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    Pesticidal bis-oxime compounds
    21.
    发明授权
    Pesticidal bis-oxime compounds 失效
    杀虫双肟化合物

    公开(公告)号：US06525092B1

    公开(公告)日：2003-02-25

    申请号：US09787481

    申请日：2001-04-27

    Applicant: Hugo Ziegler ,  Stephan Trah

    Inventor： Hugo Ziegler ,  Stephan Trah

    IPC: A01N3734

    CPC classification number: C07C251/48 ,  A01N37/50 ,  C07C251/60 ,  C07C255/61

    Abstract: Bis-oxime compounds of the general formula (I) are provided wherein X, Y, R1, R2 R3 and n are as defined in the specification. The bis-oxime compounds possess pesticidal activity, which may provide plants with protection from phytopathogenic microorganisms.

    Abstract translation: 提供通式（I）的双肟化合物，其中X，Y，R 1，R 2，R 3和n如说明书中所定义。 双肟化合物具有杀虫活性，可为植物提供植物病原微生物的保护。

    Microbicides
    22.
    发明授权
    Microbicides 失效
    杀菌剂

    公开(公告)号：US5710314A

    公开(公告)日：1998-01-20

    申请号：US460397

    申请日：1995-06-02

    Applicant: Albert Pfiffner ,  Stephan Trah

    Inventor： Albert Pfiffner ,  Stephan Trah

    IPC: C07C67/31 ,  A01N37/38 ,  A01N37/50 ,  C07C67/343 ,  C07C69/736 ,  C07C251/48 ,  C07C251/52 ,  C07C255/54 ,  C07C255/61 ,  C07C69/76 ,  A01N37/12 ,  C07C233/00

    CPC classification number: A01N37/38 ,  A01N37/50 ,  C07C251/52 ,  C07C255/61 ,  C07C69/736

    Abstract: Compounds of formula I ##STR1## and possible isomers and isomeric mixtures thereof, wherein a) X is CH.sub.2 F or CHF.sub.2 ; Y is CH and Z is OMe, or b) X is CH.sub.2 F or CHF.sub.2 ; Y is a nitrogen atom and Z is OMe or NHCH.sub.3, and wherein also m is 0, 1, 2, 3, 4 or 5 and U represents identical or different substituents selected from halogen, cyano, nitro, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkenyloxyiminomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxyiminomethyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy and unsubstituted or substituted benzyl or represents substituents at two adjacent positions of the phenyl ring of formula I that define a fused hydrocarbon bridge so as to form a larger hydrocarbon ring having up to 14 carbon atoms, are suitable for controlling and preventing microorganisms, insects and Acarina on plants. They can be used in the form of commercially customary formulated compositions.

    Abstract translation: 式I化合物Ⅰ和其可能的异构体和异构体混合物，其中a）X是CH 2 F或CHF 2; Y是CH，Z是OMe，或b）X是CH 2 F或CHF 2; Y是氮原子，Z是OMe或NHCH 3，其中m是0,1,2,3,4或5，U代表相同或不同的选自卤素，氰基，硝基，C 1 -C 12烷基，C 3 -C 8环烷基 C 3 -C 6烯基氧基亚氨基甲基，C 1 -C 4烷氧基，C 1 -C 4烷氧基亚氨基甲基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基，未取代或取代的苯基，未取代或取代的苯氧基和未取代或取代的苄基或在苯环的两个相邻位置 定义稠合烃桥以形成具有至多14个碳原子的较大烃环的式I化合物适用于控制和防止植物上的微生物，昆虫和蜱螨属。 它们可以以商业习惯配制的组合物的形式使用。

    PROCESS FOR THE PREPARATION OF PYRAZOLE CARBOXYLIC ACID AMIDES
    26.
    发明申请
    PROCESS FOR THE PREPARATION OF PYRAZOLE CARBOXYLIC ACID AMIDES 有权
    制备吡唑羧酸酰胺的方法

    公开(公告)号：US20130035496A1

    公开(公告)日：2013-02-07

    申请号：US13642406

    申请日：2011-04-14

    Applicant: Raphael Dumeunier ,  Florian Schleth ,  Thomas Vettiger ,  Michael Rommel ,  Stephan Trah

    Inventor： Raphael Dumeunier ,  Florian Schleth ,  Thomas Vettiger ,  Michael Rommel ,  Stephan Trah

