公开(公告)号：US4954653A

公开(公告)日：1990-09-04

申请号：US362509

申请日：1989-06-07

申请人： Giuseppe Bellussi ,  Franco Buonomo ,  Antonio Esposito ,  Mario Clerici ,  Ugo Romano ,  Bruno Notari

发明人： Giuseppe Bellussi ,  Franco Buonomo ,  Antonio Esposito ,  Mario Clerici ,  Ugo Romano ,  Bruno Notari

IPC分类号： B01J29/89 ,  C07C37/60 ,  C07D301/12 ,  C07D303/04

CPC分类号： C07D303/04 ,  B01J29/89 ,  C07C37/60 ,  C07C41/26 ,  C07D301/12

摘要： The invention discloses a catalyst on the basis of silicon and titanium having the form of microspheres and constituted by oligomeric silica and by titanium-silica-lite crystals having an oligomeric silica/titanium-silicalite molar ratio comprised within the range of from 0.05 to 0.11, wherein the crystals of titanium-silicalite are encaged by means of Si-O-Si bridges.

公开(公告)号：US4895988A

公开(公告)日：1990-01-23

申请号：US110329

申请日：1987-10-20

申请人： Mario G. Clerici ,  Giuseppe Bellussi

发明人： Mario G. Clerici ,  Giuseppe Bellussi

IPC分类号： B01J29/04 ,  B01J27/00 ,  B01J29/86 ,  B01J29/88 ,  B01J29/89 ,  B01J39/14 ,  C07B31/00 ,  C07B37/04 ,  C07B61/00 ,  C07C1/00 ,  C07C2/86 ,  C07C15/12 ,  C07C15/16 ,  C07C27/00 ,  C07C37/16 ,  C07C37/20 ,  C07C39/16 ,  C07C41/00 ,  C07C41/30 ,  C07C43/205 ,  C07C67/00 ,  C07C39/12

CPC分类号： C07C41/30 ,  B01J29/86 ,  B01J29/89 ,  C07C37/115 ,  C07C37/20 ,  Y02P20/582

摘要： The mutual condensation of aromatic and carbonylic compounds is carried out with zeolitic materials derived from silicalite by replacing a portion of silicon with B and Al, Al and Ti, Ti and Fe, and with ZSM-5, to yield diaryl-alkanes.

摘要翻译： 芳烃和羰基化合物的相互缩合通过用B和Al，Al和Ti，Ti和Fe以及ZSM-5代替一部分硅来产生硅沸石的沸石材料进行，得到二芳基烷烃。

公开(公告)号：US09278339B2

公开(公告)日：2016-03-08

申请号：US13499452

申请日：2010-09-23

申请人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

发明人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

IPC分类号： B01J21/00 ,  B01J23/00 ,  B01J29/00 ,  B01J31/00 ,  B01J27/049 ,  B01J27/051 ,  B01J35/10 ,  B01J37/03 ,  B01J37/20 ,  C10G45/08

CPC分类号： B01J27/0515 ,  B01J23/002 ,  B01J23/883 ,  B01J23/8885 ,  B01J27/049 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/033 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/1062 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2400/04 ,  C10G2400/06 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/41

摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, O is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

公开(公告)号：US20120261311A1

公开(公告)日：2012-10-18

申请号：US13499452

申请日：2010-09-23

申请人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

发明人： Giuseppe Bellussi ,  Angela Carati ,  Maria Federica Gagliardi ,  Stefano Zanardi ,  Marcello Marella ,  Roberto Scattolin ,  Michele Tomaselli

IPC分类号： B01J21/08 ,  C10G29/16 ,  C10G29/20 ,  B01J27/051 ,  C10G45/00

CPC分类号： B01J27/0515 ,  B01J23/002 ,  B01J23/883 ,  B01J23/8885 ,  B01J27/049 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/033 ,  B01J37/20 ,  B01J2523/00 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/1062 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2400/04 ,  C10G2400/06 ,  B01J2523/31 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/41

