Low-hygroscopic sulfur-containing urethane resin, coating material and
adhesive
    23.
    发明授权
    Low-hygroscopic sulfur-containing urethane resin, coating material and adhesive 失效
    低吸湿性含硫聚氨酯树脂,涂料和粘合剂

    公开(公告)号:US5126425A

    公开(公告)日:1992-06-30

    申请号:US483768

    申请日:1990-02-23

    摘要: There are here provided a low-hygroscopic sulfur-containing and crosslinked structure-having urethane resin, urethane resin plate and shape-recoverable molding article which is prepared by first selecting a polyisocyanate compound having m (which is an integer of 2 or more) isocyanate groups in one molecule and a polythiol compound having n (which is an integer of 2 or more) thiol groups in one molecule so that the total number of m+n may be 5 or more, and then polymerizing the composition of the polyisocyanate compound and the polythiol compound; a low-hygroscopic sulfur-containing urethane coating material which comprises the above composition; and a low-hygroscopic sulfur-containing urethane adhesive which comprises the composition. In the resin of the present invention, its water absorption is as low as a level of 0.02 to 0.20% by weight, and its adhesion to a hard coating film is also good. The coating material and the adhesive of the present invention have a long pot life, a low water absorption and a high adhesive force even after dipping in warm water.

    摘要翻译: 这里提供了一种低吸湿含硫交联结构的聚氨酯树脂,聚氨酯树脂板和形状可恢复成型制品,其通过首先选择具有m(其为2以上的整数)异氰酸酯的多异氰酸酯化合物 在一个分子中具有n(其为2以上的整数)硫醇基的多硫醇化合物,使得m + n的总数为5以上,然后使多异氰酸酯化合物的组合物和 多硫醇化合物; 包含上述组合物的低吸湿性含硫聚氨酯涂料; 和含有该组合物的低吸湿性含硫聚氨酯粘合剂。 在本发明的树脂中,其吸水率低至0.02〜0.20重量%,对硬涂膜的粘附性也良好。 本发明的涂料和粘合剂即使浸入温水中也具有长使用期,低吸水性和高粘合力。

    High-refractivity plastic lens resin formed by reacting at least one
polyisocyanate with at least one polythiol
    24.
    发明授权
    High-refractivity plastic lens resin formed by reacting at least one polyisocyanate with at least one polythiol 失效
    通过使至少一种多异氰酸酯与至少一种多硫醇反应而形成的高折射率塑料透镜树脂

    公开(公告)号:US4775733A

    公开(公告)日:1988-10-04

    申请号:US19622

    申请日:1987-02-27

    摘要: Disclosed herein are a high-refractivity plastic lens resin obtained by polymerizing under heat at least one polyisocyanate (I): ##STR1## wherein X means a hydrogen, chlorine or bromine atom or a methyl or ethyl group, Z is a hydrogen atom or a methyl group, a stands for an integer of 1-4, b is an integer of 2-4, and a+b is not greater than 6 (a+b.ltoreq.6), with at least one polythiol (II): ##STR2## wherein R means a methyl, ethyl, chloromethyl or bromomethyl group, m stands for an integer of 0-2 and n is 4-m and/or at least one polythiol (III): ##STR3## wherein X means a hydrogen, chlorine or bromine atom or a methyl or ethyl group, Y denotes an oxygen or sulfur atom, r stands for 0 or 1, s is an integer of 0-2, p is an integer of 2-4, q is an integer of 1-4 and p+q is not greater than 6 (p+q.ltoreq.6), in such amounts that the --NCO/--SH molar ratio falls within 0.5-3.0, as well as a lens made of the above resin.

    摘要翻译: 本文公开了通过在加热下聚合至少一种多异氰酸酯(I)获得的高折射率塑料透镜树脂:其中X表示氢,氯或溴原子或甲基或乙基,Z是氢 原子或甲基,a表示1-4的整数,b表示2-4的整数,a + b不大于6(a + b <6),至少有一个多硫醇( II):其中R表示甲基,乙基,氯甲基或溴甲基,m表示0-2的整数,n表示4-m和/或至少一个多硫醇(III):(III)其中X表示氢,氯或溴原子或甲基或乙基,Y表示氧或硫原子,r表示0或1,s表示0-2的整数,p表示 2-4,q是1-4的整数,p + q不大于6(p + q

    Intra-subject position display system
    27.
    发明申请
    Intra-subject position display system 有权
    学科内位置显示系统

    公开(公告)号:US20070002038A1

    公开(公告)日:2007-01-04

    申请号:US11101264

    申请日:2005-04-07

    IPC分类号: G06T15/00

    摘要: An intra-subject position display system for displaying a position of an intra-subject device, which is introduced into a subject and moves therein, wherein a relative position of the intra-subject device to an outer surface of the subject is detected and displayed. The position of the intra-subject device is displayed in a relation with the outer surface of the subject. Thereby, it is possible to easily determine in which site of the subject the intra-subject device exists. The present invention is effective to recognize a position of, for example, a capsule type endoscope or a test capsule therefor in the subject (e.g., a human body). To recognize the outer surface of the subject, for example, a plurality of radio devices are arranged on the outer surface of the subject and their radio signals are analyzed.

