公开(公告)号：US09234070B2

公开(公告)日：2016-01-12

申请号：US13649346

申请日：2012-10-11

Applicant: Arkema Inc.

Inventor： Benjamin Bin Chen ,  Maher Y. Elsheikh ,  Philippe Bonnet ,  Brett L. Van Horn ,  Joseph S. Costa

IPC: C08J9/00 ,  C08J9/04 ,  C08J9/14 ,  C08G18/76 ,  C08G18/66 ,  C08G18/40 ,  C08G18/48 ,  C08G101/00

CPC classification number: C08G18/7664 ,  C08G18/4018 ,  C08G18/482 ,  C08G18/6674 ,  C08G2101/00 ,  C08J9/144 ,  C08J9/146 ,  C08J9/149 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2375/04

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

Abstract translation: 公开了一种用于热固性泡沫的发泡剂。 发泡剂主要是氢氯氟烯烃（HCFO）HFCO-1233zd单独或与氢氟烯烃（HFO），氢氟烃（HFC），氢氯氟烯烃（HCFO），烃类的组合的反式异构体。 发泡剂在制造热固性泡沫时作为发泡剂是有效的。

公开(公告)号：US09206297B2

公开(公告)日：2015-12-08

申请号：US14519456

申请日：2014-10-21

Applicant: Arkema Inc.

Inventor： Brett L. Van Horn ,  Maher Y. Elsheikh ,  Benjamin Bin Chen ,  Philippe Bonnet

IPC: C08J9/14 ,  C08J9/00 ,  C08J9/12

CPC classification number: C08J9/144 ,  C08J9/122 ,  C08J9/127 ,  C08J9/141 ,  C08J9/146 ,  C08J9/149 ,  C08J2201/03 ,  C08J2203/06 ,  C08J2203/14 ,  C08J2203/162 ,  C08J2203/182 ,  C08J2203/202 ,  C08J2205/052 ,  C08J2323/06 ,  C08J2323/12 ,  C08J2325/06

Abstract: The present invention relates to foam products made with blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited too, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32). The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.

Abstract translation: 本发明涉及由用于制备可发泡热塑性组合物的至少一种氢氯氟烯烃（HCFO）的发泡剂组合物制成的泡沫产品。 本发明的HCFO包括但不限于1-氯-3,3,3-三氟丙烯（HCFO-1233zd），特别是反式异构体2-氯-3,3,3-三氟丙烯（HCFO -1233xf），二氯氟化丙烯及其混合物。 本发明的发泡剂组合物与包括二氧化碳，大气，氢氟烃（HFC），氢氟烯烃（HFO），烷烃，氢氟醚（HFE）及其混合物的助熔剂一起使用。 在本发明中用作起泡剂的优选的HFCs包括但不限于1,1,1,2-四氟乙烷（HFC-134a），1,1-二氟乙烷（HFC-152a），1,1,1-三氟乙烷 三氟乙烷（HFC-143a），五氟乙烷（HFC-125），二氟甲烷（HFC-32）。 发泡剂组合物可用于生产具有改进的k因子的低密度绝缘泡沫。

公开(公告)号：US09181154B2

公开(公告)日：2015-11-10

申请号：US13939233

申请日：2013-07-11

Applicant: Arkema Inc.

Inventor： Philippe Bonnet ,  Maher Y. Elsheikh

IPC: C07C17/358 ,  C07C17/383 ,  C07C17/38 ,  C07C17/386 ,  C07C17/389 ,  C07C21/18 ,  C08J9/14 ,  C09K3/30 ,  C09K5/04

CPC classification number: C07C17/358 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389 ,  C07C21/18 ,  C08J9/146 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C09K2205/22 ,  Y02P20/127

Abstract: Disclosed are the combinations containing Z and E stereoisomers of hydrofluoroolefins where the more toxic isomer is less than about 30% weight of the combination (vs the sum of Z+E), to minimize the toxicity impact in the applications they will be used for such as cooling and heat fluids, foams blowing agents or solvents. Also disclosed are means to obtain combinations containing Z and E stereoisomers of hydrofluoroolefins.

Abstract translation: 公开了含有氢氟烯烃的Z和E立体异构体的组合，其中较毒的异构体小于组合的约30重量％（相对于Z + E的总和），以最小化其将用于这些的应用中的毒性影响 作为冷却和热流体，泡沫发泡剂或溶剂。 还公开了获得含有氢氟烯烃的Z和E立体异构体的组合的方法。

公开(公告)号：US20150197614A1

公开(公告)日：2015-07-16

申请号：US14430289

申请日：2013-09-19

Applicant: ARKEMA INC.