摘要： New sulfided metal catalysts are described, containing a metal X selected from Ni, Co and mixtures thereof, a metal Y selected from Mo, W and mixtures thereof, an element Z selected from Si, Al and mixtures thereof, and possibly an organic residue, obtained by the sulfidation of mixed oxide precursors, also new, having general formula (A) XaYbZcOd.pC (A) possibly shaped without a binder, or by sulfidation of mixed oxides having formula (A), in shaped form with a binder, wherein X is selected from Ni, Co and mixtures thereof, Y is selected from Mo, W and mixtures thereof, Z is selected from Si, Al and mixtures thereof, 0 is oxygen, C is selected from: a nitrogenated compound N, an organic residue deriving from the partial calcination of the nitrogenated compound N, said nitrogenated compound N, when present, being selected from: a) an alkyl ammonium hydroxide having formula (I) RIRIIRIIIRIVNOH (I) wherein the groups RI-RIV, the same or different, are aliphatic groups containing from 1 to 7 carbon atoms, b) an amine having formula (II) R1R2R3N (II) wherein R1 is a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, and R2 and R3, the same or different, are selected from H and a linear, branched or cyclic alkyl, containing from 4 to 12 carbon atoms, said alkyl being equal to or different from R1, a, b, c, d are the number of moles of the elements X, Y, Z, O, respectively, p is the weight percentage of C with respect to the total weight of the precursor having formula (A), a, b, c, d are higher than 0 a/b is higher than or equal to 0.3 and lower than or equal to 2, (a+b)/c is higher than or equal to 0.3 and lower than or equal to 10, preferably varying from 0.8 to 10 d=(2a+6b+Hc)/2 wherein H=4 when Z=Si H=3 when Z=Al and p is higher than or equal to 0 and lower than or equal to 40%. Said catalysts can be used as hydrotreating catalysts.

公开(公告)号：US07608231B2

公开(公告)日：2009-10-27

申请号：US12065909

申请日：2006-08-31

申请人： Giuseppe Bellussi ,  Alberto De Angelis ,  Paolo Pollesel ,  Marcello Milli

发明人： Giuseppe Bellussi ,  Alberto De Angelis ,  Paolo Pollesel ,  Marcello Milli

IPC分类号： B01D53/48 ,  C01B17/16 ,  C01B17/04

CPC分类号： B01D53/14 ,  B01D53/1418 ,  B01D53/1425 ,  B01D53/1468 ,  B01D53/1493 ,  C01B17/05 ,  C10L3/10

摘要： Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.

摘要翻译： 用于从含有它的气流中连续除去硫化氢的方法，包括：a）将含有H 2 S的气体与硝酸铁的氧化酸性水溶液接触并含有具有氧化还原性质的杂多酸; b）过滤和分离由氧化还原反应产生的硫; c）用空气将硝酸亚铁氧化成硝酸铁; d）将含有硝酸铁和杂多酸的溶液循环到氧化步骤（a）中; e）使离开氧化反应器（c）的气流经还原溶液洗涤; 和f）排出气流。

公开(公告)号：US20080299026A1

公开(公告)日：2008-12-04

申请号：US12065909

申请日：2006-08-31

申请人： Giuseppe Bellussi ,  Alberto De Angelis ,  Paolo Pollesel ,  Marcello Milli

发明人： Giuseppe Bellussi ,  Alberto De Angelis ,  Paolo Pollesel ,  Marcello Milli

IPC分类号： B01D53/52

CPC分类号： B01D53/14 ,  B01D53/1418 ,  B01D53/1425 ,  B01D53/1468 ,  B01D53/1493 ,  C01B17/05 ,  C10L3/10

摘要： Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.

摘要翻译： 用于从含有它的气流中连续除去硫化氢的方法，包括：a）将含有H 2 S的气体与硝酸铁的氧化酸性水溶液接触并含有具有氧化还原性质的杂多酸; b）过滤和分离由氧化还原反应产生的硫; c）用空气将硝酸亚铁氧化成硝酸铁; d）将含有硝酸铁和杂多酸的溶液循环到氧化步骤（a）中; e）使离开氧化反应器（c）的气流经还原溶液洗涤; 和f）排出气流。

公开(公告)号：US07241931B2

公开(公告)日：2007-07-10

申请号：US11333201

申请日：2006-01-18

申请人： Giannino Pazzuconi ,  Carlo Perego ,  Giuseppe Bellussi

发明人： Giannino Pazzuconi ,  Carlo Perego ,  Giuseppe Bellussi

IPC分类号： C07C5/22 ,  C07C5/27

CPC分类号： B01J29/7034 ,  B01J29/90 ,  B01J38/56 ,  B01J2229/186 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2/864 ,  C07C5/2737 ,  C07C6/126 ,  C07C15/24 ,  C07C2529/70 ,  C07C2602/10 ,  Y02P20/584

摘要： A highly selective process is described for preparing 2,6-dimethylnaphthalene which comprises reacting a naphthalene hydrocarbon selected from naphthalene, methylnaphthalenes, dimethylnaphthalenes, trimethylnaphthalenes, polymethylnaphthalenes, and/or their mixtures with one or more benzene hydrocarbons selected from benzene, toluene, xylenes, trimethylbenzenes, tetramethylbenzenes, pentamethylbenzene and/or hexamethylbenzene, under at least partially liquid phase conditions and in the presence of a catalytic composition comprising a zeolite belonging to the MTW structural type and at least one element selected from P, B and Si. The process is preferably carried out in the presence of a methylating agent.

