productivity and significantly reduced reactor fouling 失效
    用于生产间同立构苯乙烯聚合物的负载催化剂，生产率高，反应堆结垢明显减少

    公开(公告)号：US06828270B1

    公开(公告)日：2004-12-07

    申请号：US09678171

    申请日：2000-10-02

    Applicant: Xuequan Zhang ,  Sung-Cheol Yoon ,  Jae-Gon Lim ,  Young-Sub Lee

    Inventor： Xuequan Zhang ,  Sung-Cheol Yoon ,  Jae-Gon Lim ,  Young-Sub Lee

    IPC: B01J3100

    CPC classification number: C08F4/027 ,  C08F4/65912 ,  C08F4/65916 ,  C08F12/08

    Abstract: The supported catalyst according to the present invention comprises a support of organic or inorganic powder with a high-surface area, a polymer coated onto the support and a metallocene catalyst. The polymer (1) contains polar groups; (2) interacts with the surface of the support; and (3) is insoluble in the styrenic monomer or polymerization solvent during polymerization after the catalyst is loaded. The polymer is located between the support and the metallocene catalyst such that the polymer insulates the metallocene layer from the support layer to prevent poisoning of the metallocene catalyst layer by the support layer. The styrenic polymer powder such produced by the present invention has good flow-ability and good morphology demonstrating a great deal of industrial applicability.

    Abstract translation: 根据本发明的负载型催化剂包括具有高表面积的有机或无机粉末的载体，涂覆在载体上的聚合物和金属茂催化剂。 聚合物（1）含有极性基团; （2）与支撑体的表面相互作用; 和（3）在负载催化剂后的聚合期间不溶于苯乙烯单体或聚合溶剂。 聚合物位于载体和茂金属催化剂之间，使得聚合物将金属茂层与载体层绝缘，以防止金属茂催化剂层被载体层中毒。 本发明制造的苯乙烯类聚合物粉末具有良好的流动性和良好的形态，表现出大量的工业实用性。

    Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst
    199.
    发明授权
    Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst 失效
    使用烷基锂化合物作为助催化剂的聚合催化剂体系和方法

    公开(公告)号：US06828268B1

    公开(公告)日：2004-12-07

    申请号：US09435113

    申请日：1999-11-05

    Applicant: Max P. McDaniel ,  Joseph S. Shveima ,  Elizabeth A. Benham ,  Rolf L. Geerts ,  James L. Smith

    Inventor： Max P. McDaniel ,  Joseph S. Shveima ,  Elizabeth A. Benham ,  Rolf L. Geerts ,  James L. Smith

    IPC: B01J3100

    CPC classification number: B01J31/128 ,  B01J21/063 ,  B01J21/066 ,  B01J23/26 ,  B01J31/122 ,  B01J31/14 ,  B01J35/0006 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/69 ,  C08F2500/12 ,  C08F2500/05 ,  C08F4/6341 ,  C08F2500/07 ,  C08F210/14

    Abstract: A catalyst system composition comprising a chromium compound supported on a silica-titania support, wherein said catalyst system has been reduced with carbon monoxide, and a cocatalyst selected from the group consisting of i) alkyl lithium compounds, ii) dialkyl aluminum alkoxides in combination with at least one metal alkyl selected from the group consisting of alkyl zinc compounds, alkyl aluminum compounds, alkyl boron compounds, and mixtures thereof and iii) mixtures thereof can be used to polymerize olefins to produce a low density polymer with a decreased melt index and/or high load melt index. This catalyst system also can be used with a Ziegler-Natta catalyst system to polymerize olefins. Polymerization processes using these catalyst system compositions are also provided. Polymers resulting from polymerization processes using the inventive catalyst and cocatalyst systems have a decreased high load melt index, decreased melt index, increased fluff bulk density, and are useful as components to make bi-modal molecular weight resins for film and/or blow molding applications.

    Abstract translation: 一种催化剂体系组合物，其包含负载在二氧化硅 - 二氧化钛载体上的铬化合物，其中所述催化剂体系已用一氧化碳还原，并且选择由以下组成的组的助催化剂：i）烷基锂化合物，ii）二烷基铝醇盐与 选自烷基锌化合物，烷基铝化合物，烷基硼化合物及其混合物中的至少一种金属烷基酯和iii）其混合物可用于聚合烯烃以产生具有降低的熔体指数的低密度聚合物和/ 或高负荷熔体指数。 该催化剂体系也可与齐格勒 - 纳塔催化剂体系一起使用以聚合烯烃。 还提供了使用这些催化剂体系组合物的聚合方法。 由使用本发明的催化剂和助催化剂体系的聚合方法产生的聚合物具有降低的高负荷熔体指数，降低的熔体指数，增加的绒毛堆积密度，并且可用作制备用于膜和/或吹塑应用的双模态分子量树脂的组分 。

    Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts
    200.
    发明授权
    Hexacoordinated ruthenium or osmium metal carbene metathesis catalysts 有权
    六配位钌或锇金属卡宾复分解催化剂

    公开(公告)号：US06818586B2

    公开(公告)日：2004-11-16

    申请号：US10172765

    申请日：2002-06-14

    Applicant: Robert H. Grubbs ,  Melanie S. Sanford ,  Jason L. Moore ,  Jennifer A. Love ,  Tina M. Trnka

    Inventor： Robert H. Grubbs ,  Melanie S. Sanford ,  Jason L. Moore ,  Jennifer A. Love ,  Tina M. Trnka

    IPC: B01J3100

    CPC classification number: C07C6/04 ,  B01J23/462 ,  B01J23/466 ,  B01J31/181 ,  B01J31/1815 ,  B01J31/182 ,  B01J31/1825 ,  B01J31/183 ,  B01J31/2273 ,  B01J31/28 ,  B01J2231/14 ,  B01J2231/543 ,  B01J2531/821 ,  B01J2531/825 ,  C07C6/06 ,  C07C2531/22 ,  C07F15/002 ,  C07F15/0046 ,  C08G61/06

    Abstract: The present invention relates to novel hexacoordinated metathesis catalysts and to methods for making and using the same. The inventive catalysts are of the formula wherein: M is ruthenium or osmium; X and X1 are the same or different and are each independently an anionic ligand; L, L1′ and L2 are the same or different and are each independently a neutral electron donor ligand; and, R and R1 are each independently hydrogen or a substituent selected from the group consisting of C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkynyl, aryl, C1-C20 carboxylate, C1-C20 alkoxy, C2-C20 alkenyloxy, C2-C20 alkynyloxy, aryloxy, C2-C20 alkoxycarbonyl, C1-C20 alkylthio, C1-C20 alkylsulfonyl and C1-C20 alkylsulfinyl and silyl. Optionally, each of the R or R1 substituent group may be substituted with one or more moieties selected from the group consisting of C1-C10 alkyl, C1-C10 alkoxy, and aryl which in turn may each be further substituted with one or more groups selected from a halogen, a C1-C5 alkyl, C1-C5 alkoxy, and phenyl. Moreover, any of the catalyst ligands may further include one or more functional groups. Examples of suitable functional groups include but are not limited to: hydroxyl, thiol, thioether, ketone, aldehyde, ester, ether, amine, imine, amide, nitro, carboxylic acid, disulfide, carbonate, isocyanate, carbodiimide, carboalkoxy, carbamate, halogen, alcohol, sulfonic acid, phosphine, imide, acetal, ketal, boronate, cyano, cyanohydrin, hydrazine, enamine, sulfone, sulfide, and sulfenyl. In certain embodiments, at least one of L, L1′ and L2 is an N-heterocyclic carbene ligand.

    Abstract translation: 本发明涉及新型六配位复分解催化剂及其制备和使用方法。 本发明的催化剂为糠醛：M是钌或锇; X和X 1相同或不同，各自独立地为阴离子配位体; L，L 1和L 2相同或不同 并且各自独立地为中性电子给体配体; 和R 1和R 2各自独立地为氢或选自C 1 -C 20烷基，C 2 -C 20烯基，C 2 -C 20炔基，芳基，C 1 -C 20羧酸酯，C 1 -C 20烷氧基， C20链烯氧基，C2-C20炔氧基，芳氧基，C2-C20烷氧基羰基，C1-C20烷硫基，C1-C20烷基磺酰基和C1-C20烷基亚磺酰基和甲硅烷基。 任选地，R或R ​​1取代基中的每一个可以被一个或多个选自以下的部分取代：C 1 -C 10烷基，C 1 -C 10烷氧基和芳基，其又可以进一步被一个或多个 更多选自卤素，C 1 -C 5烷基，C 1 -C 5烷氧基和苯基的基团。 此外，任何催化剂配体还可以包括一个或多个官能团。 合适的官能团的实例包括但不限于：羟基，硫醇，硫醚，酮，醛，酯，醚，胺，亚胺，酰胺，硝基，羧酸，二硫化物，碳酸酯，异氰酸酯，碳二亚胺，碳烷氧基，氨基甲酸酯，卤素 醇，磺酸，膦，酰亚胺，缩醛，缩酮，硼酸酯，氰基，氰醇，肼，烯胺，砜，硫化物和亚磺酰基。 在某些实施方案中，L，L'和L 2中的至少一个是N-杂环卡宾配体。

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