公开(公告)号：US5629076A

公开(公告)日：1997-05-13

申请号：US624531

申请日：1996-06-24

Applicant: Yoshihito Fukasawa ,  Satoshi Hashimoto

Inventor： Yoshihito Fukasawa ,  Satoshi Hashimoto

IPC: B29C44/50 ,  C08J9/04 ,  C08J9/00 ,  B32B3/26

CPC classification number: C08J9/04 ,  B29C44/50 ,  C08J2323/12 ,  Y10T428/249953

Abstract: Disclosed is an extruded propylene polymer resin foam comprising a propylene polymer resin exhibiting a biaxial extensional viscosity of at least 3.0.times.10.sup.6 poise at a biaxial extensional strain of 0.2, and a biaxial strain hardening rate .alpha. of at least 0.25, the biaxial strain hardening rate .alpha. being defined by the following formula:.alpha.=0.77.times.(log .eta..sub.2 -log .eta..sub.1)wherein .eta..sub.1 represents the biaxial extensional viscosity at a biaxial extensional strain of 0.01, and .eta..sub.2 represents the biaxial extensional viscosity at a biaxial extensional strain of 0.2,said foam containing a vast plurality of cells, and having a thickness of at least 20 mm, a density of from 0.005 to 0.03 g/cm.sup.3, an average cell diameter of from 0.4 to 2.0 mm, and a closed cell ratio of at least 80%. The resin foam of the present invention has not only light weight, but also exhibits high cushioning performance and excellent mechanical strengths, so that, after fabricated into various sizes by cutting, the resultant resin foam articles can be advantageously used in the fields of cushion packaging materials, floating materials, and heat insulating materials.

Abstract translation: PCT No.PCT / JP95 / 00126 Sec。 371日期1996年6月24日 102（e）日期1996年6月24日PCT提交1995年1月31日PCT公布。 WO95 / 20622 PCT公开号 日期1995年8月3日公开是挤出的丙烯聚合物树脂泡沫，其包含丙烯聚合物树脂，其双轴拉伸应变为0.2，双轴拉伸粘度为至少3.0×10 6泊，双轴拉伸应变硬化率α至少为0.25， 双轴应变硬化率α由下式定义：α= 0.77x（log eta 2-log eta 1）其中eta 1表示双轴拉伸应变为0.01时的双轴拉伸粘度，eta 2表示双轴拉伸粘度 所述泡沫体含有大量的细胞，并且具有至少20mm的厚度，0.005-0.03g / cm 3的密度，0.4-2.0mm的平均泡孔直径，和 闭孔率至少为80％。 本发明的树脂发泡体不仅具有重量轻，而且还具有高的缓冲性能和优异的机械强度，因此通过切割将其制成各种尺寸之后，所得树脂发泡体制品可有利地用于缓冲包装领域 材料，浮动材料和绝热材料。

公开(公告)号：US5487788A

公开(公告)日：1996-01-30

申请号：US239887

申请日：1994-05-09

Applicant: Hideaki Kamiya ,  Satoshi Hashimoto ,  Satoru Matumoto

Inventor： Hideaki Kamiya ,  Satoshi Hashimoto ,  Satoru Matumoto

IPC: A61L2/03 ,  A61L12/02 ,  B08B3/10

CPC classification number: A61L12/023 ,  A61L2/035

Abstract: A method of cleaning and disinfecting a contact lens comprising immersing a contact lens in a treating solution, applying a direct current to the treating solution with repeatedly reversing a positive electrode and a negative electrode of a pair of electrodes plural times to generate peroxide and raise the temperature of the treating solution so that the interval of time before reversing is different from or equal to the interval of time after reversing to 50.degree. to 100.degree. C., and bringing the contact lens into direct contact with bubbles generated on the electrodes. Since this method is excellent in electrical safety and cleaning and disinfecting effects, contact lenses can be easily cleaned and disinfected.

Abstract translation: 一种清洁和消毒隐形眼镜的方法，包括将隐形眼镜浸入处理溶液中，通过多次反复地反转一对电极的正电极和负电极而向处理溶液施加直流以产生过氧化物，并提高 处理溶液的温度使反转前的时间间隔在反转到50〜100℃之后的时间间隔不等于或等于，并使隐形眼镜与电极上产生的气泡直接接触。 由于该方法具有优异的电气安全性和清洁消毒效果，因此可以容易地对隐形眼镜进行清洁和消毒。

