公开(公告)号：US20150353655A1

公开(公告)日：2015-12-10

申请号：US14653961

申请日：2013-12-10

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Andreas Maus ,  Gerhardus Meier ,  Gianni Collina ,  Diego Brita

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F2/14 ,  C08F10/02 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/14

Abstract: The present invention relates to a slurry process for preparing an ethylene polymer having a melt flow ratio F/P, which is the ratio among the melt index value measured according to ASTM 1238 condition “F” and the melt index value measured according to ASTM 1238 condition “P” of equal to or lower than 27, carried out in two or more stages of polymerization at temperatures in the range from 60 to 120° C., in which at least two of the said two or more polymerization stages are carried out under different amounts of molecular weight regulator, said process being carried out in the presence of (A) a solid catalyst component comprising Ti, Mg, halogen, having a porosity (PF), measured by the mercury method and due to pores with radius equal to, or lower than, 1 μm, of at least 0.3 cm3/g and a surface area determined by BET method, of lower than 100 m2/g, and being further characterized by the fact that more than 50% of the titanium atoms are in a valence state lower than 4 and (B) of an organoaluminum compound.

Abstract translation: 本发明涉及一种用于制备熔体流动比F / P的乙烯聚合物的浆料方法，其是根据ASTM 1238条件“F”测量的熔体指数与根据ASTM 1238测量的熔体指数之间的比率 条件“P”等于或低于27，在60至120℃的温度下在两个或更多个聚合阶段进行，其中至少两个所述两个或更多个聚合阶段被执行 在不同量的分子量调节剂下，所述方法在（A）包含通过汞法测量的具有孔隙率（PF）的Ti，Mg，卤素的固体催化剂组分的存在下进行，并且由于具有半径相等的孔 至少为0.3cm 3 / g，BET法测定的表面积低于100m2 / g，进一步的特征在于，超过50％的钛原子为 在低于4的价态下，（B） 的有机铝化合物。

公开(公告)号：US20150344594A1

公开(公告)日：2015-12-03

申请号：US14654201

申请日：2013-12-11

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Benedetta Gaddi ,  Gianni Collina ,  Daniele Evangelisti

IPC: C08F110/06 ,  C07F3/02

CPC classification number: C08F110/06 ,  C07F3/02 ,  C08F2/00 ,  C08F4/6548 ,  C08F10/06 ,  C08F10/00 ,  C08F4/6543 ,  C08F4/651 ,  C08F4/6465 ,  C08F2500/18

Abstract: Spherical adducts comprising a MgCl2, an alcohol ROH in which R is a C1-C10 hydrocarbon group, present in a molar ratio with MgCl2 ranging from 0.5 to 6 and less than 20% mol based on the mol of MgCl2 of a compound of formula Mg(OR1)2 in which R1 is selected from C1-C10 alkyl groups or R2CO groups in which R2 is selected from C1-C6 alkyl or aryl groups.

Abstract translation: 以MgCl 2，其中R为C1-C10烃基的醇ROH为基础的球形加合物，其中MgCl 2的摩尔比为0.5-6，小于20mol％，相对于式Mg化合物的MgCl 2的摩尔数 （OR1）2，其中R1选自C1-C10烷基或R2CO基，其中R2选自C1-C6烷基或芳基。

公开(公告)号：US09181424B2

公开(公告)日：2015-11-10

申请号：US14349711

申请日：2012-10-05

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Gisella Biondini ,  Marco Ciarafoni ,  Paola Massari ,  Roberto Pantaleoni

IPC: C08L23/00 ,  C08L23/10 ,  C08L23/06 ,  C08L23/14

CPC classification number: C08L23/14 ,  C08L23/142 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2205/24 ,  C08L2314/02 ,  C08L2666/06

