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21.发明授权
公开(公告)号：US6080303A
公开(公告)日：2000-06-27
申请号：US38649
申请日：1998-03-11
申请人： Guang Cao , Luc R. M. Martens , Jeffrey L. White , Tan-Jen Chen , Matu J. Shah
发明人： Guang Cao , Luc R. M. Martens , Jeffrey L. White , Tan-Jen Chen , Matu J. Shah
摘要： The present invention provides a process for improving the catalytic activity of small and medium pore acidic zeolite catalyst which comprises the steps of treating a zeolite with a phosphorus compound to form a phosphorus treated zeolite and combining the phosphorus treated zeolite with AlPO.sub.4. Optionally the phosphorus treated zeolite is calcined. The step of combining the zeolite with AlPO.sub.4 may optionally be followed by steaming the combined catalyst. Examples of useful phosphorus containing compounds useful in treating the zeolite include phosphoric acid, ammonium mono or dihydrogen phosphate, organic phosphites, and organophosphines. Preferably the phosphorus containing compound is an ammonium acid phosphate. An additional alternate embodiment provides a process for increasing the hydrothermal stability of a zeolite catalyst which comprises first treating a zeolite with a phosphorus containing compound then blending with AlPO.sub.4. The catalyst of the invention may be combined with other catalysts or used alone. The invention may be used in a process for cracking hydrocarbons which comprises contacting a hydrocarbon feedstock with a catalyst prepared as described above.
摘要翻译： 本发明提供了改善中孔酸性沸石催化剂的催化活性的方法，其包括用磷化合物处理沸石以形成磷处理的沸石并将磷处理的沸石与AlPO 4组合的步骤。 任选地，将经磷处理的沸石煅烧。 将沸石与AlPO 4组合的步骤可以任选地随后蒸合组合的催化剂。 可用于处理沸石的含磷化合物的实例包括磷酸，磷酸一铵或二磷酸酯，有机亚磷酸酯和有机膦。 含磷化合物优选为磷酸铵。 另外的替代实施方案提供了一种提高沸石催化剂的水热稳定性的方法，其包括首先用含磷化合物处理沸石，然后与AlPO 4共混。 本发明的催化剂可与其它催化剂组合使用或单独使用。 本发明可用于裂解烃的方法，其包括使烃原料与如上所述制备的催化剂接触。
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22.发明授权
公开(公告)号：US5284574A
公开(公告)日：1994-02-08
申请号：US851037
申请日：1992-03-12
CPC分类号： C10G9/32
摘要： A fluid coking-gasification process for converting heavy hydrocarbonaceous chargestocks to lower boiling products in which an inorganic metal composition is used to mitigate slagging in the gasifier, wherein the metal is selected from the alkaline-earths, the rare earths, and zirconium. The inorganic metal composition is added either directly into the gasifier or it is mixed with the coke passing from the heating zone to the gasification zone.
摘要翻译： 一种用于将重质含烃物料转化为较低沸点产物的流化焦化气化方法，其中使用无机金属组合物来减轻气化器中的结渣，其中金属选自碱土金属，稀土和锆。 将无机金属组合物直接加入到气化器中，或者将其与通过加热区的焦炭混合到气化区。
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公开(公告)号：US5107058A
公开(公告)日：1992-04-21
申请号：US622688
申请日：1990-12-05
申请人： Tan-Jen Chen , James R. Sweet
发明人： Tan-Jen Chen , James R. Sweet
IPC分类号： C07C7/144
CPC分类号： C07C7/144
摘要： Olefins are selectively separated from hydrocarbon feeds containing mixtures of olefins and paraffins by contacting said hydrocarbon feed mixture with one side of a micro-porous, non-selective partition barrier membrane while simultaneously passing, preferably in countercurrent flow, along the opposite side of said membrane a polar solvent. The olefin preferentially passes through said micro-porous non selective partition barrier in response to the polar solvent yielding a permeate enriched in olefin and a retentate enriched in paraffin as compared to the original feed stream.