公开(公告)号：US4131601A

公开(公告)日：1978-12-26

申请号：US839464

申请日：1977-10-04

Applicant: Satoshi Hashimoto ,  Nobuya Okumura ,  Kiyoshi Kazama

Inventor： Satoshi Hashimoto ,  Nobuya Okumura ,  Kiyoshi Kazama

IPC: C08G63/00 ,  B01J31/02 ,  B01J31/04 ,  C08G63/82 ,  C08G63/85 ,  C09D133/04 ,  C08G63/14

CPC classification number: C08G63/85 ,  B01J31/0212

Abstract: A process for the preparation of substantially linear, highly polymerized polyesters by polycondensing a glycol ester of an aromatic dicarboxylic acid and/or a low molecular weight condensate thereof, the process being characterized by using as a polycondensation catalyst a preformed titanate compound obtained by reacting a titanic acid ester represented by the formula Ti(OR).sub.4, where R is an alkyl group having from 1 to 5 carbon atoms, with an aromatic acid selected from the group consisting of trimellitic acid, trimellitic anhydride, hemimellitic acid, hemimellitic anhydride or a mixture of one or more thereof at a molar ratio of from about 0.5 to about 2.5 mols of the aromatic acid per 1 mol of the titanic acid ester, to thereby form polyesters which have a high softening point and good color tone. SUBACKGROUND OF THE INVENTION1. Field of the InventionThis invention relates to a process for the preparation of polyesters, in particular, to a process for the preparation of substantially linear, highly polymerized aromatic polyesters having a high softening point and good color tone.2. Description of the Prior ArtPolyesters obtained by reacting an aromatic dicarboxylic acid with a glycol have excellent mechanical, physical and chemical properties, and hence are widely used for fiber, film and other moulding materials. Among such polyesters, polyesters obtained by reacting an acid component consisting mainly of terephthalic acid with a glycol component selected from the group consisting of ethylene glycol, tetramethylene glycol, hexamethylene glycol and cyclohexane-1,4-dimethanol are especially important.In manufacturing the aforesaid polyesters--e.g., polyethylene terephthalate, conventional processing consists of heating the ethylene glycol ester of terephthalic acid and/or a low molecular weight condensate thereof under reduced pressure to effect polycondensation. In carrying out the polycondensation reaction on a commercial scale, catalysts are used to accelerate reaction. The rate of polycondensation and the qualities of the resulting polyester are greatly influenced by the kind(s) of catalyst(s) used.Titanium compounds are known as excellent catalysts for the above-described polycondensation reaction.For example, U.S. Pat. No. 2,822,348, Haslam, issued Feb. 4, 1958, discloses tetraisopropyltitanate, and British patent specification No. 793,111 to I.C.I. Limited, published Apr. 9, 1958, discloses an organic titanate, such as tetramethyl titanate and tetrabutyl titanate as a catalyst in the polycondensation reaction.Although titanium compounds result in a very rapid rate of polycondensation, they also result in the formation of polyesters having a distinctly yellow color and provide polyesters with a decreased softening point. Methods have also been proposed to avoid the disadvantage of yellowness in polyesters formed as described.For example, British Pat. No. 949,085 to I.C.I. Limited, published Feb. 12, 1964, discloses the use of a catalyst system which is the combination of a germanium compound (such as germanium tetraethoxide) and a titanium compound (such as titanium tetraisopropoxide or titanium tetrabutoxide) whereby the disadvantage of yellowness in the resulting polyester is considerably reduced. However, the rate of polycondensation is also reduced as compared to the use of a titanium compound alone. Further, this catalyst system is difficult to store for extended times because titanium compounds, such as titanium tetraisopropoxide or titanium tetrabutoxide, easily lose catalytic activity in the presence of a small amount of water.British Pat. No. 851,061 to Goodyear Tire & Rubber Co., published Oct. 12, 1960, discloses the use of preformed organic titanate compounds formed by the rection of titanic acid esters with polyhydroxy compounds, such as ethylene glycol lor tetramethylene glycol, polycarboxylic compounds, such as maleic acid, phthalic acid and trimesic acid, or hydroxy carboxylic compounds, such as lactic acid and hydroxy benzoic acid. In the preparation of polyesters, these preformed organic titanate compounds accelerate the rate of polymerization and permit the formation of polymers of high molecular weight. However, as a result of experiments performed by the present inventors, it was found that the preformed organic titanate compounds disclosed in this British patent do not fully overcome the disadvantage of yellowness of the obtained polyesters so as to provide a color tone suitable for commercial use. In addition, for example, the preformed organic titanate compound derived from phthalic acid does not sufficiently accelerate the rate of polymerization. Finally, it is difficult to uniformly react trimesic acid (benzene-1,3,5-tricarboxylic acid) with a titanic acid ester.SUMMARY OF THE INVENTIONIt has now been surprisingly found that if a preformed titanate compound obtained by reacting a titanic acid ester with an aromatic tricarboxylic acid having the capacity to form an anhydride is used as a catalyst in the polycondensation of an aromatic dicarboxylic acid with a glycol to form a polyester, the above-mentioned disadvantages of the prior art can be substantially overcome.It is, therefore, one object of the present invention to provide a process for the preparation of substantially linear, highly polymerized polyesters having a high softening point and good color tone.It is another object of the present invention to provide a process for the preparation of polyesters using a polycondensation catalyst which is easily obtained and storable for extended periods of time without degradation.The above-mentioned objects are attained by the process for the preparation of polyesters in accordance with the present invention, which comprises polycondensing a glycol ester of an aromatic dicarboxylic acid and/or a low molecular weight condensate thereof while removing glycol therefrom in the presence of a polycondensation catalyst which is preformed titanate compound obtained by reacting a titanic acid ester represented by the formula Ti(OR).sub.4, where R is an alkyl group having from 1 to 5 carbon atoms, with an aromatic acid selected from the group consisting of trimellitic acid (benzene-1,2,4-tricarboxylic acid), trimellitic anhydride, hemimellitic acid (benzene-1,2,3-tricarboxylic acid), hemimellitic anhydride or a mixture of one or more thereof.