Abstract: Propylene polymer compositions comprising: A) from 70 wt % to 95 wt %, of a random copolymer of propylene with ethylene, containing from 1.5 wt % to 4.5 wt %, of ethylene derived units, having a content of fraction insoluble in xylene at 25° C. of not less than 93%; B) from 5 wt % to 35 wt %, of a copolymer of propylene with ethylene, containing from 7.0 wt % to 17.0 wt % of ethylene derived units; the sum A+B being 100; wherein the melt flow rate, MFR. (Melt Flow Rate according to ASTM 1238, condition L, i.e. 230° C. and 2.16 kg load) ranges from 40 g/10 min and 130 g/10 min; and wherein the relation (I) is fulfilled: 10

Abstract translation: 丙烯聚合物组合物，其包含：A）70重量％至95重量％的丙烯与乙烯的无规共聚物，其含有1.5重量％至4.5重量％的乙烯衍生单元，其含量在25℃不溶于二甲苯 ℃不低于93％; B）5重量％至35重量％的丙烯与乙烯的共聚物，其含有7.0重量％至17.0重量％的乙烯衍生单元; 总和A + B为100; 其中熔体流动速率MFR。 （根据ASTM 1238的熔体流动速率，条件L，即230℃和2.16kg负荷）为40g / 10min和130g / 10min; 并且其中满足关系式（I）：10

公开(公告)号：US20150284488A1

公开(公告)日：2015-10-08

申请号：US14436412

申请日：2013-10-03

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Monica Galvan ,  Andreas Neumann ,  Tiziana Caputo ,  Stefano Squarzoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/26

Abstract: A process for the preparation of random copolymer of propylene containing up to 6.0% by weight of ethylene units, suitable for the manufacture of pipes, by copolymerizing propylene and ethylene in the presence of a catalyst system comprising the product obtained by contacting the following components:(a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers,(b) an aluminum hydrocarbyl compound, and(c) optionally an external electron donor compound.

Abstract translation: 一种制备含有至多6.0重量％乙烯单元的丙烯无规共聚物的方法，该乙烯单元通过在包含通过接触以下组分获得的产物的催化剂体系存在下共聚丙烯和乙烯来制备管道： （a）固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种以相对于总量为40至90摩尔％的量存在 选自琥珀酸盐，另一种选自1,3-二醚，（b）铝烃基化合物，和（c）任选的外电子给体化合物。

公开(公告)号：US20150232588A1

公开(公告)日：2015-08-20

申请号：US14429585

申请日：2013-09-05

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Enrico Balestra ,  Tiziana Caputo ,  Maurizio Dorini ,  Antonio Mazzucco ,  Silvia Soffritti

IPC: C08F10/06 ,  B01J19/24

CPC classification number: C08F10/06 ,  B01J8/24 ,  B01J8/26 ,  B01J8/388 ,  B01J19/24 ,  B01J2208/00274 ,  B01J2208/00283 ,  B01J2208/00734 ,  B01J2219/00164 ,  B01J2219/24 ,  C08F10/00 ,  C08F210/06 ,  C08F2/34 ,  C08F2/005 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2/01

Abstract: A process and apparatus for producing olefin polymers are disclosed, comprising:a. polymerizing one or more olefins in the gas phase, in the presence of an olefin polymerization catalyst, whereby growing polymer particles flow along a cylindrically-shaped downward path in densified form under the action of gravity so as to form a densified bed of downward-flowing polymer particles b. allowing said polymer particles to flow through a restriction of the densified bed, such restriction being positioned in a restriction zone extending from the bed upward to a distance of 15% of the total height of the densified bed; and c. metering an antistatic agent through a feed line connected to the densified bed at a feed point being located in a feed zone extending from the top of the restriction upward, to a distance five times the diameter of the section of the densified bed above the restriction.

