公开(公告)号：US4504374A

公开(公告)日：1985-03-12

申请号：US473547

申请日：1983-03-09

申请人： Ronald J. Lewarchik ,  Edward J. Murphy ,  Elaine C. Beeks

发明人： Ronald J. Lewarchik ,  Edward J. Murphy ,  Elaine C. Beeks

IPC分类号： B05D1/00 ,  B05D3/06 ,  B05D5/00 ,  B05D7/00 ,  B05D7/14 ,  B05D7/16 ,  C08F2/48 ,  C09D163/00 ,  C25D13/08

CPC分类号： B05D7/16 ,  B05D7/54 ,  B05D1/007 ,  B05D3/067

摘要： A method of providing a stone chip-resistant finish to the undersurface of an automobile is disclosed in which the undersurface is coated with a cationically initiated liquid mixture of cationically curable polyepoxide, polyhydric alcohol, and a photoinitiator for an ultraviolet-activated cationic cure. The liquid mixture is applied at a resin solids content of at least about 50% and in a thickness to provide a cured coating of at least 2 mils thick, and the wet coating is cured by exposing it to ultraviolet light. The automobile undersurface is desirably primed with a cross-linked amine-functional polymer primer, and the coating includes from 1% to 8% of a finely divided silica which prevents running but does not interfere with the ultraviolet cure.

摘要翻译： 公开了一种向汽车底面提供防石材防滑涂层的方法，其中下表面涂有阳离子引发的阳离子可固化聚环氧化物，多元醇和用于紫外线活化阳离子固化的光引发剂的液体混合物。 以至少约50％和厚度的树脂固体含量施加液体混合物以提供至少2密耳厚的固化涂层，并且湿涂层通过将其暴露于紫外光而固化。 汽车下表面优选用交联的胺官能聚合物底漆涂布，并且涂层包含1％至8％的细碎二氧化硅，其防止流动但不干扰紫外线固化。

公开(公告)号：US4464436A

公开(公告)日：1984-08-07

申请号：US334919

申请日：1981-12-28

申请人： Edward J. Murphy

发明人： Edward J. Murphy

IPC分类号： C08F2/50 ,  C08F30/04 ,  C09D4/00 ,  B32B15/08

CPC分类号： C09D4/00 ,  C08F30/04 ,  Y10T428/31696 ,  Y10T428/31699

摘要： An unsaturated ionic dimer of chromic acid with monoethylenically unsaturated monomer containing a single amine group is disclosed which can be incorporated into liquid coating compositions containing ultraviolet-curable polyethylenically unsaturated material. On curing, the ionic dimer increases the corrosion resistance of the photocured coatings, and is especially useful as a basecoat over thermoplastic molded objects which are coated with a metallic film.

摘要翻译： 公开了含有单一胺基的单烯属不饱和单体的铬酸不饱和离子二聚体，其可以并入含有紫外线固化型多烯属不饱和材料的液体涂料组合物中。 在固化时，离子二聚体增加光固化涂层的耐腐蚀性，并且特别可用作涂覆有金属膜的热塑性模制物体上的底涂层。

公开(公告)号：US4416750A

公开(公告)日：1983-11-22

申请号：US311057

申请日：1981-10-13

申请人： Edward J. Murphy ,  Ronald J. Lewarchik ,  Jeffrey W. Thompson

发明人： Edward J. Murphy ,  Ronald J. Lewarchik ,  Jeffrey W. Thompson

IPC分类号： C08F2/00 ,  C08F2/48 ,  C08F290/00 ,  C08F299/00 ,  C08F299/02 ,  C08F299/06 ,  C08J3/28 ,  C08J7/04 ,  C08J7/18 ,  C09D175/14 ,  C08G18/00 ,  C08G63/00

CPC分类号： C08F299/065 ,  C08J7/18 ,  Y10S525/92

摘要： An ultraviolet light-curable liquid coating composition for molded plastic objects is disclosed. The composition is a liquid mixture of a polyurethane oligomer polyacrylate and an hydroxy-functional polyacrylate ester. The polyacrylate ester is present in an amount of 5% to 95% of total polyacrylate. The composition is preferably in solution in alcoholic solvent having a solids content of from 40% to 90%. A photoinitiator is included to render the composition curable upon exposure to ultraviolet light.

