公开(公告)号：US20170218097A1

公开(公告)日：2017-08-03

申请号：US15477645

申请日：2017-04-03

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Wanchao Jiang ,  Shijun Feng ,  Siyuan Zhang ,  Yun Lin ,  Andrew J. Poss

IPC: C08F14/18 ,  C08F4/76

CPC classification number: C08F14/185 ,  C08F4/76 ,  C08F14/18 ,  C08F214/18 ,  C08F214/186 ,  C08F214/188 ,  C09D127/12

Abstract: The present invention is directed to partially fluorinated copolymers and the production thereof. More specifically, the copolymers, which are preferably produced by a solution polymerization process, preferably have at least three units, the first unit selected from 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene, the second unit having a polymerized monomer selected from the vinyl esters and vinyl ethers, and the third unit having a polymerized monomer derived from a hydroxyl group-containing vinyl ether. The resulting copolymer is environmentally friendly, has favorable molecular weight characteristics, and may be shipped economically in high concentration.

公开(公告)号：US09532567B2

公开(公告)日：2017-01-03

申请号：US14076624

申请日：2013-11-11

Applicant: Honeywell International Inc.

Inventor： Changqing Lu ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek ,  Cheryl Cantlon

IPC: C09K3/18 ,  A01N29/02 ,  A01N31/00 ,  C08F214/22 ,  C09D5/16 ,  C09D127/16 ,  C08L23/08

CPC classification number: A01N29/02 ,  A01N31/00 ,  C08F214/22 ,  C08F214/222 ,  C08L23/0815 ,  C09D5/16 ,  C09D5/1668 ,  C09D127/16 ,  C08F214/182 ,  C08F216/1408 ,  C08L27/16

Abstract: A copolymer comprising trans-1,3,3,3-tetrafluoropropene units and vinylidene fluoride units, and methods of making the same. A method of preventing biofouling on an article of manufacture, comprising applying such copolymer to the article of manufacture. A process of preparing a surface having a surface energy of between about 20 and about 30 mJ/m2, comprising applying such a copolymer to a support. A method of preventing accumulation of ice on an article of manufacture, comprising applying such a copolymer to an article of manufacture. A method of preparing a polymer, comprising a step of adding trans-1,3,3,3-tetrafluoropropene/vinylidene fluoride copolymer as a polymer processing additive/aid to said polymer.

Abstract translation: 包含反式-1,3,3,3-四氟丙烯单元和偏二氟乙烯单元的共聚物及其制备方法。 一种防止在制品上生物污损的方法，包括将这种共聚物应用于制品。 制备具有约20至约30mJ / m 2的表面能的表面的方法，包括将这样的共聚物施加到载体上。 一种防止在制品上积聚冰的方法，包括将这种共聚物应用于制品。 一种制备聚合物的方法，包括将反式-1,3,3,3-四氟丙烯/偏二氟乙烯共聚物作为聚合物加工添加剂/助剂添加到所述聚合物中的步骤。

公开(公告)号：US20160135450A1

公开(公告)日：2016-05-19

申请号：US14978436

申请日：2015-12-22

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek ,  Cheryl L. Cantlon

IPC: A01N29/02

CPC classification number: A01N29/02 ,  A01N25/30 ,  A01N33/18 ,  A01N35/02 ,  A01N41/12 ,  A01N43/08 ,  A01N43/20 ,  A01N47/08 ,  A01N47/14 ,  A01N2300/00

Abstract: Fumigant compositions including hexafluoropropene or 1,1,3,3,3-pentafluoropropene, and methods of preparing such compositions, are provided herein. The fumigant compositions may be suitable for use as soil fumigant compositions and structural fumigant compositions against a variety of undesirable species such as weeds, nematodes, pathogens, animals and insects. The fumigant compositions also have low toxicity and low Global Warming Potential.