Abstract translation: 公开了一种用于生产烯烃聚合物的方法和设备，包括：a。 在气相中聚合一种或多种烯烃，在烯烃聚合催化剂的存在下，由此生长的聚合物颗粒在致密形式的重力作用下沿着圆柱形的向下的路径流动，以形成向下流动的致密化床 聚合物颗粒b。 允许所述聚合物颗粒流过致密化床的限制，这种限制被定位在从床向上延伸到致密化床的总高度的15％的距离的限制区域中; 和c。 通过连接到致密化床的供给管线的计量抗静电剂，所述供给管线位于从限制件的顶部向上延伸的进料区域中的进料点，距离所述限制物上方的致密化床部分的直径的五倍。

公开(公告)号：US20150191852A1

公开(公告)日：2015-07-09

申请号：US14408023

申请日：2013-06-13

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Monica Galvan ,  Andreas Neumann ,  Roberto Pantaleoni ,  Antonio Mazzucco ,  Ofelia Fusco ,  Benedetta Gaddi ,  Gianni Collina

IPC: D01F6/06 ,  D04H3/016 ,  D04H3/007 ,  B29C47/00 ,  D04H3/16

Abstract: Fibers comprising a polypropylene obtainable by a process comprising the steps of: (i) polymerizing propylene in the presence of a catalyst system comprising the product obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum hydrocarbyl compound, and (c) optionally an external electron donor compound, to obtain a polypropylene precursor having a melt flow rate MFR1; (ii) subjecting the thus-obtained polypropylene precursor to visbreaking to obtain a visbroken polypropylene having a melt flow rate MFR2; (iii) spinning the visbroken polypropylene obtained in the previous step; wherein MFR2 is comprised between from 15 to 40 g/10 min, the ratio MFR2/MFR1 is comprised between 8 and 18, both MFR1 and MFR2 being measured according to ISO method 1133 (230° C., 2.16 kg).

Abstract translation: 包含聚丙烯的纤维包括以下步骤：（i）在催化剂体系存在下聚合丙烯，所述催化剂体系包含通过使以下组分接触获得的产物：（a）固体催化剂组分，其包含卤化镁，钛化合物 具有至少一个Ti-卤素键和至少两个电子给体化合物，其中一种以相对于供体总量为40-90％摩尔量存在，选自琥珀酸盐，另一种选自1， 3个二醚，（b）铝烃基化合物和（c）任选的外电子给体化合物，得到熔体流动速率MFR 1的聚丙烯前体; （ii）将由此获得的聚丙烯前体进行减粘裂化以得到熔体流动速率MFR 2的减粘裂化聚丙烯; （iii）纺丝上一步获得的耐磨破坏聚丙烯; 其中MFR 2在15至40g / 10min之间，MFR 2 / MFR 1的比率在8和18之间，MFR 1和MFR 2均根据ISO方法1133（230℃，2.16kg）测量。

公开(公告)号：US20150141594A1

公开(公告)日：2015-05-21

申请号：US14406470

申请日：2013-06-05

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Alessandro Mignogna ,  Simona Guidotti ,  Igor Kashulin ,  Giampiero Morini ,  Ilya Nifant'ev ,  Joachim T.M. Pater

IPC: C08F4/52 ,  C08F4/16 ,  C08F4/10

CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

Abstract: A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C1-C15 hydrocarbon groups, the R1-R2 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.

Abstract translation: 包含Mg，Ti和其中R基彼此相同或不同的下式（I）的电子给体化合物的烯烃聚合催化剂组分是C 1 -C 15烃基，R 1 -R 2基， 相同或不同的是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N和Si的杂原子，其可以一起稠合形成一个或多个循环; n和m是0-3的整数，条件是它们中的至少一个不同于0，并且排除邻苯二乙酸二异丁酯。

公开(公告)号：US20150087770A1

公开(公告)日：2015-03-26

申请号：US14402262

申请日：2013-05-21

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Roberta Marzolla ,  Monica Galvan ,  Tiziana Caputo

IPC: C08F210/06 ,  C08J5/18

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08J2323/12 ,  C08J2323/14 ,  C08L23/14 ,  C08L23/142 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/26

Abstract: A propylene, ethylene, 1-butene terpolymer containing from 0.5 wt % to 2.2 wt % of ethylene derived units and from 6.0 wt % to 20.0 wt % of 1 butene derived units; wherein: i) the ratio C2 wt %/C4 wt % ranges from 0.09 to 0.06; wherein C2 wt % is the weight per cent of ethylene derived units and C4 wt % is the weight per cent of 1-butene derived units; ii) the Melt flow rate ranges from 0.4 to 54 g/10 min; iii) the xylene soluble fraction at 25° C. is lower than 15.0 wt % the minimum value being 5.0 wt %.

