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公开(公告)号：US20220235149A1
公开(公告)日：2022-07-28
申请号：US17302463
申请日：2021-05-04
Applicant: Eastman Chemical Company
Inventor： Matthew Allen Boone , Christopher Harlan Burk , Peter Borden Mackenzie , Jennifer A. Fish , Eduardo Gallas Cervo , Elaine Beatrice Mackenzie , Robert Joseph Maleski , Wesley Wayne McConnell , David William Norman , Tabatha Stearns , Bin Wang
IPC: C08B3/16 , B32B27/24 , B32B27/08 , B32B27/36 , B32B7/12 , B32B27/28 , C08L1/14 , B32B23/08 , B32B27/32 , B32B27/18 , G02B5/30 , B32B27/22 , B32B27/06 , G02F1/13363 , H01L51/52
Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.
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22.发明授权公开(公告)号：US10065180B2
公开(公告)日：2018-09-04
申请号：US15829245
申请日：2017-12-01
Applicant: Eastman Chemical Company
Inventor： David William Norman , Greg Alan King
IPC: C07B35/00 , B01J27/199 , B01J37/08 , B01J21/06 , B01J23/00 , C07C51/353 , C07C57/04 , B01J27/198 , B01J37/03 , B01J35/00
Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus modified with alkali metal. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.
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公开(公告)号：US09834501B2
公开(公告)日：2017-12-05
申请号：US15008833
申请日：2016-01-28
Applicant: EASTMAN CHEMICAL COMPANY
Abstract: A process is described that uses a silver catalyst to convert methanol into formaldehyde in the presence of less than a stoichiometric amount of oxygen. The resulting formaldehyde is reacted without isolation with propionaldehyde over a commercially available anatase titania catalyst that is shown to be catalytically active towards the formation of methacrolein from formaldehyde and propionaldehyde with conversions and selectivities close to 90%. This titania catalyst is readily available, non-toxic, and can be used with formaldehyde and a variety of other aldehyde compounds to make α,β-unsaturated aldehyde compounds. This process benefits from low raw material costs and is economically advantaged due to the elimination of catalyst separation. This process shows promising stability and selectivity during lifetime studies, particularly when performed in the presence of a hydrogen carrier gas.
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24.发明申请METHYL-IODIDE-FREE CARBONYLATION OF AN ALCOHOL TO ITS HOMOLOGOUS ALDEHYDE AND/OR ALCOHOL 有权酒精对其异构醛和/或醇的甲基无碘羰基化公开(公告)号：US20160251292A1
公开(公告)日：2016-09-01
申请号：US15153827
申请日：2016-05-13
Applicant: Eastman Chemical Company
Inventor： Jonathan Michael Penney , David William Norman , Andrew James Vetter
CPC classification number: C07C45/49 , B01J27/128 , B01J31/0239 , B01J31/0268 , B01J31/20 , B01J2231/321 , B01J2531/821 , C07C29/32 , C07C51/12 , C07C31/08 , C07C47/06 , C07C53/08
Abstract: Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a single component catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 without additional promoters. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.
Abstract translation: 公开了一种用于还原性羰基化低分子量醇以产生同源醛和/或醇的方法。 该方法包括进行反应以在由钴，鎓阳离子和碘化物组成的单组分催化剂络合物的存在下以1:2:4的比例进行反应，而无需另外的助催化剂。 钌助催化剂用于同源醇的生产。 还原羰基化反应不需要另外的碘化物促进剂并产生基本上不含甲基碘的粗还原羰基化产物。
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25.发明申请公开(公告)号：US20160185700A1
公开(公告)日：2016-06-30
申请号：US14585884
申请日：2014-12-30
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： Jonathan Michael Penney , David William Norman , Andrew James Vetter
IPC: C07C45/49 , B01J31/24 , B01J31/22 , C07C29/157 , B01J27/128
CPC classification number: C07C45/49 , B01J27/128 , B01J31/0239 , B01J31/0268 , B01J31/20 , B01J2231/321 , B01J2531/821 , C07C29/32 , C07C51/12 , C07C31/08 , C07C47/06 , C07C53/08
Abstract: Disclosed is a process for the reductive carbonylation of a low molecular weight alcohol to produce the homologous aldehyde and/or alcohol. The process includes conducting the reaction to produce the aldehyde in the presence of a single component catalyst complex composed of cobalt, an onium cation and iodide in a ratio of 1:2:4 without additional promoters. A ruthenium co-catalyst is used in the production of the homologous alcohol. The reductive carbonylation reaction does not require an additional iodide promoter and produces a crude reductive carbonylation product substantially free of methyl iodide.
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Patent Agency Ranking
26.发明申请PROCESS FOR PREPARING V-Ti-P CATALYSTS FOR SYNTHESIS OF 2,3-UNSATURATED CARBOXYLIC ACIDS 审中-公开制备用于合成2,3-不饱和羧酸的V-Ti-P催化剂的方法公开(公告)号：US20150166454A1
公开(公告)日：2015-06-18
申请号：US14626111
申请日：2015-02-19
Applicant: Eastman Chemical Company
IPC: C07C51/377 , B01J27/198
CPC classification number: C07C51/377 , B01J21/063 , B01J27/198 , B01J35/002 , B01J37/031 , B01J2523/00 , C07C51/09 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed. Additionally, the catalyst composition is catalytically active towards the formation of acrylic acid from methylene diacetate and methacrylic acid from methylene dipropionate; both reactions are carried out with high space time yields.