摘要翻译： 公开了一种用于模制塑料物体的紫外线可光固化液体涂料组合物。 该组合物是聚氨酯低聚物聚丙烯酸酯和羟基官能聚丙烯酸酯的液体混合物。 聚丙烯酸酯以总聚丙烯酸酯的5％至95％的量存在。 该组合物优选在固体含量为40％至90％的醇溶剂中的溶液中。 包括光引发剂以使组合物在暴露于紫外线下时可固化。

公开(公告)号：US08426021B2

公开(公告)日：2013-04-23

申请号：US13233670

申请日：2011-09-15

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B9/00 ,  D02G3/00 ,  C08F283/10 ,  C08F20/22

CPC分类号： G02B1/12 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D163/00 ,  C09D175/14 ,  C09D175/16 ,  Y10T428/2938 ,  Y10T428/2964 ,  C08G18/48

摘要： The invention relates to a Radiation Curable Secondary Coating composition for use on an Optical Fiber. The Radiation Curable Secondary Coating composition is a urethane-free Alpha Oligomer prepared by reaction of the following: (a) an acrylate compound selected from an alcohol-containing acrylate or alcohol-containing methacrylate compound, (b) an anhydride compound, (c) an epoxy-containing compound, (d) optionally an extender compound, and (e) optionally a catalyst. The invention also relates to a coated wire and to a coated optical fiber.

摘要翻译： 本发明涉及一种用于光纤的辐射固化二次涂料组合物。 辐射固化二次涂料组合物是通过以下反应制备的不含氨基甲酸酯的α-低聚物：（a）选自含醇丙烯酸酯或含醇甲基丙烯酸酯化合物的丙烯酸酯化合物，（b）酸酐化合物，（c） 含环氧基的化合物，（d）任选的增量化合物，和（e）任选的催化剂。 本发明还涉及涂覆线和涂覆光纤。

公开(公告)号：US08426020B2

公开(公告)日：2013-04-23

申请号：US11955541

申请日：2007-12-13

申请人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Steven R. Schmid ,  Petrus Jacobus Hubertus Niels ,  Paulus Antonius Maria Steeman ,  Xiaosong Wu ,  Wendell Wayne Cattron ,  Tyson Dean Norlin ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： C08F2/50 ,  B05D5/06 ,  D02G3/00 ,  G02B6/00

CPC分类号： G02B1/14 ,  C03C25/1065 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B1/10 ,  G02B6/02395 ,  Y10T428/24942 ,  Y10T428/2933 ,  Y10T428/2942 ,  Y10T428/2947 ,  C08G18/48

摘要： The invention provides an optical fiber coated with a Supercoating, wherein the Supercoating comprises at least two layers, wherein the first layer is a Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a Secondary Coating in contact with the outer surface of the Primary Coating, wherein the cured Primary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 84% to about 99%;B) an in-situ modulus of between about 0.15 MPa and about 0.60 MPa; andC) a Tube Tg, of from about −25° C. to about −55° C.; wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85° C. and 85% relative humidity: A) a % RAU of from about 80% to about 98%; B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and C) a Tube Tg, of from about 50° C. to about 80° C.

摘要翻译： 本发明提供涂覆有超涂层的光纤，其中超涂层包括至少两层，其中第一层是与光纤的外表面接触的主涂层，第二层是接触的第二涂层 其中主要涂层的外表面，其中光纤上的固化的一次涂层在初始固化后和在85℃和85％相对湿度下老化一个月后具有以下性质：A）约84％的％RAU， 至约99％; B）约0.15MPa至约0.60MPa的原位模量; 和C）管Tg，约-25℃至约-55℃; 其中光纤上的固化的二次涂层在初始固化之后和在85℃和85％相对湿度下老化一个月后具有以下性能：A）约80％至约98％的％RAU; B）原位模量在约0.60GPa和约1.90GPa之间; 和C）管Tg，为约50℃至约80℃

公开(公告)号：US08218931B2

公开(公告)日：2012-07-10

申请号：US12611562

申请日：2009-11-03

申请人： Edward J. Murphy ,  Timothy Bishop ,  Steven R. Schmid

发明人： Edward J. Murphy ,  Timothy Bishop ,  Steven R. Schmid

IPC分类号： G02B6/02

CPC分类号： C09D4/06 ,  C03C25/1065 ,  C03C25/36

摘要： A Radiation Curable Coating composition, which may be used as an inner primary coating, an outer primary coating, single coats, a matrix, or a buffer resin composition, comprising: A Radiation Curable Coating composition, which may be used as an inner primary coating, an outer primary coating, single coats, a matrix, or a buffer resin composition, comprising at least one radiation-curable oligomer wherein said at least one radiation curable oligomer is a fatty-acid modified epoxy acrylate; at least one ethylenenic unsaturated reactive diluent; wherein said oligomer(s) and diluent(s) are selected from the group that does not include moieties with Urethane chemistry. This composition, when tested, is found to have resistance to thermal degradation as measured by less than 10% weight loss after exposure of cured specimens in a natural convection furnace for 100 hours at 180° C.