摘要翻译： 描述了用于制备2,6-二甲基萘的高选择性方法，其包括将选自萘，甲基萘，二甲基萘，三甲基萘，聚甲基萘和/或其混合物的萘烃与一种或多种选自苯，甲苯，二甲苯， 三甲基苯，四甲基苯，五甲基苯和/或六甲基苯，在至少部分液相条件下和在包含属于MTW结构类型的沸石和选自P，B和Si中的至少一种元素的催化组合物存在下进行。 该方法优选在甲基化剂的存在下进行。

公开(公告)号：US06689819B2

公开(公告)日：2004-02-10

申请号：US10404041

申请日：2003-04-02

申请人： Giuseppe Bellussi ,  Roberto Zennaro ,  Vincenzo Piccolo ,  Enrico Radaelli ,  Magalie Roy-Auberger

发明人： Giuseppe Bellussi ,  Roberto Zennaro ,  Vincenzo Piccolo ,  Enrico Radaelli ,  Magalie Roy-Auberger

IPC分类号： C07C2706

CPC分类号： C10G2/332 ,  B01J21/04 ,  B01J23/75 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  C07C1/0425

摘要： A supported cobalt-based catalyst, characterized in that the carrier has an average particle diameter, measured by Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured by the B.E.T. method. The catalyst is particularly useful in the Fischer-Tropsch reaction.

摘要翻译： 一种负载的钴基催化剂，其特征在于载体的平均粒径由Coulter LS230测量，范围为70-250μm，表面积高于175m 2 / g，孔体积高于0.35cm <3> / g，由BET测量 方法。 催化剂在费 - 托反应中特别有用。

公开(公告)号：US06596667B2

公开(公告)日：2003-07-22

申请号：US09795105

申请日：2001-03-01

申请人： Giuseppe Bellussi ,  Roberto Zennaro ,  Vincenzo Piccolo ,  Enrico Radaelli ,  Magalie Roy-Auberger

发明人： Giuseppe Bellussi ,  Roberto Zennaro ,  Vincenzo Piccolo ,  Enrico Radaelli ,  Magalie Roy-Auberger

IPC分类号： B01J2340

CPC分类号： C10G2/332 ,  B01J21/04 ,  B01J23/75 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1038 ,  C07C1/0425

摘要： A supported cobalt-based catalyst characterized in that the carrier has an average particle diameter, measured by means of Coulter LS230, ranging from 70 to 250 &mgr;m, a surface area higher than 175 m2/g and a pore volume higher than 0.35 cm3/g, measured with the B.E.T. method. The catalyst is useful in the Fischer-Tropsch reaction.

摘要翻译： 一种负载的钴基催化剂，其特征在于载体具有通过Coulter LS230测量的平均粒径，范围为70-250μm，表面积高于175m 2 / g，孔体积高于0.35cm 3 / g 用BET测量 方法。 该催化剂可用于费 - 托反应。

公开(公告)号：US06524984B2

公开(公告)日：2003-02-25

申请号：US09159751

申请日：1998-09-24

申请人： Angela Carati ,  Giuseppe Bellussi ,  Maria Angela Mantegazza ,  Giudo Petrini

发明人： Angela Carati ,  Giuseppe Bellussi ,  Maria Angela Mantegazza ,  Giudo Petrini

IPC分类号： B01J2906

CPC分类号： C01B37/005 ,  B01J29/06 ,  B01J29/40 ,  B01J2229/32 ,  C01B37/02 ,  C01B39/40 ,  Y10S423/22 ,  Y10S423/29

摘要： A process is described for the preparation of zeolitic catalysts in the form of microspheres, comprising zeolite and oligomeric silica, characterized by a high mechanical resistance. The process consists in subjecting to rapid drying the suspension, to which tetra-alkylorthosilicate is optionally added, resulting from the synthesis of zeolite by hydrothermal treatment at autogenous pressure of the reagent mixture containing tetra-alkylammoniumhydroxide as templating agent, and subjecting the product resulting from the drying to calcination.