Abstract translation: 本发明涉及包含钒，钛和磷的混合氧化物的催化剂组合物。 钛组分衍生自水溶性，氧化还原活性有机钛化合物。 催化剂组合物在促进甲醛与乙酸的气相缩合以产生丙烯酸方面是非常有效的，特别是使用工业上相关的水性液体进料。 此外，催化剂组合物对于从亚甲基二乙酸酯和甲基丙烯酸由二丙酸亚丙酯形成丙烯酸具有催化活性; 两个反应均以高空时产率进行。
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27.发明申请公开(公告)号：US20130237724A1
公开(公告)日：2013-09-12
申请号：US13826180
申请日：2013-03-14
Applicant: EASTMAN CHEMICAL COMPANY
Inventor： Venkata Bharat Ram Boppana , David William Norman , Melissa Dawn Page
IPC: B01J27/198 , C07C51/377
CPC classification number: C07C51/377 , B01J21/063 , B01J27/198 , B01J35/002 , B01J37/031 , B01J2523/00 , C07C51/09 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C57/04
Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed. Additionally, the catalyst composition is catalytically active towards the formation of acrylic acid from methylene diacetate and methacrylic acid from methylene dipropionate; both reactions are carried out with high space time yields.
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28.发明申请公开(公告)号：US20180085741A1
公开(公告)日：2018-03-29
申请号：US15829218
申请日：2017-12-01
Applicant: Eastman Chemical Company
Inventor： David William Norman , Greg Alan King
IPC: B01J27/199 , B01J37/08 , B01J21/06 , B01J23/00
CPC classification number: B01J27/199 , B01J21/063 , B01J23/002 , B01J27/198 , B01J35/002 , B01J37/03 , B01J37/086 , B01J2523/00 , B01J2523/13 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C51/353 , C07C57/04
Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus modified with alkali metal. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.
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29.发明申请公开(公告)号：US20180078927A1
公开(公告)日：2018-03-22
申请号：US15829245
申请日：2017-12-01
Applicant: Eastman Chemical Company
Inventor： David William Norman , Greg Alan King
IPC: B01J27/199 , B01J23/00 , B01J27/198 , C07C57/04 , B01J37/03 , B01J37/08 , C07C51/353 , B01J21/06 , B01J35/00
CPC classification number: B01J27/199 , B01J21/063 , B01J23/002 , B01J27/198 , B01J35/002 , B01J37/03 , B01J37/086 , B01J2523/00 , B01J2523/13 , B01J2523/47 , B01J2523/51 , B01J2523/55 , C07C51/353 , C07C57/04
Abstract: The invention relates to a catalyst composition comprising a mixed oxide of vanadium, titanium, and phosphorus modified with alkali metal. The titanium component is derived from a water-soluble, redox-active organo-titanium compound. The catalyst composition is highly effective at facilitating the vapor-phase condensation of formaldehyde with acetic acid to generate acrylic acid, particularly using an industrially relevant aqueous liquid feed.
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公开(公告)号：US20170307796A1
公开(公告)日：2017-10-26
申请号：US15482920
申请日：2017-04-10
Applicant: Eastman Chemical Company
Inventor： Matthew Allen Boone , Christopher Harlan Burk , Peter Borden Mackenzie , Jennifer A. Fish , Eduardo Gallas Cervo , Elaine Beatrice Mackenzie , Robert Joseph Maleski , Wesley McConnell , David William Norman , Tabatha Stearns , Bin Wang
IPC: G02B5/30 , H01L51/52 , G02F1/13363 , B32B27/06 , C08B3/16
CPC classification number: C08B3/16 , B32B7/12 , B32B23/08 , B32B27/06 , B32B27/08 , B32B27/18 , B32B27/22 , B32B27/24 , B32B27/281 , B32B27/325 , B32B27/36 , B32B27/365 , B32B2307/40 , B32B2307/516 , B32B2307/518 , B32B2307/546 , B32B2307/732 , B32B2309/105 , B32B2457/202 , B32B2457/206 , C08L1/08 , C08L1/10 , C08L1/14 , G02B5/3033 , G02B5/305 , G02B5/3083 , G02F1/13363 , G02F2001/133638 , G02F2413/13 , H01L51/5259 , H01L51/5281 , Y10T428/1036 , Y10T428/105
Abstract: Regioselectively substituted cellulose esters having a plurality of pivaloyl substituents and a plurality of aryl-acyl substituents are disclosed along with methods for making the same. Such cellulose esters may be suitable for use in films, such as +A optical films, and/or +C optical films. Optical films prepared employing such cellulose esters have a variety of commercial applications, such as, for example, as compensation films in liquid crystal displays and/or waveplates in creating circular polarized light used in 3-D technology.
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