    摘要翻译: 一种被摄体内位置显示系统,用于显示被摄体装置的位置,其被引入到被摄体中并在其中移动,其中检测并显示被检体内装置与被检体的外表面的相对位置。 被检体内部的位置与被检体的外表面显示关系。 由此,可以容易地确定被检体内的哪个部位存在受检者内部。 本发明能够有效地识别例如对象(例如人体)中的胶囊型内窥镜或其测试胶囊的位置。 为了识别对象的外表面,例如,多个无线电设备被布置在被摄体的外表面上,并且分析其无线电信号。

    Mercapto compound, its preparation process, and sulfur-containing
urethane resins and lenses using the same
    29.
    发明授权
    Mercapto compound, its preparation process, and sulfur-containing urethane resins and lenses using the same 失效
    巯基化合物,其制备方法和含硫聚氨酯树脂和使用其的透镜

    公开(公告)号:US5352758A

    公开(公告)日:1994-10-04

    申请号:US169708

    申请日:1993-12-20

    摘要: A mercapto compound represented by the following formula (1): ##STR1## is obtained by reacting, in the presence of a mineral acid, thiourea with a compound represented by the following formula (2): ##STR2## wherein X means a hydroxyl group or a chlorine or bromine atom, and then adding a base to alkalinize the reaction mixture so that the reaction product is hydrolyzed.The mercapto compound represented by the formula (1) can be reacted with at least one cyanate compound selected from the group consisting of polyisocyanate compounds, polyisothiocyanate compounds and isocyanate-group-containing isothiocyanate compounds to form a sulfur- containing urethane resin. A lens made of the resin is colorless and transparent, has high refractive index and low dispersion characteristics, and is excellent especially in heat resistance.

    摘要翻译: (1)表示的巯基化合物:通过在无机酸存在下硫脲与下式(2)表示的化合物反应得到:(2) 其中X表示羟基或氯或溴原子,然后加入碱使反应混合物碱化,使反应产物水解。 由式(1)表示的巯基化合物可与至少一种选自多异氰酸酯化合物,多异氰酸酯化合物和含异氰酸酯基的异硫氰酸酯化合物的氰酸酯化合物反应,形成含硫聚氨酯树脂。 由树脂制成的透镜是无色透明的,具有高折射率和低分散特性,特别是耐热性优异。

    Alicyclic diamines, alicyclic diisocyanates and
polyisocyanato-isocyanurates and method for the preparation thereof
    30.
    发明授权
    Alicyclic diamines, alicyclic diisocyanates and polyisocyanato-isocyanurates and method for the preparation thereof 失效
    脂环族二胺,脂环族二异氰酸酯和多异氰酸酯 - 异氰脲酸酯及其制备方法

    公开(公告)号:US5336749A

    公开(公告)日:1994-08-09

    申请号:US18717

    申请日:1993-02-17

    摘要: Herein disclosed are an .alpha.-(aminocyclohexyl)alkylamine represented by the following general formula (II): ##STR1## wherein R represents hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms, provided that the amino group bonded to the cyclohexyl group may be in either of the 2-, 3- and 4-positions and a method for preparing it; an .alpha.-(isocyanatocyclohexyl)alkylisocyanate of Formula (II) wherein the amino groups are replaced with isocyanato groups and a method for preparing it; polyisocyanato-isocyanurate represented by the following general formula (IV): ##STR2## wherein R.sub.1, R.sub.2 and R.sub.3 may be the same or different and each represents a group represented by the following general formula: ##STR3## wherein R represents hydrogen atom or an alkyl group having 1 to 5 carbon atoms and n is an integer ranging from 1 to 5 and a method for preparing it; and a resin obtained by polymerizing an organic polyisocyanate containing not lower than 10% by weight of the polyisocyanato-isocyanurate represented by Formula (IV) and a compound having at least two active hydrogen atoms as well as a resin composition for coating materials which comprises the resin.

    摘要翻译: 本文公开的是由以下通式(II)表示的α-(氨基环己基)烷基胺:其中R表示氢原子或具有1至5个碳原子的低级烷基,条件是与 环己基可以在2-,3-和4-位中的任一个和其制备方法; 其中氨基被异氰酸酯基取代的式(II)的α-(异氰酸根合环己基)烷基异氰酸酯及其制备方法; 由下列通式(Ⅳ)表示的多异氰酸酯 - 异氰脲酸酯:不同且各自表示由以下通式表示的基团:其中R表示氢原子或碳原子数1〜5的烷基,n表示 1至5的整数及其制备方法; 和通过使由式(IV)表示的多异氰酸酯基 - 异氰脲酸酯的10重量%以上的有机多异氰酸酯和具有至少2个活性氢原子的化合物以及用于涂料的树脂组合物聚合而得到的树脂,其包含 树脂。