Inventor： Benjamin Bin Chen ,  Joseph S. Costa ,  Laurent Abbas ,  Maher Y. Elsheikh ,  Sri R. Seshadri ,  Gary S. Smith

IPC: C08J9/14 ,  C08G18/18 ,  C08J9/00 ,  C08G18/08 ,  C08G18/72 ,  C08G18/40

CPC classification number: C08J9/144 ,  C08G18/14 ,  C08G18/1808 ,  C08G18/1816 ,  C08G18/1833 ,  C08G18/4018 ,  C08G18/4208 ,  C08G18/4829 ,  C08G18/6674 ,  C08G18/72 ,  C08G2101/0025 ,  C08J9/0023 ,  C08J9/0061 ,  C08J2203/162 ,  C08J2375/08 ,  C08J2383/12

Abstract: A polyol pre-mix composition includes a blowing agent having a halogenated hydroolefin, a polyol, a catalyst composition, and an antioxidant. The antioxidant may be, for example, a benzene diol or a benzene triol or other polyhydroxy-substituted aromatic compound, which is optionally substituted with one or more substituents such as alkyl groups. A two-part system for producing a thermosetting foam blend includes (a) a polyisocyanate and, optionally, one or more isocyanate compatible raw materials; and (b) the polyol pre-mix composition. A method for producing a thermosetting foam blend includes combining: (a) a polyisocyanate; and (b) the polyol pre-mix composition.

Abstract translation: 多元醇预混合物组合物包括具有卤化氢烯烃，多元醇，催化剂组合物和抗氧化剂的发泡剂。 抗氧化剂可以是例如苯二醇或苯三醇或其它多羟基取代的芳族化合物，其任选被一个或多个取代基例如烷基取代。 用于生产热固性泡沫共混物的两部分系统包括（a）多异氰酸酯和任选的一种或多种异氰酸酯相容的原料; 和（b）多元醇预混合组合物。 一种制备热固性泡沫共混物的方法包括：（a）多异氰酸酯; 和（b）多元醇预混合组合物。

公开(公告)号：US20130246288A1

公开(公告)日：2013-09-19

申请号：US13873266

申请日：2013-04-30

Applicant: ARKEMA INC.

Inventor： Brett L. Van Horn ,  Phillippe Bonnet ,  Benjamin Bin Chen ,  Maher Y. Elsheikh ,  Richard M. Crooker

IPC: C09K5/04

CPC classification number: C09K5/044 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/112 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/32 ,  C09K2205/40 ,  C09K2205/41 ,  C10M171/008 ,  C10M2203/065 ,  C10M2203/1006 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2205/223 ,  C10M2207/2835 ,  C10M2209/043 ,  C10M2209/1033 ,  C10N2040/30 ,  C10N2220/301 ,  C10N2220/302 ,  C10N2220/303 ,  C10N2220/305 ,  C10N2240/30 ,  F25B1/005 ,  F25B1/053 ,  F25B1/10 ,  F25B9/006 ,  F25B31/002 ,  F25B45/00 ,  F25B2339/047 ,  F25B2400/18

Abstract: The invention relates to heat transfer agents and heat transfer compositions containing hydrocarbon lubricating oils and halogenated alkene heat transfer fluid that promote oil flow and provide for improved oil return. The heat transfer compositions are useful in various heat transfer systems such as refrigeration, cooling, air conditioning, chiller operations.

Abstract translation: 本发明涉及含有烃润滑油和卤代烯烃传热流体的传热剂和传热组合物，其促进油流并提供改进的回油。 传热组合物可用于各种传热系统，例如制冷，冷却，空调，冷却器操作。

公开(公告)号：US10301520B2

公开(公告)日：2019-05-28

申请号：US15155251

申请日：2016-05-16

Applicant: Arkema Inc.

Inventor： Benjamin Bin Chen ,  Philippe Bonnet ,  Maher Y. Elsheikh ,  Brett L. Van Horn ,  Laurent Abbas

IPC: C09K5/04 ,  C11D7/50 ,  C09K3/00 ,  C11D7/30 ,  F25B47/00 ,  C23G5/028

Abstract: The present invention relates to solvent/cleaner and heat transfer fluid compositions comprising at least one hydrochlorofluoroolefin (HCFO), 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer. The HCFO of the present invention can be used in combination with co-agents including, hydrofluorocarbons (HFCs), hydrofluoroolefins (HFOs), hydrocarbons, ethers including hydrofluoroethers (HFEs), esters, ketones, alcohols, 1,2-transdichloroethylene and mixtures thereof.

公开(公告)号：US10072192B2

公开(公告)日：2018-09-11

申请号：US14964940

申请日：2015-12-10

Applicant: Arkema Inc.