摘要翻译： 一种可用作内部主要涂层，外部初级涂层，单层涂层，基体或缓冲树脂组合物的辐射固化涂料组合物，其包含：可辐射固化涂料组合物，其可用作内部初级涂层 包括至少一种可辐射固化的低聚物，其中所述至少一种可辐射固化的低聚物是脂肪酸改性的环氧丙烯酸酯; 至少一种烯属不饱和反应性稀释剂; 其中所述低聚物和稀释剂选自不含氨基甲酸酯化学部分的基团。 当被测试时，发现该组合物在180℃下在自然对流炉中暴露固化样品100小时后，重量损失小于10％，具有耐热降解性。

公开(公告)号：US07660505B2

公开(公告)日：2010-02-09

申请号：US11735802

申请日：2007-04-16

申请人： David M. Chase ,  Kenneth Dake ,  Kelly A. Hawkinson ,  Jack Kelly ,  Edward J. Murphy

发明人： David M. Chase ,  Kenneth Dake ,  Kelly A. Hawkinson ,  Jack Kelly ,  Edward J. Murphy

IPC分类号： G02B6/02

CPC分类号： C03C25/1065

摘要： An optical fiber comprising a flame retardant UV light-curable tight-buffer coating coated onto the fiber, wherein said tight-buffer coating is substantially halogen-free, and has a limiting oxygen index of at least about 22%, and wherein said tight-buffer coating is removable from said fiber with a strip-force of less than about 1800 grams when the fiber is upjacketed with said coating at a line speed of at least 300 m/min.

摘要翻译： 一种光纤，其包含涂覆在所述纤维上的阻燃UV可光固化的紧缓冲涂层，其中所述紧缓冲涂层基本上不含卤素，并且具有至少约22％的极限氧指数，并且其中所述紧密 - 当纤维用所述涂层以至少300m / min的线速度被覆盖时，缓冲涂层可以以小于约1800克的剥离力从所述纤维中除去。

公开(公告)号：US20080226914A1

公开(公告)日：2008-09-18

申请号：US11955614

申请日：2007-12-13

申请人： Tyson Dean Norlin ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Tyson Dean Norlin ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： G02B6/036 ,  C03B37/01262 ,  C03C25/106 ,  C08G18/672 ,  C08G18/724 ,  C09D5/002 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964 ,  C08G18/48

摘要： Radiation curable coatings for use as a Primary Coating for optical fibers, optical fibers coated with said coatings and processes for coating optical fibers. The radiation curable Primary Coating composition of the instant claimed invention includes an oligomer, a diluent monomer; a photoinitiator; an antioxidant; and an adhesion promoter; wherein said oligomer is the reaction product of: a hydroxyethyl acrylate; an aromatic isocyanate; an aliphatic isocyanate; a polyol; a catalyst; and an inhibitor, wherein said oligomer has a number average molecular weight of from at least about 4000 g/mol to less than or equal to about 15,000 g/μmol; and wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and wherein a cured film of said radiation curable Primary Coating composition has a peak tan delta Tg of from about −25° C. to about −45° C. and a modulus of from about 0.50 MPa to about 1.2 MPa.

摘要翻译： 用作光纤的主要涂层的可辐射固化涂层，涂覆有所述涂层的光纤和用于涂覆光纤的工艺。 本发明的可辐射固化的初级涂料组合物包括低聚物，稀释剂单体; 光引发剂; 抗氧化剂 和粘合促进剂; 其中所述低聚物是以下物质的反应产物：丙烯酸羟乙酯; 芳香族异氰酸酯; 脂族异氰酸酯; 多元醇 催化剂 和抑制剂，其中所述低聚物的数均分子量为至少约4000g / mol至小于或等于约15,000g / mumol; 并且其中所述催化剂选自二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于：1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述可辐射固化的初级涂料组合物的固化膜的峰值tanδTg为约-25℃至约-45℃，模量为约0.50MPa至约1.2MPa。

