公开(公告)号：US11958932B2

公开(公告)日：2024-04-16

申请号：US18082726

申请日：2022-12-16

申请人： LAWRENCE LIVERMORE NATIONAL SECURITY, LLC

发明人： Thomas S. Wilson ,  Michael Keith Hearon ,  Jane P. Bearinger

IPC分类号： C08G18/32 ,  B29C45/00 ,  B29C48/03 ,  B29C61/06 ,  B29C67/20 ,  B29C71/02 ,  B29C71/04 ,  C08G18/67 ,  C08G18/72 ,  C08G18/73 ,  C08G18/75 ,  C08G18/83 ,  C08G63/52 ,  B29C48/00 ,  B29C51/00 ,  B29K75/00 ,  B29K105/04 ,  C08G101/00

CPC分类号： C08G18/3206 ,  B29C45/0001 ,  B29C48/03 ,  B29C61/06 ,  B29C67/20 ,  B29C71/02 ,  B29C71/04 ,  C08G18/673 ,  C08G18/675 ,  C08G18/722 ,  C08G18/73 ,  C08G18/758 ,  C08G18/83 ,  C08G63/52 ,  B29C48/00 ,  B29C51/00 ,  B29C51/002 ,  B29K2075/00 ,  B29K2105/04 ,  C08G2101/00 ,  C08G2280/00

摘要： This invention relates to chemical polymer compositions, methods of synthesis, and fabrication methods for devices regarding polymers capable of displaying shape memory behavior (SMPs) and which can first be polymerized to a linear or branched polymeric structure, having thermoplastic properties, subsequently processed into a device through processes typical of polymer melts, solutions, and dispersions and then crossed linked to a shape memory thermoset polymer retaining the processed shape.

公开(公告)号：US20240075455A1

公开(公告)日：2024-03-07

申请号：US18262278

申请日：2022-01-24

申请人： Ohio University

发明人： Andrew Weems

IPC分类号： B01J20/26 ,  A61L27/18 ,  C08G83/00

CPC分类号： B01J20/264 ,  A61L27/18 ,  C08G83/003 ,  C08G2101/00 ,  C08G2280/00

摘要： A shape memory polymer foam comprising a reaction product of a reaction of an epoxide and a thiol monomer in the presence of an organobase is provided. In addition, a method of making the shape memory polymer foam is provided. The method includes reacting an epoxide with thiol monomers in the presence of an organobase to form the shape memory polymer foam.

公开(公告)号：US11781993B2

公开(公告)日：2023-10-10

申请号：US17903312

申请日：2022-09-06

申请人： University of Florida Research Foundation, Inc.

发明人： Sin Yen Leo ,  Peng Jiang ,  Tianwei Xie

IPC分类号： G01N21/78 ,  G01N21/25 ,  G01N21/27 ,  G01N33/28 ,  G01N21/77 ,  G02B1/00 ,  C08G18/67 ,  C08G18/81 ,  C08J9/26 ,  C08G101/00

CPC分类号： G01N21/78 ,  C08G18/6755 ,  C08G18/81 ,  C08J9/26 ,  G01N21/25 ,  G01N21/255 ,  G01N21/272 ,  G01N33/2852 ,  C08G2101/00 ,  C08G2280/00 ,  C08J2201/0442 ,  C08J2205/044 ,  C08J2375/14 ,  G01N2021/7723 ,  G01N2021/7773 ,  G02B1/005

摘要： Embodiments of the present disclosure provide for methods of detecting, sensors (e.g., chromogenic sensor), kits, compositions, and the like that related to or use tunable macroporous polymer. In an aspect, tunable macroporous materials as described herein can be used to determine the presence of a certain type(s) and quantity of liquid in a liquid mixture.

公开(公告)号：US20230192938A1

公开(公告)日：2023-06-22

申请号：US17918054

申请日：2021-04-15

申请人： SMART MATERIALS LIMITED

发明人： Keith Mario AZZOPARDI ,  Matthew Anthony XUEREB ,  Ruben GATT

IPC分类号： C08G18/38 ,  C08G18/16 ,  C08G18/20 ,  C08G18/24 ,  C08G18/66 ,  C08G18/48 ,  C08G18/32 ,  C08G18/76 ,  C08J9/12 ,  C08J9/02

CPC分类号： C08G18/3893 ,  C08G18/165 ,  C08G18/2063 ,  C08G18/244 ,  C08G18/6677 ,  C08G18/4837 ,  C08G18/3206 ,  C08G18/7621 ,  C08J9/125 ,  C08J9/02 ,  C08G2110/0058 ,  C08G2110/0066 ,  C08G2280/00 ,  C08G2110/0083 ,  C08J2375/08 ,  C08J2205/05 ,  C08J2201/022 ,  C08J2203/10

摘要： A method for the synthesis of an auxetic polyurethane foam with a defined cell structure and an auxetic polyurethane foam substrate obtainable by a method according to the invention. The method includes mixing a polyol reagent and a foaming reagent, forming a reaction mixture, mixing an isocyanate with the reaction mixture, compressing and/or contracting the isocyanate/reaction mixture, and allowing the compressed and/or contracted isocyanate/reaction mixture to cure.

