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    Integrated coking-gasification process with mitigation of bogging and slagging
    1.
    发明授权
    Integrated coking-gasification process with mitigation of bogging and slagging 失效
    综合焦化气化过程，减轻了流化床和结渣

    公开(公告)号：US5094737A

    公开(公告)日：1992-03-10

    申请号：US591335

    申请日：1990-10-01

    Applicant: Roby Bearden, Jr. ,  Tan-Jen Chen ,  William N. Olmstead

    Inventor： Roby Bearden, Jr. ,  Tan-Jen Chen ,  William N. Olmstead

    IPC: C10G9/32

    CPC classification number: C10G9/32

    Abstract: A fluid coking-gasification process for converting heavy hydrocarbonaceous chargestocks to lower boiling products in which calcium silicate is used to mitigate bogging, slagging, or both. The calcium silicate can be added directly to the heavy hydrocarbonaceous chargestock to mitigate both bogging and slagging or it can be added directly into the gasifier to mitigate slagging.

    Abstract translation: 用于将重质含烃物料转化为较低沸点产物的流化焦化气化方法，其中使用硅酸钙来缓解沉淀，结渣或两者。 可以将硅酸钙直接加入到重质含烃物料中以减少淤渣和结渣，或者将其直接加入到气化器中以减轻结渣。

    Dehydrogenation Process
    5.
    发明申请
    Dehydrogenation Process 有权
    脱氢工艺

    公开(公告)号：US20120271077A1

    公开(公告)日：2012-10-25

    申请号：US13512625

    申请日：2010-12-17

    Applicant: Teng Xu ,  Stuart L. Soled ,  Edward A. Lemon, JR. ,  Christine E. Kliewer ,  Tan-Jen Chen ,  Joseph E. Baumgartner ,  Sabato Miseo

    Inventor： Teng Xu ,  Stuart L. Soled ,  Edward A. Lemon, JR. ,  Christine E. Kliewer ,  Tan-Jen Chen ,  Joseph E. Baumgartner ,  Sabato Miseo

    IPC: C07C5/367

    CPC classification number: B01J37/0203 ,  B01J23/40 ,  C07C5/367 ,  C07C5/373 ,  C07C13/19 ,  C07C2523/42 ,  Y02P20/52 ,  C07C15/04 ,  C07C9/14

    Abstract: In a dehydrogenation process a hydrocarbon stream comprising at least one non-aromatic six-membered ring compound and at least one five-membered ring compound is contacted with a dehydrogenation catalyst produced by a method comprising treating the support with a liquid composition comprising the dehydrogenation component or a precursor thereof and at least one organic dispersant selected from an amino alcohol and an amino acid. The contacting is conducted under conditions effective to convert at least a portion of the at least one non-aromatic six-membered ring compound in the hydrocarbon stream to benzene and to convert at least a portion of the at least one five-membered ring compound in the hydrocarbon stream to paraffins.

    Abstract translation: 在脱氢方法中，包含至少一种非芳族六元环化合物和至少一种五元环化合物的烃流与脱氢催化剂接触，所述脱氢催化剂通过包括用包含脱氢组分的液体组合物处理载体的方法制备 或其前体和至少一种选自氨基醇和氨基酸的有机分散剂。 该接触在有效将烃流中的至少一种非芳香族六元环化合物的至少一部分转化为苯并将至少一部分至少一种五元环化合物转化为 烃流至石蜡。

    Multi component catalyst and its use in catalytic cracking
    8.
    发明授权
    Multi component catalyst and its use in catalytic cracking 有权
    多组分催化剂及其在催化裂化中的应用

    公开(公告)号：US07326332B2

    公开(公告)日：2008-02-05

    申请号：US10671080

    申请日：2003-09-25

    Applicant: Tan-Jen Chen ,  John Scott Buchanan ,  Brian Erik Henry ,  Paul F. Keusenkothen ,  Philip A. Ruziska ,  David L. Stern

    Inventor： Tan-Jen Chen ,  John Scott Buchanan ,  Brian Erik Henry ,  Paul F. Keusenkothen ,  Philip A. Ruziska ,  David L. Stern

    IPC: C10G11/00 ,  C10G11/05

    CPC classification number: C10G11/05 ,  B01J29/005 ,  B01J29/40 ,  B01J29/85

    Abstract: A multi component catalyst and catalytic cracking process for selectively producing C3 olefins. The catalyst comprises a first molecular sieve having an intermediate pore size, a second molecular sieve and, optionally a third molecular sieve having a large pore size. At least one of the channels of the second molecular sieve has a pore size index that is less than the pore size index of at least one channel of the first molecular sieve. The process is carried out by contacting a feedstock containing hydrocarbons having at least 5 carbon atoms is contacted, under catalytic cracking conditions, with the multi component catalyst. The catalyst finds application in the cracking of naphtha and heavy hydrocarbon feedstocks.

