Polyolefin production
    21.
    发明授权

    公开(公告)号:US06579822B2

    公开(公告)日:2003-06-17

    申请号:US10066440

    申请日:2002-01-31

    IPC分类号: B01J3100

    摘要: A metallocene compound having the general formula: CpAXMQ1Q2Cp′A′X′M′Q1′Q2′ wherein Cp and Cp′ are each independently a substituted or unsubstituted cyclopentadienyl moiety; M and M′ are each independently a metal chosen from Group IV B transition metals and vanadium, and coordinate to Cp and Cp′ respectively; X and X′ are each independently a substituted or unsubstituted Group VA or VIA heteroatom and coordinate to M and M′ respectively; A and A′ are bridging groups between Cp and X and between Cp′ and X′ respectively and are independently chosen from —SiR′2—O—SiR′2—, —SinR′m—, —CnR′m— and —CR′2—SiR′2—CR′2—SiR′2—, in which each R′ is independently H or hydrocarbyl having 1 to 20 carbon atoms, n is an integer in the range 1 to 4 and m=2n; each Q1, Q2 and Q1′ and Q2′ is independently a coordinating group which is hydrogen, halogen or hydrocarbyl having 1 to 20 carbon atoms and each of Q1 and Q1′ is coordinated to both M and M′.