摘要翻译： 通过使所述烃进料混合物与微孔非选择性分隔阻隔膜的一侧接触，同时通过，优选逆流，沿着所述膜的相对侧，将烯烃与包含烯烃和链烷烃的混合物的烃进料选择性分离 极性溶剂。 与原始进料流相比，响应于极性溶剂产生富含烯烃的渗透物和富含石蜡的滞留物，烯烃优先通过所述微孔非选择性分隔壁。
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24.发明授权Integrated coking-gasification process with mitigation of bogging and slagging 失效综合焦化气化过程，减轻了流化床和结渣
公开(公告)号：US5094737A
公开(公告)日：1992-03-10
申请号：US591335
申请日：1990-10-01
IPC分类号： C10G9/32
CPC分类号： C10G9/32
摘要： A fluid coking-gasification process for converting heavy hydrocarbonaceous chargestocks to lower boiling products in which calcium silicate is used to mitigate bogging, slagging, or both. The calcium silicate can be added directly to the heavy hydrocarbonaceous chargestock to mitigate both bogging and slagging or it can be added directly into the gasifier to mitigate slagging.
摘要翻译： 用于将重质含烃物料转化为较低沸点产物的流化焦化气化方法，其中使用硅酸钙来缓解沉淀，结渣或两者。 可以将硅酸钙直接加入到重质含烃物料中以减少淤渣和结渣，或者将其直接加入到气化器中以减轻结渣。
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25.发明授权Selective multi-ring aromatics extraction using a porous, non-selective partition membrane barrier 失效选择性多环芳烃萃取采用多孔非选择性分隔膜屏障
公开(公告)号：US5045206A
公开(公告)日：1991-09-03
申请号：US622706
申请日：1990-12-05
申请人： Tan-Jen Chen , James R. Sweet
发明人： Tan-Jen Chen , James R. Sweet
CPC分类号： B01D61/246 , B01D11/0415 , C07C7/144 , C10G31/11
摘要： Multi-ring aromatic hydrocarbons and/or toxins are selectively solvent extracted from hydocarbon feed streams by the process comprising contacting the aromatics and/or toxins containing hydrocarbon stream with one side of a porous, non-selective partition barrier membrane while simultaneously contacting the other side of said membrane with an aromatics selective extraction solvent whereby the multi-ring aromatic hydrocarbons and/or toxins selectively migrate through the porous partition barrier membrane in response to the selective solvent. A preferred extraction solvent is ethylenediamine. The permeate comprising multi-ring aromatics in solvent can be subjected to a membrane separation process to separate the extraction solvent from the aromatics.
摘要翻译： 多环芳烃和/或毒素通过包括将含芳烃和/或毒素的烃流与多孔非选择性分隔壁隔膜的一侧接触的方法从碳氢化合物进料流中选择性溶剂萃取，同时使另一侧接触 的所述膜具有芳族选择性提取溶剂，由此多环芳族烃和/或毒素响应于选择性溶剂选择性地迁移穿过多孔分隔壁。 优选的提取溶剂是乙二胺。 在溶剂中包含多环芳族化合物的渗透物可以进行膜分离过程以将萃取溶剂与芳族化合物分离。
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公开(公告)号：US08487140B2
公开(公告)日：2013-07-16
申请号：US12996219
申请日：2009-07-14
CPC分类号： C07C37/06 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , C07C13/28 , C07C39/04 , C07C49/403 , C07C409/14
摘要： In a process for producing phenol, cyclohexylbenzene is oxidized to produce cyclohexylbenzene hydroperoxide and then the resultant cyclohexylbenzene hydroperoxide is cleaved to produce an effluent stream comprising phenol and cyclohexanone. At least a portion of the effluent stream is then fed to at least one dehydrogenation reaction zone, where the effluent stream portion is contacted with a dehydrogenation catalyst under conditions effective to convert at least part of the cyclohexanone in the effluent portion into phenol and hydrogen.