公开(公告)号：US20230183471A1

公开(公告)日：2023-06-15

申请号：US17550653

申请日：2021-12-14

申请人： Saudi Arabian Oil Company ,  William Marsh Rice University

发明人： Hasmukh A. Patel ,  Ali Zein Khater ,  Peter Boul ,  Pulickel M. Ajayan ,  Muhammad M. Rahman

IPC分类号： C08L63/00 ,  C08G83/00 ,  B33Y70/00 ,  B33Y10/00

CPC分类号： C08L63/00 ,  C08G83/007 ,  B33Y70/00 ,  B33Y10/00 ,  C08G2280/00

摘要： This document relates to shape memory compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin. The shape memory compositions are able to deform and reform in response to external stimuli. This document also relates to 3D-printed shape memory compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin.

公开(公告)号：US20190077955A1

公开(公告)日：2019-03-14

申请号：US16019353

申请日：2018-06-26

申请人： Elevance Renewable Sciences, Inc.

发明人： Allyson Beuhler ,  Debra Tindall ,  Kamlesh Mody ,  Donald A. Meltzer

IPC分类号： C08L75/06 ,  C08G18/42 ,  C08G81/00 ,  C08G63/16 ,  C08G18/32 ,  C08L101/00 ,  C08G18/66 ,  C08G18/76 ,  C08L75/04

CPC分类号： C08L75/06 ,  C08G18/3206 ,  C08G18/42 ,  C08G18/4238 ,  C08G18/4263 ,  C08G18/664 ,  C08G18/7671 ,  C08G63/16 ,  C08G81/00 ,  C08G2280/00 ,  C08L101/00 ,  C08L75/04

摘要： Polyester polyols are generally disclosed, including methods of making and using them. In some embodiments, the polyester polyols are incorporated into a block copolymer, such as a polyurethane block copolymer. In some embodiments, the polyurethane block copolymers can be used as compatibilizing agents, which can be used, for example, in polymer blends, polymer alloys, solutions, emulsions, as well as in extruded and injection molded articles. In some embodiments, at least a portion of the polyurethane block copolymer is derived from a renewable source.

公开(公告)号：US20180155492A1

公开(公告)日：2018-06-07

申请号：US15579629

申请日：2016-06-06

申请人： The University of Rochester

发明人： Mitchell ANTHAMATTEN ,  Yuan MENG

IPC分类号： C08G63/688 ,  C08G63/08 ,  C08G63/91

CPC分类号： C08G63/6882 ,  C08G63/08 ,  C08G63/912 ,  C08G2280/00 ,  G01N25/4866 ,  G01R33/46

摘要： Described are shape-memory polymers that have a composite prepolymer crosslinked with a stoichiometric amount of a multifunctional crosslinker, the composite prepolymer having a branched or telechelic prepolymer having a low polydispersity reacted with a non-crystalline chain extender. Also described are methods of making shape-memory polymers by reacting a branched or telechelic prepolymer having a low polydispersity with a non-crystalline chain extender to form a composite prepolymer, and crosslinking a stoichiometric amount of a multifunctional crosslinker with the composite prepolymer, thereby forming the shape-memory polymer.

公开(公告)号：US09822222B2

公开(公告)日：2017-11-21

申请号：US14748144

申请日：2015-06-23

申请人： Agency for Science, Technology and Research

发明人： Xian Jun Loh ,  Jun Li

IPC分类号： A61L27/50 ,  C08G81/00 ,  A61L27/14 ,  A61L27/58 ,  A61L29/04 ,  A61L29/14 ,  A61L31/04 ,  A61L31/14 ,  B29C61/00 ,  C08G18/42 ,  C08G18/61 ,  C08G18/73 ,  C08G63/08 ,  C08G63/664 ,  C08G77/458 ,  C08L87/00 ,  C09D187/00 ,  A61K47/34 ,  C08G77/16 ,  C08K5/57

CPC分类号： C08G81/00 ,  A61K47/34 ,  A61L27/14 ,  A61L27/50 ,  A61L27/58 ,  A61L29/04 ,  A61L29/14 ,  A61L29/148 ,  A61L31/04 ,  A61L31/14 ,  A61L31/148 ,  A61L2400/16 ,  B29C61/003 ,  C08G18/4277 ,  C08G18/61 ,  C08G18/73 ,  C08G63/08 ,  C08G63/664 ,  C08G77/16 ,  C08G77/458 ,  C08G2230/00 ,  C08G2261/126 ,  C08G2280/00 ,  C08K5/57 ,  C08L87/005 ,  C08L2201/12 ,  C09D187/005

摘要： This invention relates to shape memory block copolymers comprising: at least one switching segment having a Ttrans from 10 to 70° C.; and at least one soft segment, wherein at least one of the switching segments in linked to at least one of the soft segments by at least one linkage, and wherein the copolymer transforms from a first shape to a second shape by application of a first stimulus and the copolymer transforms back to the first shape from the second shape by application of a second stimulus. The shape memory block copolymers may be biocompatible and biodegradable.

