摘要:
Process for the polymerization of cyclic aliphatic carbonates in the presence of aprotic organic solvents with exclusion of atmospheric oxygen and atmospheric moisture, wherein organometallic compounds of elements of main group 1 of the periodic table are used as initiators, the monomer/solvent ratio is in the range from 1 part by weight to 50 parts by weight of monomer per 100 parts by weight of solvent and the polymerization temperature is between -100.degree. C. and +20.degree. C.
摘要:
Molding compounds of(A) 5 to 95% by weight of a graft product of a mixture of 50 to 100 parts by weight styrene, .alpha.-methyl styrene, vinyl toluene, methyl methacrylate or mixtures thereof and 0 to 50 parts by weight acrylonitrile on a particulate silicone rubber with a mean particle diameter (d.sub.50) of from 0.10 to 0.50 .mu.m having a total rubber content of from 30 to 90% by weight and(B) 95 to 5% by weight of a graft product of a mixture of 50 to 100 parts by weight styrene, .alpha.-methyl styrene, vinyl toluene, methyl methacrylate or mixtures thereof and 0 to 50 parts by weight acrylonitrile on a particulate acrylate rubber with a mean particle diameter (d.sub.50) of from 0.05 to 1.00 .mu.m having a total rubber content of 30 to 80% by weight.
摘要:
Graft polymers ofa) 5 to 95% by weight of a copolymer of 20 to 60% by weight of a 1,3,5-triazine derivative corresponding to formula (I) ##STR1## in which R=H, C.sub.1-2 alkyl, and 40 to 80% by weight of other vinyl monomers as the graft base andb) 5 to 95% by weight of a thermoplastic polymer as the graft shell,their use as thermoplastic molding compounds and as flame-proofing agents for other synthetic materials.
摘要:
Thermoplastic block copolymers of the idealized formulae (I)A--B--A; B--A--B or (A--B).sub.x (I)in whichx=1 to 40,and whereinA is the radical of a homopolymer of styrene, vinylnaphthalene, butadiene and isoprene, andB the radical of a homopolymer of a cyclic polycarbonate or lactone,the average molecular weight of blocks A and B being greater than 800, and a process for the preparation of these blocks copolymers in several reaction stages.
摘要:
Block copolymers composed of recurrent structural units belonging to the series comprising polysiloxanes and recurring structural units belonging to the series comprising homopolymers, copolymers or terpolymers of vinyl-aromatic compounds and acrylic monomers of mixtures thereof.
摘要:
Thermoplastic molding compositions of a vinyl chloride polymer and one or more emulsion polymers made with special emulsifiers have improved properties for technical application, such as reduced fogging. They are used for the production of molded articles, sheet products and films.
摘要:
Dispersions of stabilizers for plastics in water which contain special reaction products of diols and carboxylic acid anhydrides as auxiliary emulsifiers, and which are characterized by simple preparation, stability and good effectiveness in chemical materials.
摘要:
Polymer mixtures having high tensile strength and good tear propagation resistance, consisting of(A) from 10 to 95 parts by weight of a graft polymer,(B) from 0 to 75 parts by weight of a thermoplastic resin component and(C) from 5 to 60 parts by weight of a copolymer having a sequence type of structure corresponding to the idealized formula (I)(A--X--B).sub.n (I) whereinA=polymer of a cyclic carbonate,B=polymer of another cyclic ester andX=middle member containing partial structures of both A and B.
摘要:
Multi-block copolymers of recurring structural units of polysiloxanes and recurring structural units of aliphatic polyesters, polyethers or polyetheresters with rubber properties, the individual polymeric blocks constituting rubber-type products with glass transition temperatures below practical usefulness and a process for their production.
摘要:
A method of using Raman Spectra for determining the progress of a graft polymerization reaction is disclosed. The method entails (a) measuring at the beginning of the reaction and at a plurality of time intervals in the course of the reaction, continuously and on-site, the Raman spectrum in the wave number range of 100 to 4000 cm−1 of one or more of the monomers and/or polymers entailed in the reaction and of at least one internal standard and (b) recording the spectra and (c) adding reaction partners necessary to the reaction continuously and/or discontinuously and (d) calculating the change in concentration of the monomers and polymers by comparing the spectra of the monomers or polymers with the internal standard.