Abstract translation: 本文提供了包括六氟丙烯或1,1,3,3,3-五氟丙烯的熏蒸剂组合物及其制备方法。 熏蒸剂组合物可适用于土壤熏蒸剂组合物和结构熏蒸剂组合物，其针对各种不期望的物种如杂草，线虫，病原体，动物和昆虫。 熏蒸剂组合物也具有低毒性和低全球变暖潜能。

公开(公告)号：US20160023973A1

公开(公告)日：2016-01-28

申请号：US14877225

申请日：2015-10-07

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Haridasan K. Nair ,  Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C07C19/16 ,  C07C323/03 ,  C07C43/13 ,  C07C309/06

CPC classification number: C07C19/16 ,  C07C21/18 ,  C07C41/03 ,  C07C43/137 ,  C07C43/1786 ,  C07C57/03 ,  C07C229/12 ,  C07C309/06 ,  C07C323/03 ,  C07C323/25 ,  C08F14/18 ,  C08F214/18

Abstract: To address the problem of insufficient biodegradability of perfluorinated surfactants, the present invention provides biodegradable fluorosurfactants derived from olefins having —CHR, —CHRf, —CHF, and/or —CH2 groups, where R is an alkyl group and Rf is a perfluoro or fluroroalkyl group. Preferably, the —CHR, —CHRf, —CHF, and/or —CH2 groups are contained within partially fluorinated alkenes.

公开(公告)号：US09126889B2

公开(公告)日：2015-09-08

申请号：US14459375

申请日：2014-08-14

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C11D3/37 ,  C11D3/24 ,  C09D11/00 ,  C07C21/18 ,  C07C57/03 ,  C07C43/178 ,  C07C309/06 ,  C07C323/25 ,  C07C229/12 ,  C08F14/18 ,  C08F214/18 ,  C07C41/03

CPC classification number: C07C19/16 ,  C07C21/18 ,  C07C41/03 ,  C07C43/137 ,  C07C43/1786 ,  C07C57/03 ,  C07C229/12 ,  C07C309/06 ,  C07C323/03 ,  C07C323/25 ,  C08F14/18 ,  C08F214/18

Abstract: To address the problem of insufficient biodegradability of perfluorinated surfactants, the present invention provides biodegradable fluorosurfactants derived from olefins having —CHR, —CHRf, —CHF, and/or —CH2 groups, where R is an alkyl group and Rf is a perfluoro or fluroroalkyl group. Preferably, the —CHR, —CHRf, —CHF, and/or —CH2 groups are contained within partially fluorinated alkenes.

Abstract translation: 为了解决全氟化表面活性剂生物降解性不足的问题，本发明提供了衍生自具有-CHR，-CHRf，-CHF和/或-CH 2基团的烯烃的可生物降解的含氟表面活性剂，其中R是烷基，Rf是全氟或氟烷基 组。 优选地，-CHR，-CHRf，-CHF和/或-CH 2基团包含在部分氟化的烯烃中。

公开(公告)号：US20150112015A1

公开(公告)日：2015-04-23

申请号：US14463747

申请日：2014-08-20

Applicant: Honeywell International Inc.

Inventor： Wanchao Jiang ,  Shijun Feng ,  Siyuan Zhang ,  Yun Lin ,  Andrew J. Poss

IPC: C08F214/18 ,  C09D127/20

CPC classification number: C08F14/185 ,  C08F4/76 ,  C08F14/18 ,  C08F214/18 ,  C08F214/186 ,  C08F214/188 ,  C09D127/12

Abstract: The present invention is directed to partially fluorinated copolymers and the production thereof. More specifically, the copolymers, which are preferably produced by a solution polymerization process, preferably have at least three units, the first unit selected from 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene, the second unit having a polymerized monomer selected from the vinyl esters and vinyl ethers, and the third unit having a polymerized monomer derived from a hydroxyl group-containing vinyl ether. The resulting copolymer is environmentally friendly, has favorable molecular weight characteristics, and may be shipped economically in high concentration.

Abstract translation: 本发明涉及部分氟化共聚物及其制备。 更具体地，优选通过溶液聚合方法制备的共聚物优选具有至少三个单元，第一单元选自2,3,3,3-四氟丙烯和1,3,3,3-四氟丙烯，第二单元 单元，其具有选自乙烯基酯和乙烯基醚的聚合单体，第三单元具有衍生自含羟基的乙烯基醚的聚合单体。 所得共聚物是环境友好的，具有有利的分子量特性，并且可以以高浓度经济运输。

公开(公告)号：US20150065746A1

公开(公告)日：2015-03-05

申请号：US14459375

申请日：2014-08-14

Applicant: Honeywell International Inc.

