Integrated coking-gasification process with mitigation of bogging and
slagging
    1.
    发明授权
    Integrated coking-gasification process with mitigation of bogging and slagging 失效
    综合焦化气化过程,减轻了流化床和结渣

    公开(公告)号:US5094737A

    公开(公告)日:1992-03-10

    申请号:US591335

    申请日:1990-10-01

    IPC分类号: C10G9/32

    CPC分类号: C10G9/32

    摘要: A fluid coking-gasification process for converting heavy hydrocarbonaceous chargestocks to lower boiling products in which calcium silicate is used to mitigate bogging, slagging, or both. The calcium silicate can be added directly to the heavy hydrocarbonaceous chargestock to mitigate both bogging and slagging or it can be added directly into the gasifier to mitigate slagging.

    摘要翻译: 用于将重质含烃物料转化为较低沸点产物的流化焦化气化方法,其中使用硅酸钙来缓解沉淀,结渣或两者。 可以将硅酸钙直接加入到重质含烃物料中以减少淤渣和结渣,或者将其直接加入到气化器中以减轻结渣。

    Coal as an additive to accelerate thermal cracking in coking
    2.
    发明授权
    Coal as an additive to accelerate thermal cracking in coking 失效
    煤作为添加剂加速焦化中的热裂解

    公开(公告)号:US5228981A

    公开(公告)日:1993-07-20

    申请号:US870165

    申请日:1992-04-16

    IPC分类号: C10G9/00 C10G9/32

    CPC分类号: C10G9/005 C10G9/32

    摘要: A coking process wherein a heavy hydrocarbonaceous chargestock is mixed with a minor amount of coal and preheated to a temperature from about 500.degree. F. up to, but not including, coking temperatures. The pretreated mixture is then reacted in a coking zone at coking conditions.

    摘要翻译: 一种焦化方法,其中将重质烃类带电料与少量煤混合并预热至约500°F至但不包括焦化温度的温度。 然后将预处理的混合物在焦化条件下在焦化区中反应。

    Chemical structural and compositional yields model for predicting hydrocarbon thermolysis products
    3.
    发明授权
    Chemical structural and compositional yields model for predicting hydrocarbon thermolysis products 有权
    用于预测碳氢化合物热解产物的化学结构和组成产量模型

    公开(公告)号:US07344889B2

    公开(公告)日:2008-03-18

    申请号:US10426356

    申请日:2003-04-30

    IPC分类号: G01N33/24

    摘要: A method of predicting the composition of hydrocarbon products of a complex carbonaceous material when exposed to specific time and temperature conditions is disclosed. In one embodiment, the material is characterized to obtain elemental, chemical and structural parameters. A representative chemical structure of the material is constructed based on the characterization information. The representative chemical structure is then stochastically expanded to a molecular ensemble chemical structural model that includes heteroatoms. The chemical structural model is coupled to a compositional yield model and the composition of the material products is determined using kinetic modeling. Methods are provided of constructing a chemical structural model of complex carbonaceous material, of coupling a molecular ensemble of chemical structures to a thermal chemical mechanism, of updating an ensemble of chemical structures during the kinetic modeling to reflect chemical reaction products and of eliminating molecules from the system.

    摘要翻译: 公开了当暴露于特定的时间和温度条件时预测复合碳质材料的烃产物的组成的方法。 在一个实施方案中,该材料的特征在于获得元素,化学和结构参数。 基于特征信息构建材料的代表性化学结构。 然后将代表性的化学结构随机扩展到包括杂原子的分子整体化学结构模型。 化学结构模型与组合产量模型耦合,并且使用动力学模型确定材料产物的组成。 提供了构建复杂碳质材料的化学结构模型的方法,将化学结构的分子组合耦合到热化学机制,在动力学建模期间更新化学结构的集合以反映化学反应产物并从中消除分子 系统。

    Process for removal of heteroatoms under reducing conditions in
supercritical water
    4.
    发明授权
    Process for removal of heteroatoms under reducing conditions in supercritical water 失效
    在超临界水中还原条件下去除杂原子的方法

    公开(公告)号:US5611915A

    公开(公告)日:1997-03-18

    申请号:US583692

    申请日:1996-01-05

    摘要: A process for heteroatom removal-enhancing hydrogenation of highly refractory aromatic ring structures that involves contacting a highly refractory structure having at least one aryl linkage connecting a first heteroaryl moiety and a moiety selected from the group consisting of an aryl moiety and a second heteroaryl moiety with supercritical water having a temperature of from about 400.degree. C. to about 600.degree. C. in the presence of from about 3.4 MPa to about 18.6 MPa of CO to produce lower molecular weight products having decreased aromatic and heteroatom content. The process has utility for producing more valuable lower molecular weight products having a reduced aromatic heteroatom content from starting materials that are highly refractory and widely considered to be difficult to upgrade such as coals and asphaltenes, and model compounds containing the biaryl linkages.

    摘要翻译: 使高难度芳族环结构的杂原子去除增强氢化的方法包括将具有至少一个连接第一杂芳基部分的芳基与选自芳基部分和第二杂芳基部分的部分的至少一个芳基键接触的高度耐火结构与 在约3.4MPa至约18.6MPa的CO存在下,温度为约400℃至约600℃的超临界水,以产生具有降低的芳族和杂原子含量的较低分子量产物。 该方法可用于生产具有降低的芳族杂原子含量的低价分子量产物,所述低分子量产物具有高度耐火且被广泛认为难以升级的起始材料,例如煤和沥青质,以及含有联芳基键的模型化合物。

    Removal of nitrogen and sulfur from oil-shale
    9.
    发明授权
    Removal of nitrogen and sulfur from oil-shale 失效
    从油页岩中去除氮和硫

    公开(公告)号:US4566965A

    公开(公告)日:1986-01-28

    申请号:US630892

    申请日:1984-07-13

    IPC分类号: C10G1/00 C10L9/02 C10G1/02

    CPC分类号: C10L9/02 C10G1/00 C10G1/002

    摘要: Disclosed is a method for enhancing the removal of nitrogen and sulfur from oil-shale which process comprises heating the oil-shale with a basic solution comprised of one or more hydroxides of the alkali metal and alkaline-earth metals.

    摘要翻译: 公开了一种用于增强从油页岩中去除氮和硫的方法,该方法包括用碱金属溶液和碱土金属的一种或多种氢氧化物加热油页岩。