公开(公告)号：US20170066921A1

公开(公告)日：2017-03-09

申请号：US15190914

申请日：2016-06-23

申请人： Elevance Renewable Sciences, Inc.

发明人： Allyson Beuhler ,  Debra Tindall ,  Kamlesh Mody ,  Donald A. Meltzer

IPC分类号： C08L75/06 ,  C08G63/16 ,  C08G18/42 ,  C08G81/00

CPC分类号： C08L75/06 ,  C08G18/3206 ,  C08G18/42 ,  C08G18/4238 ,  C08G18/4263 ,  C08G18/664 ,  C08G18/7671 ,  C08G63/16 ,  C08G81/00 ,  C08G2280/00 ,  C08L101/00 ,  C08L75/04

摘要： Polyester polyols are generally disclosed, including methods of making and using them. In some embodiments, the polyester polyols are incorporated into a block copolymer, such as a polyurethane block copolymer. In some embodiments, the polyurethane block copolymers can be used as compatibilizing agents, which can be used, for example, in polymer blends, polymer alloys, solutions, emulsions, as well as in extruded and injection molded articles. In some embodiments, at least a portion of the polyurethane block copolymer is derived from a renewable source.

摘要翻译： 通常公开了聚酯多元醇，包括制备和使用它们的方法。 在一些实施方案中，将聚酯多元醇引入嵌段共聚物中，例如聚氨酯嵌段共聚物。 在一些实施方案中，聚氨酯嵌段共聚物可以用作相容剂，其可以用于例如聚合物共混物，聚合物合金，溶液，乳液以及挤出和注模制品中。 在一些实施方案中，聚氨酯嵌段共聚物的至少一部分来自可再生来源。

公开(公告)号：US20170002130A1

公开(公告)日：2017-01-05

申请号：US15269516

申请日：2016-09-19

申请人： LAWRENCE LIVERMORE NATIONAL SECURITY, LLC ,  The Texas A&M University System

发明人： Pooja Singhal ,  Thomas S. Wilson ,  Elizabeth Cosgriff-Hernandez ,  Duncan J. Maitland

IPC分类号： C08G18/66 ,  C08J9/00 ,  C08G18/10 ,  C08G18/16 ,  C08G18/73 ,  C08G18/08

CPC分类号： C08G18/6622 ,  A61B17/0057 ,  A61B2017/00592 ,  A61B2017/00606 ,  A61B2017/00623 ,  C08G18/10 ,  C08G18/14 ,  C08G18/165 ,  C08G18/73 ,  C08G63/00 ,  C08G63/6852 ,  C08G71/04 ,  C08G2101/005 ,  C08G2101/0083 ,  C08G2230/00 ,  C08G2280/00 ,  C08J9/00 ,  C08J2375/06

摘要： Compositions and/or structures of degradable shape memory polymers (SMPs) ranging in form from neat/unfoamed to ultra low density materials of down to 0.005 g/cc density. These materials show controllable degradation rate, actuation temperature and breadth of transitions along with high modulus and excellent shape memory behavior. A method of making extremely low density foams (up to 0.005 g/cc) via use of combined chemical and physical blowing agents, where the physical blowing agents may be a single compound or mixtures of two or more compounds, and other related methods, including of using multiple co-blowing agents of successively higher boiling points in order to achieve a large range of densities for a fixed net chemical composition. Methods of optimization of the physical properties of the foams such as porosity, cell size and distribution, cell openness etc. of these materials, to further expand their uses and improve their performance.

摘要翻译： 范围从纯/未发泡到超低密度材料形式的可降解形状记忆聚合物（SMP）的组合物和/或结构，其浓度低至0.005g / cc。 这些材料显示可控的降解速率，致动温度和转变幅度以及高模量和优异的形状记忆行为。 通过使用组合的化学和物理发泡剂制造极低密度泡沫（高达0.005g / cc）的方法，其中物理发泡剂可以是单一化合物或两种或更多种化合物的混合物，以及其它相关方法，包括 使用多个连续较高沸点的共发泡剂，以实现固定净化学成分的大范围密度。 优化泡沫物理性能的方法，如孔隙度，孔径，分布，细胞开放度等，进一步扩大使用范围，提高其性能。