Abstract translation: 通过使芳族二羧酸和/或其低分子量缩合物的二醇酯缩聚来制备基本上线性的高聚合聚酯的方法，该方法的特征在于使用预成型钛酸酯化合物作为缩聚催化剂， 由式Ti（OR）4表示的钛酸酯，其中R是具有1至5个碳原子的烷基，选自偏苯三酸，偏苯三酸酐，偏苯三酸，偏苯三酸酐或 其中一种或多种的摩尔比为每摩尔钛酸酯约0.5至约2.5摩尔芳族酸，从而形成具有高软化点和良好色调的聚酯。

公开(公告)号：US09748526B2

公开(公告)日：2017-08-29

申请号：US14004896

申请日：2012-03-09

Applicant: Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

Inventor： Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

IPC: C23C14/24 ,  H01L51/56 ,  C23C14/04 ,  C23C14/12 ,  H05B33/10

CPC classification number: H01L51/56 ,  C23C14/042 ,  C23C14/12 ,  C23C14/243 ,  H05B33/10

Abstract: A vapor deposition device (1) performs a vapor deposition treatment to form a luminescent layer (47) having a predetermined pattern on a film formation substrate (40). The vapor deposition device includes: a nozzle (13) having a plurality of injection holes (16) from which vapor deposition particles (17), which constitute the luminescent layer, are injected toward the film formation substrate when the vapor deposition treatment is carried out; and a plurality of control plates (20) provided between the nozzle and the film formation substrate and restricting an incident angle, with respect to the film formation substrate, of the vapor deposition particles injected from the plurality of injection holes. The nozzle includes: a nozzle main body (14b) in a container shape having an opening (14c) on a surface thereof on a film formation substrate side and (ii) a plurality of blocks (15) covering the opening and separated from each other, each of the plurality of blocks having the plurality of injection holes. The above arrangement allows a vapor-deposited film pattern to be formed with high definition.

公开(公告)号：US09299946B2

公开(公告)日：2016-03-29

申请号：US14008535

申请日：2012-03-27

Applicant: Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

Inventor： Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

IPC: H01L33/14 ,  H01L51/50 ,  H05B33/14 ,  H01L51/56 ,  H01L27/32 ,  H01L51/52

CPC classification number: H01L51/504 ,  H01L27/3213 ,  H01L27/3218 ,  H01L27/3244 ,  H01L51/5265 ,  H01L51/56 ,  H05B33/145

Abstract: TFT substrate (10) includes a plurality of pixel regions each including light emitting regions of at least three colors, which light emitting regions include light emitting layers (23R(1), 23G, 23R(2), and 23B), respectively, and two adjacent ones of the light emitting regions are a combination other than a combination of (i) a light emitting region included in a light emitting layer (23G) of a color having a highest current efficiency in a case where the light emitting layers of the light emitting regions of the at least three colors emit light having an identical luminance and (ii) a light emitting region included in a light emitting layer (23B) of a color having a lowest current efficiency in a case where the light emitting layers of the light emitting regions of the at least three colors emit light having an identical luminance.