Inventor： Haridasan K. Nair ,  Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C07C309/20 ,  C07C21/18 ,  C07C57/03 ,  C07C43/178 ,  C07C323/58 ,  C07C229/30

CPC classification number: C07C19/16 ,  C07C21/18 ,  C07C41/03 ,  C07C43/137 ,  C07C43/1786 ,  C07C57/03 ,  C07C229/12 ,  C07C309/06 ,  C07C323/03 ,  C07C323/25 ,  C08F14/18 ,  C08F214/18

Abstract: To address the problem of insufficient biodegradability of perfluorinated surfactants, the present invention provides biodegradable fluorosurfactants derived from olefins having —CHR, —CHRf, —CHF, and/or —CH2 groups, where R is an alkyl group and Rf is a perfluoro or fluroroalkyl group. Preferably, the —CHR, —CHRf, —CHF, and/or —CH2 groups are contained within partially fluorinated alkenes.

Abstract translation: 为了解决全氟化表面活性剂生物降解性不足的问题，本发明提供了衍生自具有-CHR，-CHRf，-CHF和/或-CH 2基团的烯烃的可生物降解的含氟表面活性剂，其中R是烷基，R f是全氟或氟烷基 组。 优选地，-CHR，-CHRf，-CHF和/或-CH 2基团包含在部分氟化的烯烃内。

公开(公告)号：US08791309B2

公开(公告)日：2014-07-29

申请号：US14099560

申请日：2013-12-06

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C07C17/00 ,  C07C17/23

CPC classification number: C07C17/23 ,  C07C17/25 ,  C07C21/22

Abstract: In accordance with the present invention, processes of synthesizing 3,3,3-trifluoropropyne from 1,3,3,3-tetrafluoropropene, 1-chloro-3,3,3-trifluoropropene, and/or 1,1,1,3,3-pentafluoropropane are provided.

Abstract translation: 根据本发明，从1,3,3,3-四氟丙烯，1-氯-3,3,3-三氟丙烯和/或1,1,1,3,3-四氟丙烯合成3,3,3-三氟丙炔的方法 ，提供3-五氟丙烷。

公开(公告)号：US20140179961A1

公开(公告)日：2014-06-26

申请号：US14099560

申请日：2013-12-06

Applicant: Honeywell International Inc.

Inventor： Yian Zhai ,  Andrew J. Poss ,  Rajiv R. Singh ,  David Nalewajek

IPC: C07C17/23

CPC classification number: C07C17/23 ,  C07C17/25 ,  C07C21/22

Abstract: In accordance with the present invention, processes of synthesizing 3,3,3-trifluoropropyne from 1,3,3,3-tetrafluoropropene, 1-chloro-3,3,3-trifluoropropene, and/or 1,1,1,3,3-pentafluoropropane are provided.

Abstract translation: 根据本发明，从1,3,3,3-四氟丙烯，1-氯-3,3,3-三氟丙烯和/或1,1,1,3,3-四氟丙烯合成3,3,3-三氟丙炔的方法 ，提供3-五氟丙烷。

公开(公告)号：US11453731B2

公开(公告)日：2022-09-27

申请号：US16220189

申请日：2018-12-14

Applicant: HONEYWELL INTERNATIONAL INC.

Inventor： Wanchao Jiang ,  Shijun Feng ,  Siyuan Zhang ,  Yun Lin ,  Andrew J. Poss

IPC: C08F14/18 ,  C08F4/76 ,  C08F214/18 ,  C09D127/12

Abstract: The present invention is directed to partially fluorinated copolymers and the production thereof. More specifically, the copolymers, which are preferably produced by a solution polymerization process, preferably have at least three units, the first unit selected from 2,3,3,3-tetrafluoropropene and 1,3,3,3-tetrafluoropropene, the second unit having a polymerized monomer selected from the vinyl esters and vinyl ethers, and the third unit having a polymerized monomer derived from a hydroxyl group-containing vinyl ether. The resulting copolymer is environmentally friendly, has favorable molecular weight characteristics, and may be shipped economically in high concentration.