Abstract translation: 含有0.5重量％至2.2重量％的乙烯衍生单元和6.0重量％至20.0重量％的1-丁烯衍生单元的丙烯，乙烯，1-丁烯三元共聚物; 其中：i）C2重量％/ C4重量％的比率范围为0.09至0.06; 其中C2重量％是乙烯衍生单元的重量百分比，C4重量％是1-丁烯衍生单元的重量百分数; ii）熔体流动速率范围为0.4至54g / 10min; iii）25℃下的二甲苯可溶级分低于15.0wt％，最小值为5.0wt％。

公开(公告)号：US20150051351A1

公开(公告)日：2015-02-19

申请号：US14384939

申请日：2013-03-12

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Mara Destro ,  Marco Ciarafoni ,  Paola Massari ,  Stefano Squarzoni

IPC: C08L23/14

CPC classification number: C08L23/14 ,  B29C48/022 ,  B29C48/08 ,  B29C48/40 ,  C08L23/142 ,  C08L2201/10 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2314/02 ,  C08F210/06 ,  C08F4/6545 ,  C08F2/001 ,  C08F4/6465 ,  C08F4/651 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/26

Abstract: Propylene polymer compositions comprising: A) from 70 wt % to 95 wt %, of a random copolymer of propylene with ethylene, containing from 3.5 wt % to 6.5 wt % of ethylene derived units, having a content of fraction insoluble in xylene at 25° C. of not less than 93 wt %; B) from 5 wt % to 35 wt %, of a copolymer of propylene with ethylene, containing from 8.5 Wt % to 17.0 wt % of ethylene derived units; the sum A+B being 100; the melt flow rate ,MFR (ISO 1133 (230° C., 2.16 kg) ranges from 0.6 g/10 min to 20.2 g/10 min.

Abstract translation: 丙烯聚合物组合物，其包含：A）70重量％至95重量％的丙烯与乙烯的无规共聚物，其含有3.5重量％至6.5重量％的乙烯衍生单元，其含量在25℃不溶于二甲苯 C.不小于93wt％; B）5重量％至35重量％的丙烯与乙烯的共聚物，其含有8.5重量％至17.0重量％的乙烯衍生单元; 总和A + B为100; 熔体流动速率MFR（ISO 1133（230℃，2.16kg））为0.6g / 10min至20.2g / 10min。

公开(公告)号：US20140316083A1

公开(公告)日：2014-10-23

申请号：US14365357

申请日：2012-12-11

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： Diego Brita ,  Gianni Collina ,  Giampiero Morini

IPC: C08F10/02

CPC classification number: C08F10/02 ,  C08F10/00 ,  C08F4/6492 ,  C08F110/06 ,  C08F4/651

Abstract: A pre-polymerized catalyst component for the polymerization of olefins endowed with high activity and morphological stability comprises a non-stereospecific solid catalyst component containing Ti, Mg and a halogen, and an amount of an ethylene/alpha-olefin block (co)polymer ranging from 0.1 up to 5 g per g of said solid catalyst component, said prepolymerized catalyst component being characterized by a mercury porosity, due to pores having radius up to 1 μm, ranging from 0.15 to 0.5 cm3/g and by the fact that at least 55% of said porosity is due to pores having pore radius up to 0.2 μm.

Abstract translation: 用于聚合具有高活性和形态稳定性的烯烃聚合的预聚合催化剂组分包括含有Ti，Mg和卤素的非立体特异性固体催化剂组分和一定量的乙烯/α-烯烃嵌段（共）聚合物范围 0.1至5g / g所述固体催化剂组分，所述预聚催化剂组分的特征在于水银孔隙率，由于孔径半径为1μm，范围为0.15至0.5cm 3 / g，并且至少 所述孔隙率的55％是由于孔半径高达0.2μm的孔。