Abstract translation: TFT基板（10）包括分别包括至少三种颜色的发光区域的多个像素区域，该发光区域分别包括发光层（23R（1），23G，23R（2）和23B），以及 两个相邻的发光区域是除了（i）包含在发光层（23G）中的发光区域的组合之外的组合，在发光层的发光层的情况下具有最高电流效率的颜色 所述至少三种颜色的发光区域发射具有相同亮度的光，以及（ii）包含在具有最低电流效率的颜色的发光层（23B）中的发光区域，在发光层的发光层 至少三种颜色的发光区域发射具有相同亮度的光。

公开(公告)号：US09297547B2

公开(公告)日：2016-03-29

申请号：US13497701

申请日：2010-09-17

Applicant: Gen Kumamoto ,  Satoshi Hashimoto

Inventor： Gen Kumamoto ,  Satoshi Hashimoto

IPC: F24F11/00 ,  F24F1/00 ,  F24F11/02

CPC classification number: F24F11/0078 ,  F24F1/0011 ,  F24F1/0014 ,  F24F11/30 ,  F24F11/64 ,  F24F11/65 ,  F24F11/72 ,  F24F11/79 ,  F24F11/85 ,  F24F13/1413 ,  F24F2001/0037 ,  F24F2110/10

Abstract: A control device controls a swing action of flaps of an air conditioning apparatus. The flaps are swung up and down. The control device includes an operation mode determining section, a swing pattern storage area and a control command generator. The operation mode determining section determines at least an air-cooling operation mode and an air-warming operation mode that are operation modes of the air conditioning apparatus. The swing pattern storage area stores a plurality of swing patterns that include information pertaining to the swing action. The control command generator generates a control command of the air conditioning apparatus on the basis of a swing pattern corresponding to the mode determined by the operation mode determining section from among the plurality of swing patterns.

Abstract translation: 控制装置控制空调装置的襟翼的摆动动作。 襟翼上下摆动。 控制装置包括操作模式确定部，摆动模式存储区和控制指令发生器。 操作模式确定部至少确定作为空调装置的操作模式的制冷运转模式和制热运转模式。 摆动图案存储区域存储包括与摆动动作有关的信息的多个摆动图案。 控制指令发生器根据与多个摆动模式中由操作模式确定部分确定的模式相对应的摆动模式，生成空调装置的控制命令。

公开(公告)号：US09240572B2

公开(公告)日：2016-01-19

申请号：US13984799

申请日：2012-03-02

Applicant: Shinichi Kawato ,  Satoshi Inoue ,  Tohru Sonoda ,  Satoshi Hashimoto

Inventor： Shinichi Kawato ,  Satoshi Inoue ,  Tohru Sonoda ,  Satoshi Hashimoto

IPC: H01L51/56 ,  C23C14/04 ,  C23C14/12 ,  C23C14/56 ,  C23C16/455 ,  H01L51/00

CPC classification number: H01L51/56 ,  C23C14/044 ,  C23C14/12 ,  C23C14/562 ,  C23C16/45578 ,  H01L51/0011

Abstract: A vapor deposition device includes a vapor deposition source (60) having a plurality of vapor deposition source openings (61) that discharge vapor deposition particles (91), a limiting unit (80) having a plurality of limiting openings (82), and a vapor deposition mask (70) in which a plurality of mask openings (71) are formed only in a plurality of vapor deposition regions (72) where the vapor deposition particles that have passed through a plurality of limiting openings reach. The plurality of vapor deposition regions are arranged along a second direction that is orthogonal to the normal line direction of the substrate (10) and the movement direction of the substrate, with non-vapor deposition regions (73) where the vapor deposition particles do not reach being sandwiched therebetween. Mask openings through which the vapor deposition particles pass are formed at different positions in the movement direction of the substrate from the positions of the non-vapor deposition regions located on a straight line parallel to the second direction, as viewed along the normal line direction of the substrate. Accordingly, it is possible to stably form a vapor deposition coating film in which edge blurring is suppressed at a desired position on a substrate.

Abstract translation: 蒸镀装置包括：蒸镀源（60），具有排出气相沉积粒子（91）的多个气相沉积源开口（61），具有多个限制开口（82）的限制单元（80） 气相沉积掩模（70），其中多个掩模开口（71）仅形成在已经通过多个限制孔的气相沉积颗粒到达的多个气相沉积区（72）中。 多个气相沉积区域沿着与基板（10）的法线方向正交的第二方向和基板的移动方向排列，其中气相沉积微粒不具有非气相沉积区域（73） 夹在其间。 沿着平行于第二方向的直线上的非蒸镀区域的位置，沿着基板的移动方向的不同位置，沿蒸镀粒子的法线方向 底物。 因此，可以稳定地形成在基板上的期望位置抑制边缘模糊的气相沉积涂膜。

