摘要:
Compounds useful as additives for lubricants, hydraulic oils and metal-working fluids include those of formula IV ##STR1## where R.sup.1 and R.sup.2 are independently alkyl or substituted aryl, R.sup.3 and R.sup.13 are independently hydrogen or methyl, R.sup.6 is alkyl, alkenyl, aralkyl or substituted benzyl, and R.sup.15 and R.sup.16 are independently hydrogen, alkyl, aryl or aralkyl.
摘要:
There is disclosed a process for the preparation of compounds of formula I or II ##STR1## from phenols by reaction with formaldehyde and mercaptans in the presence of mono-, di- or trimethylamine or mono- or diethylamine.The symbols R.sub.1 is alkyl, hydroxy or alkoxycarbonyl substituted alkyl; alkyl; aryl, cycloalkyl or aralkyl, R.sub.2 is hydrogen, alkyl, alkenyl or halogen, R.sub.3 and R.sub.4 are independently alkyl, allyl, cycloalkyl, phenyl, benzyl, halogen or --CH.sub.2 --S--R.sub.1, Z.sub.1 is --S-- or alkylene, and Z.sub.2 is hydrogen, alkyl or --CH.sub.2 --S--R.sub.1.The mercaptomethylphenols are valuable antioxidants for plastics, elastomers, mineral oils and synthetic lubricants.
摘要:
Composition containing(a) at least one lubricant, hydraulic oil or metal-working fluid based on mineral oil or synthetic oils and(b) 0.05-5% by weight, based on the total weight of the lubricant, hydraulic oil or metal-working fluid composition, of at least one compound of the formula II ##STR1## where R.sup.1 and R.sup.2 are independently alkyl, aryl, subsituted aryl or benzyl, R.sup.3 is hydrogen or methyl, R.sup.4 and R.sup.5 are independently hydrogen, methyl, methoxy, chloro or nitro, R.sup.7 is hydrogen or methyl, R.sup.8 is hydrogen, alkyl, alkylthiomethyl or alkylene, R.sup.9 is hydrogen or methyl and n is 1 to 4.
摘要:
Novel o-bridged polynuclear polyphenols of the formula I ##STR1## which contain at least one organic radical, such as alkyl, cycloalkyl or aryl, per phenyl nucleus and are formed by condensation of the monomeric phenolic components with customary bridging reagents, such as formaldehyde, acetone or sulfur dichloride, or by oxidative coupling of the monomeric phenolic components, and which, depending on the reaction procedure, can contain between 2 and 50 monomer units, are described.The substances according to the invention can be used for stabilizing plastics from oxidative degradation and have a good resistance to extraction.
摘要:
Compounds of the formula I ##STR1## wherein R.sub.1 and R.sub.2 independently of one another are substituted or unsubstituted hydrocarbon radicals, or halogen,x and y independently of one another are 0, 1, 2 or 3, andA is a substituted primary or secondary aliphatic or alicyclic, aromatic or araliphatic amine, in which the substituents are identical or different, a heterocyclic amine or a hydrazine derivative.
摘要:
New 1,3,5-triazines containing at least one hindered phenolic moiety and at least one hindered amine moiety are useful light stabilizers and antioxidants for polymeric materials.
摘要:
In an electric cell having a solid electrolyte which bounds on one side a mpartment for liquid anode and on its opposite side a compartment for liquid cathode, the liquid anode compartment is made of very limited capacity. The bulk of the liquid anode required by the cell is held in a reservoir and fed to the liquid anode compartment by a capillary duct to provide a restricted feed which limits the flow of liquid anode therebetween. The reservoir may be disposed within the cell, or outside the cell, and may supply liquid anode to several cells.
摘要:
In a sodium-sulphur battery cell, an extended surface area current collector is sandwiched between portions of solid electrolyte, also of extended surface area, which provide between them a space for the liquid sulphur. The spacing between the current collector and each of the portions does not exceed the maximum distance that the sodium ions can diffuse in the liquid sulphur during a specified recharge time. A plurality of portions defining a plurality of spaces for the liquid sulphur may be provided, each space having an extended surface area current collector sandwiched between the portions defining the space.A plurality of these battery cells may be arranged so that they are separated one from another by a bipolar electrode to provide a series connection.
摘要:
This invention relates to a process for stabilising and at the same time phase compatibilising plastics or plastic compositions by incorporating polymeric compounds obtainable by reacting a compound selected from the group consisting of the sterically hindered phenols, sterically hindered amines, lactones, sulfides, phosphites, benzotriazoles, benzophenones and 2-(2-hydroxyphenyl)-1,3,5-triazines, which compounds contain at least one reactive group, with a compatibilisator.
摘要:
This invention relates to a process for stabilising and at the same time phase compatibilising plastics or plastic compositions by incorporating polymeric compounds obtainable by reacting a compound selected from the group consisting of the sterically hindered phenols, sterically hindered amines, lactones, sulfides, phosphites, benzotriazoles, benzophenones and 2-(2-hydroxyphenyl)-1,3,5-triazines, which compounds contain at least one reactive group, with a compatibilisator.