公开(公告)号：US20080226913A1

公开(公告)日：2008-09-18

申请号：US11955604

申请日：2007-12-13

申请人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

发明人： Wendell Wayne Cattron ,  Steven R. Schmid ,  Edward J. Murphy ,  John M. Zimmerman ,  Anthony Joseph Tortorello

IPC分类号： B32B17/02 ,  C08L75/04 ,  B32B17/10 ,  C03C25/34

CPC分类号： C03C25/1065 ,  C08G18/6674 ,  C08G18/672 ,  C09D175/16 ,  G02B6/02395 ,  Y10T428/2964

摘要： A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises: α) an Omega Oligomer; and β) an Upsilon Oligomer; wherein said Omega Oligomer is synthesized by the reaction of α1) a hydroxyl-containing (meth)acrylate; α2) an isocyanate; α3) a polyether polyol; and α4) tripropylene glycol; in the presence of α5) a polymerization inhibitor; and α6) a catalyst; to yield the Omega Oligomer; wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and wherein said Upsilon Oligomer is an epoxy diacrylate.

摘要翻译： 描述和要求保护的用于光纤的新的可辐射固化的二次涂层，其中所述组合物包含与第一稀释剂单体混合的第二涂料低聚物混合物; 第二稀释剂单体; 任选地，第三稀释剂单体; 抗氧化剂 第一种光引发剂; 第二光引发剂; 和任选的滑爽添加剂或滑爽添加剂的混合物; 其中所述第二涂料低聚物共混物包含：α）ω-低聚物; 和β）Upsilon低聚物; 其中所述欧米加低聚物通过α1）含羟基的（甲基）丙烯酸酯的反应合成; α2）异氰酸酯; α3）聚醚多元醇; 和α4）三丙二醇; 在α5的存在下）聚合抑制剂; 和α6）催化剂; 产生欧米茄低聚物; 其中所述催化剂选自二月桂酸二丁基锡; 金属羧酸盐，包括但不限于：有机铋催化剂如新戊酸铋; 新癸酸锌; 新癸酸锆; 2-乙基己酸锌; 磺酸，包括但不限于十二烷基苯磺酸，甲磺酸; 氨基或有机碱催化剂，包括但不限于：1,2-二甲基咪唑和二氮杂双环辛烷; 三苯基膦 锆和钛的醇盐包括但不限于丁氧基锆和丁醇钛; 和离子液体鏻盐; 和十四烷基（三己基）鏻氯化物; 并且其中所述Upsilon低聚物是环氧二丙烯酸酯。

公开(公告)号：US06265476B1

公开(公告)日：2001-07-24

申请号：US09411326

申请日：1999-10-04

申请人： Vadim V. Krongauz ,  Michael G. Sullivan ,  Stephen C. Lapin ,  Edward J. Murphy

发明人： Vadim V. Krongauz ,  Michael G. Sullivan ,  Stephen C. Lapin ,  Edward J. Murphy

IPC分类号： C08K537

CPC分类号： C09D175/16 ,  C08F290/067 ,  C08G18/10 ,  C08G18/672 ,  C09D4/06 ,  Y10T428/2938 ,  Y10T428/31645

摘要： Radiation-curable compositions, having high elongation at break and toughness after cure can include the following pre-mixture components: a) a polymer, oligomer or monomer having at least one (meth)acrylate functional group; b) an oligomer or monomer, exclusive of (meth)acrylate functional groups, having an ethylenically unsaturated functional group; and c) an elongation promoter; wherein the composition, after radiation-cure, has an elongation at break of at least about 200%. Glass substrates and optical fibers are coated with the radiation-curable composition. Monofilament fiber or a plurality of fiber filaments, such as sewing thread, are coated with the radiation-curable binder composition, which after cure, demonstrates high elongation at break.

摘要翻译： 具有高的断裂伸长率和固化后的韧性的可辐射固化组合物可以包括以下预混物组分：a）具有至少一个（甲基）丙烯酸酯官能团的聚合物，低聚物或单体; b）低聚物或单体， 的具有烯键式不饱和官能团的（甲基）丙烯酸酯官能团; 和c）伸长促进剂;其中所述组合物在辐射固化后具有至少约200％的断裂伸长率。 用可辐射固化组合物涂覆玻璃基材和光纤。 单丝纤维或多根纤维丝，例如缝纫线，用可辐射固化粘合剂组合物涂覆，其固化后表现出高的断裂伸长率。