公开(公告)号：US09076989B2

公开(公告)日：2015-07-07

申请号：US13976422

申请日：2011-12-20

Applicant: Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

Inventor： Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

IPC: H01L51/56 ,  H05B33/04 ,  H05B33/10 ,  H01L21/02 ,  H01L51/00 ,  C23C14/04 ,  C23C16/04 ,  H01L27/32

CPC classification number: H01L51/56 ,  C23C14/042 ,  C23C16/042 ,  H01L21/02104 ,  H01L27/3211 ,  H01L51/0011 ,  H01L2227/323 ,  H01L2251/566 ,  H05B33/04 ,  H05B33/10

Abstract: A masking film (13) is formed so as to have an opening in a display region (R1) (luminescent region) and a sealing region. Subsequently, luminescent layers (8R, 8G, and 8B) having a stripe pattern are formed. Then, the masking film (13) is peeled off, so that the luminescent layers (8R, 8G, and 8B) patterned with high resolution are provided.

Abstract translation: 掩模膜（13）形成为在显示区域（R1）（发光区域）和密封区域中具有开口。 随后，形成具有条纹图案的发光层（8R，8G，8B）。 然后，剥离掩模膜（13），从而提供以高分辨率图案化的发光层（8R，8G，8B）。

公开(公告)号：US08673077B2

公开(公告)日：2014-03-18

申请号：US13984283

申请日：2012-03-02

Applicant: Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

Inventor： Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

IPC: C23C16/00 ,  H01L21/31

CPC classification number: H01L51/5012 ,  C23C14/042 ,  C23C14/243 ,  C23C14/564 ,  H01L51/0011 ,  H01L51/56 ,  H05B33/10

Abstract: Vapor deposition particles (91) discharged from at least one vapor deposition source opening (61) pass through a plurality of limiting openings (82) of a limiting unit (80) and a plurality of mask openings (71) of a vapor deposition mask (70), and adhere to a substrate (10) that relatively moves along a second direction (10a) so as to form a coating film. The limiting unit includes a plurality of plate members stacked on one another. Accordingly, it is possible to efficiently form a vapor deposition coating film in which edge blurring is suppressed on a large-sized substrate at a low cost.

Abstract translation: 从至少一个气相沉积源开口（61）排出的气相沉积颗粒（91）通过限制单元（80）的多个限制开口（82）和气相沉积掩模的多个掩模开口（71） 70），并且粘附到沿着第二方向（10a）相对移动以形成涂膜的基板（10）。 限制单元包括彼此堆叠的多个板构件。 因此，可以以低成本有效地形成在大尺寸基板上抑制边缘模糊的气相沉积涂膜。

公开(公告)号：US20140004641A1

公开(公告)日：2014-01-02

申请号：US14004896

申请日：2012-03-09

Applicant: Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

Inventor： Tohru Sonoda ,  Shinichi Kawato ,  Satoshi Inoue ,  Satoshi Hashimoto

IPC: H01L51/56

CPC classification number: H01L51/56 ,  C23C14/042 ,  C23C14/12 ,  C23C14/243 ,  H05B33/10

Abstract: A vapor deposition device (1) performs a vapor deposition treatment to form a luminescent layer (47) having a predetermined pattern on a film formation substrate (40). The vapor deposition device includes: a nozzle (13) having a plurality of injection holes (16) from which vapor deposition particles (17), which constitute the luminescent layer, are injected toward the film formation substrate when the vapor deposition treatment is carried out; and a plurality of control plates (20) provided between the nozzle and the film formation substrate and restricting an incident angle, with respect to the film formation substrate, of the vapor deposition particles injected from the plurality of injection holes. The nozzle includes: a nozzle main body (14b) in a container shape having an opening (14c) on a surface thereof on a film formation substrate side and (ii) a plurality of blocks (15) covering the opening and separated from each other, each of the plurality of blocks having the plurality of injection holes. The above arrangement allows a vapor-deposited film pattern to be formed with high definition.

Abstract translation: 蒸镀装置（1）进行蒸镀处理，在成膜基板（40）上形成具有规定图案的发光层（47）。 气相沉积装置包括：具有多个喷射孔（16）的喷嘴（13），当进行气相沉积处理时，构成发光层的气相沉积颗粒（17）从该注入孔喷射到成膜基底 ; 以及设置在喷嘴和成膜基板之间的多个控制板（20），并且限制从多个喷射孔喷射的气相沉积颗粒相对于成膜基板的入射角。 喷嘴包括：容器形状的喷嘴主体（14b），其在成膜基板侧的表面上具有开口（14c），和（ii）覆盖开口并分离的多个块体（15） 所述多个块中的每个具有所述多个喷射孔。 上述布置允许以高清晰度形成气相沉积膜图案。