    Abstract translation: 用于选择性制备C 3 O 3烯烃的多组分催化剂和催化裂解方法。 催化剂包括具有中等孔径的第一分子筛，第二分子筛和任选的具有大孔径的第三分子筛。 第二分子筛的至少一个通道的孔径指数小于第一分子筛的至少一个通道的孔径指数。 该方法通过使含有至少5个碳原子的烃的原料在催化裂化条件下与多组分催化剂接触来进行。 该催化剂可用于石脑油和重质烃原料的裂解。

    Method for selectively producing propylene by catalytically cracking an olefinic hydrocarbon feedstock
    9.
    发明授权
    Method for selectively producing propylene by catalytically cracking an olefinic hydrocarbon feedstock 失效
    通过催化裂化烯烃原料选择性生产丙烯的方法

    公开(公告)号：US06429348B1

    公开(公告)日：2002-08-06

    申请号：US09073148

    申请日：1998-05-05

    Applicant: Tan-Jen Chen ,  S. Mark Davis ,  Luc R. M. Martens ,  Marcel J. G. Janssen ,  Philip A. Ruziska

    Inventor： Tan-Jen Chen ,  S. Mark Davis ,  Luc R. M. Martens ,  Marcel J. G. Janssen ,  Philip A. Ruziska

    IPC: C07C406

    CPC classification number: C07C4/06 ,  B01J29/85 ,  C07C2529/84 ,  C07C2529/85 ,  C10G2400/20 ,  Y02P20/52

    Abstract: The invention provides a method for converting an olefinic hydrocarbon feedstock to propylene comprising: contacting a hydrocarbon feedstock under catalytic cracking conditions with a catalyst comprising a catalyst selected from the group consisting of SAPO catalysts, MeAPO catalysts, MeASPO catalysts, ElAPO catalysts, ElASPO catalysts, rare earth exchanged catalysts from any of the preceding groups, and mixtures thereof, under cracking conditions to selectively produce propylene. The invention further provides a method for stabilizing a catalyst to steam from the foregoing group by ion exchange with a rare earth metal. A catalyst has enhanced stability as used herein when treated with a rare earth metal or metals in a concentration effective to provide a catalyst which exhibits a higher conversion of a hydrocarbon feedstock to propylene than does an equal quantity of an untreated sample of the same catalyst under the same conditions following exposure of each catalyst to steam for a period of at least 10 hours.

    Abstract translation: 本发明提供了一种将烯烃原料转化成丙烯的方法，包括：在催化裂化条件下使烃原料与包含选自SAPO催化剂，MeAPO催化剂，MeASPO催化剂，ElAPO催化剂，ElASPO催化剂， 在裂化条件下稀土交换任何前述基团的催化剂及其混合物，以选择性地生产丙烯。 本发明还提供了一种通过与稀土金属离子交换将催化剂稳定化成来自上述组的蒸汽的方法。 当用稀土金属或金属处理时，催化剂具有增强的稳定性，该稀土金属或金属的浓度有效地提供催化剂，其表现出比同样催化剂下的相同催化剂的等量的未处理样品的烃原料比丙烯更高的转化率 在每种催化剂暴露于蒸汽至少10小时的时间后，相同的条件。

    Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process
    10.
    发明授权
    Process for producing polypropylene from C3 olefins selectively produced in a fluid catalytic cracking process 失效
    在流化催化裂化过程中选择性生产的C3烯烃生产聚丙烯的方法

    公开(公告)号：US06388152B1

    公开(公告)日：2002-05-14

    申请号：US09517554

    申请日：2000-03-02

    Applicant: Paul K. Ladwig ,  John E. Asplin ,  Gordon F. Stuntz ,  Tan-Jen Chen

    Inventor： Paul K. Ladwig ,  John E. Asplin ,  Gordon F. Stuntz ,  Tan-Jen Chen

    IPC: C07C406

    CPC classification number: C10G57/02 ,  C10G2400/20

    Abstract: A process for producing polymers from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500° to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone. Overhead products from the reaction zone are passed to a fractionation zone where a stream of C3 products is recovered and a stream rich in C4 and/or C5 olefins is recycled to the stripping zone. The olefins can be further processed and polymerized to form a variety of polymer materials.

    Abstract translation: 本文公开了从由催化裂化或热裂解的石脑油流选择性地生产的烯烃生产聚合物的方法。 将石脑油流引入由反应区，汽提区，催化剂再生区和分馏区构成的工艺单元中。 石脑油原料流在反应区中与含有约10至50wt。 在包括约500℃至650℃的温度和约10至40psia的烃分压的反应条件下具有平均孔径小于约0.7纳米的结晶沸石的％。 蒸气产物被顶部收集，催化剂颗粒在通向催化剂再生区的途中通过汽提区。 挥发物在汽提区中用蒸汽汽提，并将催化剂颗粒送入催化剂再生区，其中焦炭从催化剂燃烧，然后再循环到反应区。 来自反应区的开销产物被送入分馏区，其中回收C3产物流，并且将富含C4和/或C5烯烃的物流再循环到汽提区。 烯烃可以进一步加工和聚合以形成各种聚合物材料。

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