    IPC: C07D231/14 ,  C07C35/37 ,  C07C25/18 ,  C07D303/10

    CPC classification number: C07D231/14 ,  C07C17/23 ,  C07C17/30 ,  C07C25/24 ,  C07C29/132 ,  C07C35/52 ,  C07C45/29 ,  C07C209/10 ,  C07C2603/66 ,  C07D303/17 ,  C07C49/697 ,  C07C23/10 ,  C07C25/22 ,  C07C211/61

    Abstract: The invention relates to a process for the preparation of the compound of formula (I), which process comprises a) reacting a compound of formula (II), wherein X is chloro or bromo, with an organometallic species in an inert atmosphere to a halobenzyne of formula (X), reacting the halobenzyne of formula X so formed with cyclopentadiene to (III), b) reacting III in the presence of an inert solvent with an oxidant to (IV), c) reacing IV in the presence of a Lewis acid and a hydride source to (V), d) reacting V in the presence of an oxidizing agent, a base and an inert solvent to (VI), e) converting VI in the presence of a phosphane and CCL4 or CHCl3 to (VII), and either f1) reacting VII with NH3 in the presence of a catalyst to the compound of formula (VIII); and g) reacting VIII in the presence of a base with a compound of formula (IX), to the compound of formula (I); or f2) reacting the compound of formula (VII), in the presence of a solvent, a base, a copper catalyst and at least one ligand with the compound of formula (IXa), to the compound of formula (I).

    Abstract translation: 本发明涉及一种制备式（I）化合物的方法，该方法包括：a）使惰性气氛下的有机金属物质使式（II）化合物（其中X为氯或溴）与卤代苯 使式（X）所示的卤代苯与环戊二烯反应，（b）使惰性溶剂与惰性溶剂的存在下的III反应与式（Ⅳ）反应：c）在Lewis 酸和氢化物源至（V），d）使V在氧化剂，碱和惰性溶剂的存在下与（VI）反应，e）将VI在磷烷和CCL 4或CHCl 3存在下转化为（VII ），并且f1）使VII与NH 3在催化剂存在下与式（VIII）化合物反应; 和g）在碱存在下使VIII与式（IX）化合物反应，得到式（I）化合物; 或者f2）使式（Ⅶ）化合物在溶剂存在下，碱，铜催化剂和至少一种配体与式（Ⅸa）化合物反应，得到式（I）化合物。

    PYRIDAZINE FUNGICIDES
    27.
    发明申请
    PYRIDAZINE FUNGICIDES 失效
    吡咯烷类杀真菌剂

    公开(公告)号：US20110112108A1

    公开(公告)日：2011-05-12

    申请号：US12863377

    申请日：2009-01-14

    Applicant: Stephan Trah ,  Clemens Lamberth ,  Raphael Dumeunier ,  Sebastian Volker Wenderborn

    Inventor： Stephan Trah ,  Clemens Lamberth ,  Raphael Dumeunier ,  Sebastian Volker Wenderborn

    IPC: A61K31/501 ,  C07D401/04 ,  A01N43/48 ,  A61P35/00 ,  A01P3/00

    CPC classification number: C07D401/04

    Abstract: The present invention relates to novel pyridazine derivatives of formula (I) as active ingredients which have microbiocidal activity, in particular fungicidal activity: wherein R1 is methyl, ethyl or isopropyl; R2 is chloro, fluoro, hydroxy or C1-C2alkoxy; R3 is H, chloro, fluoro, methoxy or C1-C3alkyl; R4 is chloro, fluoro or bromo; and R3 is H, fluoro or methoxy; or an agrochemically usable salt form thereof; with the proviso that when R1 is methyl, R2 is chloro and R3 is H, then R4 or R5 is different from fluoro.

    Abstract translation: 本发明涉及式（I）的新的哒嗪衍生物作为具有杀微生物活性的活性成分，特别是杀真菌活性：其中R1是甲基，乙基或异丙基; R2是氯，氟，羟基或C1-C2烷氧基; R3是H，氯，氟，甲氧基或C1-C3烷基; R4是氯，氟或溴; 且R 3为H，氟或甲氧基; 或其农业化学可用的盐形式; 条件是当R 1为甲基时，R 2为氯且R 3为H，则R 4或R 5不同于氟。

    Pesticidal heterocyclic dihaloallyl compounds
    28.
    发明授权
    Pesticidal heterocyclic dihaloallyl compounds 失效
    杀虫杂环二卤代烯化合物