Inventor： Brett L. Van Horn ,  Maher Y. Elsheikh ,  Benjamin Bin Chen ,  Philippe Bonnet

IPC: C09K5/04 ,  C09K5/00 ,  B01F17/00 ,  C10M171/00

CPC classification number: C09K5/04 ,  B01F17/0085 ,  C09K5/00 ,  C09K5/044 ,  C10M171/008 ,  C10M2203/065 ,  C10M2205/0285 ,  C10M2207/2835 ,  C10M2209/043 ,  C10M2209/1033 ,  C10N2220/302

Abstract: The present invention relates to formulated refrigerant systems of 1-chloro-3,3,3-trifluoropropene (R-1233zd) that are sufficiently thermally and chemically stable such that they can be effectively used sans additional stabilizers. The formulations of the present invention are particularly useful compositions for refrigeration, heat transfer and foam blowing.

公开(公告)号：US09890097B2

公开(公告)日：2018-02-13

申请号：US14870160

申请日：2015-09-30

Applicant: Arkema Inc.

Inventor： Philippe Bonnet ,  Maher Y. Elsheikh

IPC: C07C17/383 ,  C07C21/18 ,  C07C17/358 ,  C07C17/38 ,  C07C17/386 ,  C07C17/389 ,  C08J9/14 ,  C09K3/30 ,  C09K5/04

CPC classification number: C07C17/358 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389 ,  C07C21/18 ,  C08J9/146 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C09K2205/22 ,  Y02P20/127

Abstract: Disclosed are the combinations containing Z and E stereoisomers of hydrofluoroolefins where the more toxic isomer is less than about 30% weight of the combination (vs the sum of Z+E), to minimize the toxicity impact in the applications they will be used for such as cooling and heat fluids, foams blowing agents or solvents. Also disclosed are means to obtain combinations containing Z and E stereoisomers of hydrofluoroolefins.

公开(公告)号：US09809515B2

公开(公告)日：2017-11-07

申请号：US15279680

申请日：2016-09-29

Applicant: ARKEMA INC.

Inventor： Maher Y. Elsheikh ,  Philippe Bonnet ,  Olga C. N. Keeley ,  Benjamin Bin Chen

IPC: C07C17/25 ,  C07C21/18 ,  B01J23/26 ,  B01J27/132 ,  B01J37/08 ,  B01J21/18 ,  B01J37/00 ,  B01J37/14

CPC classification number: C07C17/25 ,  B01J21/18 ,  B01J23/26 ,  B01J27/132 ,  B01J37/0018 ,  B01J37/0072 ,  B01J37/08 ,  B01J37/14 ,  C07C21/18

Abstract: A method for producing a tetrafluoroolefin, such as 2,3,3,3-tetrafluoropropene (HFO-1234yf), comprises dehydrofluorinating a pentafluoroalkane in a gas phase in the presence of a catalyst comprising chromium oxyfluoride. In a preferred embodiment, 2,3,3,3-tetrafluoropropene (HFO-1234yf) is produced by forming a catalyst comprising chromium oxyfluoride by calcining CrF3.xH2O, where x is 1-10, in the presence of a flowing gas comprising nitrogen to form a calcined chromium oxyfluoride, and dehydrofluorinating 1,1,1,2,2-pentafluoropropane (HFC-245cb) in a gas phase in the presence of the catalyst to form the 2,3,3,3-tetrafluoropropene (HFO-1234yf).

公开(公告)号：US20160016868A1

公开(公告)日：2016-01-21

申请号：US14870160

申请日：2015-09-30

Applicant: Arkema Inc.

Inventor： Philippe Bonnet ,  Maher Y. Elsheikh

IPC: C07C17/358 ,  C07C17/383 ,  C07C17/38

CPC classification number: C07C17/358 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389 ,  C07C21/18 ,  C08J9/146 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C09K2205/22 ,  Y02P20/127

Abstract: Disclosed are the combinations containing Z and E stereoisomers of hydrofluoroolefins where the more toxic isomer is less than about 30 % weight of the combination (vs the sum of Z+E), to minimize the toxicity impact in the applications they will be used for such as cooling and heat fluids, foams blowing agents or solvents. Also disclosed are means to obtain combinations containing Z and E stereoisomers of hydrofluoroolefins.

Abstract translation: 公开了含有氢氟烯烃的Z和E立体异构体的组合，其中较毒的异构体小于组合的约30重量％（相对于Z + E的总和），以最小化其将用于这些的应用中的毒性影响 作为冷却和热流体，泡沫发泡剂或溶剂。 还公开了获得含有氢氟烯烃的Z和E立体异构体的组合的方法。