摘要翻译： 在生产苯酚的方法中，将环己基苯氧化生产环己基苯氢过氧化物，然后将所得的环己基苯氢过氧化物切割以产生包含苯酚和环己酮的流出物流。 然后将至少一部分流出物流送入至少一个脱氢反应区，其中流出物流部分与脱氢催化剂在有效地将流出物部分中的至少一部分环己酮转化为酚和氢的条件下接触。
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公开(公告)号：US08106243B2
公开(公告)日：2012-01-31
申请号：US12933709
申请日：2009-02-23
CPC分类号： C07C37/06 , C07C2/74 , C07C6/126 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are contacted with a catalyst under hydroalkylation conditions to produce an effluent containing cyclohexylbenzene. The catalyst comprises a composite of a molecular sieve, an inorganic oxide different from said molecular sieve and at least one hydrogenation metal, wherein at least 50 wt % of said hydrogenation metal is supported on the inorganic oxide and the inorganic oxide has an average particle size less than 40 μm (microns).
摘要翻译： 在生产环己基苯的方法中，苯和氢在加氢烷基化条件下与催化剂接触以产生含有环己基苯的流出物。 催化剂包括分子筛，不同于所述分子筛的无机氧化物和至少一种氢化金属的复合物，其中至少50重量％的所述氢化金属负载在无机氧化物上，无机氧化物具有平均粒度 小于40μm（微米）。
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公开(公告)号：US20100179351A1
公开(公告)日：2010-07-15
申请号：US12663303
申请日：2008-08-12
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2529/70 , C07C2529/74 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The catalyst system has an acid-to-metal molar ratio of from about 75 to about 750.
摘要翻译： 在生产环己基苯的方法中，将苯和氢气进料至至少一个反应区。 然后使苯和氢在加氢烷基化条件下在至少一个反应区中与包含分子筛的催化剂体系接触，所述催化剂体系包含具有12.4±0.25,6.9±0.15,3.57±0.07的d间距最大值的X射线衍射图， 3.42±0.07埃，和至少一种氢化金属，以生产含有环己基苯的流出物。 催化剂体系具有约75-约750的酸 - 金属摩尔比。
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公开(公告)号：US20060021912A1
公开(公告)日：2006-02-02
申请号：US10903152
申请日：2004-07-30
申请人： Tan-Jen Chen , Paul Keusenkothen , J. Wu , John Buchanan , Guang Cao , Larry Laccino , David Stern , Matthew Vincent
发明人： Tan-Jen Chen , Paul Keusenkothen , J. Wu , John Buchanan , Guang Cao , Larry Laccino , David Stern , Matthew Vincent
IPC分类号： C10G11/05
CPC分类号： C10G11/05 , C10G2400/20
摘要： There is provided a catalyst composition having improved hydrothermal stability for the catalytic cracking of a hydrocarbon feedstock to selectively produce propylene. The catalyst composition comprises a first crystalline molecular sieve selected from the group consisting of IM-5, MWW, ITH, FER, MFS, AEL, and AFO and an effective amount of a stabilization metal (copper, zirconium, or mixtures thereof) exchanged into the molecular sieve. The catalyst finds application in the cracking of naphtha and heavy hydrocarbon feedstocks. When used in the catalytic cracking of heavier hydrocarbon feedstocks, the catalyst composition preferably comprises a second molecular sieve having a pore size that is greater than the pore size of the first molecular sieve. The process is carried out by contacting a feedstock containing hydrocarbons having at least 4 carbon atoms is contacted, under catalytic cracking conditions, with the catalyst composition.
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公开(公告)号：US5318695A
公开(公告)日：1994-06-07
申请号：US982933
申请日：1992-11-30
CPC分类号： C10G11/05
摘要： A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is an amorphous silica-alumina or a zeolitic material having a relatively small unit cell size. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.
摘要翻译： 用于生产相对低排放燃料的流化催化裂化方法。 原料的氮气和芳烃特别低，氢气相对较高。 该催化剂是具有相对小的晶胞尺寸的无定形二氧化硅 - 氧化铝或沸石材料。 原料可以表征为具有小于约50wppm氮; 大于约13重量％ ％氢; 小于约7.5重量％ ％2 +环芳烃芯; 并且不超过约15wt。 ％芳香核心总体。
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