    公开(公告)号：US07723362B2

    公开(公告)日：2010-05-25

    申请号：US10597005

    申请日：2005-01-07

    Applicant: Roger Graham Hall ,  Stephan Trah ,  Werner Zambach ,  Juraj Tuleja

    Inventor： Roger Graham Hall ,  Stephan Trah ,  Werner Zambach ,  Juraj Tuleja

    IPC: C07D401/12 ,  C07D257/04 ,  A61K31/4439 ,  A61K31/41 ,  C07D285/13 ,  C07D271/113 ,  C07D249/12 ,  C07D237/12 ,  C07D241/18 ,  C07D239/36 ,  C07D273/04 ,  C07D233/72

    CPC classification number: C07D271/113 ,  C07D233/72 ,  C07D237/14 ,  C07D239/36 ,  C07D241/18 ,  C07D249/12 ,  C07D273/04 ,  C07D285/13

    Abstract: The invention relates to compounds of formula wherein Het, A1, A2, A3, A4, D, W, T, Q, Y, X1, X2, R1, R2, R3, R4, k and m are as defined hereinabove, and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, to a process for the preparation of and to the use of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, to pesticidal compositions in which the active ingredient has been selected from those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in agrochemically usable salt form, to a process for the preparation of and to the use of those compositions, to plant propagation material treated with those compositions, to a method of controlling pests, to intermediates and, where applicable, to possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form, for the preparation of those compounds, E/Z isomers, mixtures of E/Z isomers and/or tautomers, and to a process for the preparation of and to the use of those intermediates and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof.

    Abstract translation: 本发明涉及下式的化合物，其中Het，A1，A2，A3，A4，D，W，T，Q，Y，X1，X2，R1，R2，R3，R4，k和m如上所定义， 在适用的情况下，可能的E / Z异构体，E / Z异构体和/或其互变异构体的混合物，在每种情况下为游离形式或盐形式，用于制备和使用这些化合物的方法E / Z异构体，E / Z异构体和/或互变异构体的混合物，其中活性成分选自那些化合物，E / Z异构体，E / Z异构体和/或互变异构体的混合物，在每种情况下为游离 形式或农业化学上可用的盐形式，涉及制备和使用这些组合物，用这些组合物处理的繁殖材料的方法，控制害虫的方法，中间体和适用时可能的E / Z异构体，E / Z异构体和/或其互变异构体的混合物，在每种情况下为游离形式或盐形式，用于制备这些化合物 ds，E / Z异构体，E / Z异构体和/或互变异构体的混合物，以及制备和使用那些中间体的方法，以及在适用时可能的E / Z异构体，E / Z异构体的混合物 和/或其互变异构体。

    NOVEL PYRIDAZINE DERIVATIVES
    29.
    发明申请
    NOVEL PYRIDAZINE DERIVATIVES 审中-公开
    新的吡咯烷酮衍生物

    公开(公告)号：US20100029668A1

    公开(公告)日：2010-02-04

    申请号：US12374052

    申请日：2007-07-16

    Applicant: Stephan Trah ,  Clemens Lamberth ,  Sebastian Volker Wendeborn

    Inventor： Stephan Trah ,  Clemens Lamberth ,  Sebastian Volker Wendeborn

    IPC: A01N43/58 ,  C07D405/04 ,  A01P3/00

    CPC classification number: C07D401/14 ,  A01N43/58 ,  C07D403/14 ,  C07D405/14 ,  C07D407/14 ,  C07D409/14 ,  C07D417/14

    Abstract: The present invention relates to novel pyridazine derivatives of formula (I) as active ingredients which have microbiocidal activity, in particular fungicidal activity: wherein R1 is hydrogen, C1-C6alkyl, C1-C6haloalkyl or C3-C6cycloalkyl; R2 is an optionally substituted heteroaryl; R3 is an optionally substituted heteroaryl; and R4 is hydrogen, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, hydroxy or cyano; or an agrochemically usable salt form thereof.

    Abstract translation: 本发明涉及具有杀微生物活性，特别是杀真菌活性的活性成分的式（I）的新哒嗪衍生物，其中R1是氢，C1-C6烷基，C1-C6卤代烷基或C3-C6环烷基; R2是任选取代的杂芳基; R3是任选取代的杂芳基; R4是氢，卤素，C1-C6烷基，C1-C6卤代烷基，C1-C6烷氧基，C1-C6卤代烷氧基，羟基或氰基; 或其农业化学上可用的盐形式。

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