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公开(公告)号：US06872300B1
公开(公告)日：2005-03-29
申请号：US10113125
申请日：2002-03-29
IPC分类号： B01J23/656 , B01J37/00 , B01J37/02 , B01J37/24 , C10G35/085 , C10G35/09 , B01J23/40
CPC分类号： C10G35/09 , B01J23/6567 , B01J35/0093 , B01J37/0009 , B01J37/0207 , B01J37/24 , C10G35/085
摘要： A process for preparing a naphtha reforming catalyst has been developed. The process involves the use of a chelating ligand such as ethylenediaminetetraacetic acid (EDTA). The aqueous solution of the chelating ligand and a tin compound is used to impregnate a support, e.g., alumina extrudates. A platinum-group metal is also an essential component of the catalyst. Rhenium may also be a component. A reforming process using the catalyst has enhanced yield, activity, and stability for conversion of naphtha into valuable gasoline and aromatic products.
摘要翻译： 已经开发了制备石脑油重整催化剂的方法。 该方法包括使用螯合配体如乙二胺四乙酸（EDTA）。 螯合配体和锡化合物的水溶液用于浸渍载体，例如氧化铝挤出物。 铂族金属也是催化剂的重要组成部分。 铼也可以是组分。 使用该催化剂的重整方法具有提高的石脑油转化成贵重汽油和芳香族产物的产率，活性和稳定性。
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公开(公告)号：US06646159B2
公开(公告)日：2003-11-11
申请号：US09746585
申请日：2000-12-21
申请人： Lance A. Baird , Leonid B. Galperin , R. Joe Lawson , Robert H. Jensen , Oleg L. Eliseev , Albert L. Lapidus , Aduard G. Ostapenco
发明人： Lance A. Baird , Leonid B. Galperin , R. Joe Lawson , Robert H. Jensen , Oleg L. Eliseev , Albert L. Lapidus , Aduard G. Ostapenco
IPC分类号： C07C51114
CPC分类号： C07C51/14 , C07C29/149 , C07C53/126 , C07C31/125
摘要： Long chain alcohols and acids or other similar oxygenates such as esters are produced from paraffins of similar carbon number by a process comprising paraffin dehydrogenation, carbonylation, and separation. Preferably a mixture of paraffins extending over several carbon numbers and recovered from a kerosene fraction is processed, and unconverted paraffins are recycled to a dehydrogenation zone. Alternative reaction zone configurations, catalyst systems and product recovery methods are disclosed.
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23.发明授权Hydrogen generation via methane cracking for integrated heat and electricity production using a fuel cell 失效使用燃料电池进行集成热电生产的甲烷裂解产生氢气公开(公告)号：US06506510B1
公开(公告)日：2003-01-14
申请号：US09737990
申请日：2000-12-15
申请人： Daniel R. Sioui , Gavin P. Towler , Anil R. Oroskar , Lubo Zhou , Stephen R. Dunne , Santi Kulprathipanja , Leonid B. Galperin , Frank S. Modica , Timur V. Voskoboinikov
发明人： Daniel R. Sioui , Gavin P. Towler , Anil R. Oroskar , Lubo Zhou , Stephen R. Dunne , Santi Kulprathipanja , Leonid B. Galperin , Frank S. Modica , Timur V. Voskoboinikov
IPC分类号： H01M804
CPC分类号： H01M8/04014 , H01M8/0612
摘要： A novel integrated system for the co-production of heat and electricity for residences or commercial buildings is based on the cracking of hydrocarbons to generate hydrogen for a fuel cell. Compared to prior art reforming methods for hydrogen production, the cracking reaction provides an input stream to the fuel cell that is essentially free of CO, a known poison to the anode catalyst in many fuel cell designs, such as PEM fuel cells. The cracking reaction is coupled with an air or steam regeneration cycle to reactivate that cracking catalyst for further use. This regeneration can provide a valuable source of heat or furnace fuel to the system. A novel control method for system adjusts the durations of the cracking and regeneration cycles to optimize the recovery of reaction heat.
摘要翻译： 用于住宅或商业建筑共同生产热电的新型综合系统是基于碳氢化合物的裂解以产生燃料电池的氢气。 与现有技术的用于氢气生产的重整方法相比，裂化反应为燃料电池提供基本上不含CO的输入流，这是许多燃料电池设计中的阳极催化剂的已知毒物，例如PEM燃料电池。 裂化反应与空气或蒸汽再生循环相结合，使该裂化催化剂再次使用。 这种再生可以为系统提供有价值的热源或炉燃料。 一种新颖的系统控制方法，可以调节裂解和再生循环的持续时间，以优化反应热的回收。
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公开(公告)号：US06383967B1
公开(公告)日：2002-05-07
申请号：US09431857
申请日：1999-11-02
IPC分类号： B01J2906
CPC分类号： B01J29/40 , B01J2229/42 , C07C6/123 , C07C2521/04 , C07C2523/08 , C07C2523/18 , C07C2523/36 , C07C2527/167 , C07C2529/40
摘要： A zeolitic catalyst useful in the selective disproportionation and transalkylation of toluene comprises a molecular sieve having a pore diameter of about 5 to 8 Å, a refractory inorganic oxide and a reduced weak non-framework metal which is believed to provide Lewis acidity.
摘要翻译： 可用于甲苯的选择性歧化和烷基转移的沸石催化剂包括孔径为约5至8的分子筛，耐火无机氧化物和被认为提供路易斯酸度的还原的弱非骨架金属。
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公开(公告)号：US5905181A
公开(公告)日：1999-05-18
申请号：US998930
申请日：1997-12-29
申请人： Leonid B. Galperin
发明人： Leonid B. Galperin
CPC分类号： C07C5/2724 , C07C5/2791 , C07C2521/12 , C07C2529/66 , C07C2529/70 , C07C2529/85
摘要： A paraffin isomerization process is described and claimed. The process involves contacting the paraffins with an isomerization catalyst at isomerization conditions. Additionally, the process requires the injection of a nitrogen containing compound such as an amine, e.g., t-butylamine, and raising the operating temperature by about 20.degree. C. to about 150.degree. C. The effect of these modifications is to provide improved selectivity and sulfur resistance to the catalyst.
摘要翻译： 链烷烃异构化方法被描述和要求保护。 该方法包括在异构化条件下使链烷烃与异构化催化剂接触。 此外，该方法需要注入含氮化合物如胺，例如叔丁胺，并将操作温度提高约20℃至约150℃。这些修饰的效果是提供改善的选择性 和对催化剂的耐硫性。
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公开(公告)号：US5851949A
公开(公告)日：1998-12-22
申请号：US922016
申请日：1997-09-02
IPC分类号： B01J29/12 , B01J29/85 , B01J23/44 , B01J29/068
CPC分类号： B01J29/126 , B01J29/85 , B01J2229/26 , B01J2229/42
摘要： Applicants have developed a catalyst for various hydrocarbon conversion processes which is tolerant to the presence of large amounts of sulfur (1000 ppm) in the feedstream. The catalyst consists of a molecular sieve support such as MeAPSO or zeolite Y that has dispersed thereon palladium and a modifier such as lanthanum.
摘要翻译： 申请人已经开发了用于各种烃转化方法的催化剂，其耐受在进料流中大量的硫（1000ppm）的存在。 催化剂由分子筛载体如MeAPSO或沸石Y组成，其上分散有钯和改性剂如镧。
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公开(公告)号：US5770042A
公开(公告)日：1998-06-23
申请号：US550694
申请日：1995-10-31
IPC分类号： C10G59/02 , C10G35/085
CPC分类号： C10G59/02 , Y10S585/94
摘要： A process combination is disclosed to selectively upgrade naphtha to obtain an isoparaffin-rich product for blending into gasoline. A naphtha feedstock is subjected to ring cleavage to convert naphthenes to paraffins using a nonacidic catalyst followed by isomerization of paraffins to obtain an increased proportion of isoparaffins. Ring cleavage also may be effected on the product of isomerization and separation by fractionation or adsorption.
摘要翻译： 公开了一种方法组合以选择性地升级石脑油以获得用于混合成汽油的富含异链烷烃的产物。 将石脑油原料进行环切割，使用非酸催化剂将环烷烃转化成链烷烃，随后将链烷烃异构化，以获得比例增加的异链烷烃。 也可以通过分级或吸附来进行异构化和分离的产物进行环裂解。
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公开(公告)号：US5755956A
公开(公告)日：1998-05-26
申请号：US766264
申请日：1996-12-13
IPC分类号： B01J29/068 , B01J29/62 , C10G35/095 , C07C5/00
CPC分类号： C10G35/095 , B01J29/068 , B01J29/62 , B01J2229/26 , B01J2229/42
摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a catalyst containing multiple Group VIII (8-10) noble metals having different gradients within the catalyst and a nonacidic large-pore molecular sieve. The use of this bed of catalyst results in greater selectivity of conversion of paraffins to aromatics and improved catalyst stability, particularly in the presence of small amounts of sulfur.
摘要翻译： 使用在催化剂中含有不同梯度的多种VIII族（8-10）贵金属的催化剂和非酸性大孔分子筛，可以选择性地将烷烃脱氢环化成芳族化合物的重整方法。 使用这种催化剂床导致链烷烃转化为芳族化合物的更大选择性和改进的催化剂稳定性，特别是在少量硫的存在下。
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公开(公告)号：US5614454A
公开(公告)日：1997-03-25
申请号：US445620
申请日：1995-05-22
IPC分类号： B01J29/068 , B01J29/62 , B01J35/00 , C10G35/095 , B01J29/60 , B01J29/68
CPC分类号： C10G35/095 , B01J29/068 , B01J29/62 , B01J35/0006 , B01J2229/26 , B01J2229/42 , B01J35/008
摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a catalyst containing multiple Group VIII (8-10) noble metals having different gradients within the catalyst and a nonacidic large-pore molecular sieve. The use of this bed of catalyst results in greater selectivity of conversion of paraffins to aromatics and improved catalyst stability, particularly in the presence of small amounts of sulfur.
摘要翻译： 使用在催化剂中含有不同梯度的多种VIII族（8-10）贵金属的催化剂和非酸性大孔分子筛，可以选择性地将烷烃脱氢环化成芳族化合物的重整方法。 使用这种催化剂床导致链烷烃转化为芳族化合物的更大选择性和改进的催化剂稳定性，特别是在少量硫的存在下。
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公开(公告)号：US5384038A
公开(公告)日：1995-01-24
申请号：US194973
申请日：1994-02-14
申请人： Leonid B. Galperin
发明人： Leonid B. Galperin
IPC分类号： B01J23/40 , B01J29/04 , B01J29/068 , B01J29/60 , B01J29/62 , B01J35/00 , C07C15/02 , C10G35/085 , C10G35/095 , C07C5/00
CPC分类号： C10G35/095 , B01J29/068 , B01J29/62 , B01J35/0006 , B01J2229/26 , B01J2229/42
摘要： A reforming process, selective for the dehydrocyclization of paraffins to aromatics, is effected using a bed of catalyst particles containing multiple Group VIII (8-10) noble metals having different gradients within the catalyst particles and a nonacidic large-pore molecular sieve. The use of this bed of catalyst particles results in greater selectivity of conversion of paraffins to aromatics and improved catalyst stability, particularly in the presence of small amounts of sulfur.
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