Abstract:
A polymer electrolyte membrane fuel cell is provided. The polymer electrolyte membrane fuel cell includes a phosphoric acid-doped polyimidazole electrolyte membrane and a complex catalyst. In the complex catalyst, an alloy or mixture of a metal and a chalcogen element is supported on a carbon carrier. The polymer electrolyte membrane fuel cell exhibits further improved long-term operation, power generation efficiency, and operational stability at high temperature. The complex catalyst can be produced by a simple method.
Abstract:
Provided are a ceria-based composition having an undoped or metal-doped ceria and an undoped or metal-doped bismuth oxide, wherein the undoped or metal-doped bismuth oxide is present in an amount equal to or more than about 10 wt % and less than about 50 wt % based on the total weight of the ceria-based composition, and at least one selected from the ceria and the bismuth oxide is metal-doped. The ceria-based composition may ensure high sintering density even at a temperature significantly lower than the known sintering temperature of about 1400° C., i.e., for example at a temperature of about 1000° C. or lower, and increase ion conductivity as well.
Abstract:
Disclosed are a method for preparing a pure isophthalaldehyde bisulfite adduct free from impurities through a specific purification process, and use thereof as a starting material for polymerizing polybenzimidazole under a mild condition. According to the present disclosure, it is possible to obtain a pure isophthalaldehyde bisulfite adduct free from impurities, such as unreacted materials or byproducts. In addition, it is possible to accomplish industrial mass production of a high-molecular weight polybenzimidazole by using the adduct as a starting material for polymerizing polybenzimidazole under a mild condition in an organic solvent.
Abstract:
Disclosed is an anode for a molten carbonate fuel cell (MCFC) having improved creep property by adding an additive for imparting creep resistance to nickel-aluminum alloy and nickel as materials for an anode. Improved sintering property, creep property and increased mechanical strength of a molten carbonate fuel cell may be obtained accordingly.
Abstract:
Disclosed are a reversible fuel cell oxygen electrode in which IrO2 is electrodeposited and formed on a porous carbon material and platinum is applied thereon to form a porous platinum layer, a reversible fuel cell including the same, and a method for preparing the same. According to the corresponding reversible fuel cell oxygen electrode, as the loading amounts of IrO2 and platinum used in the reversible fuel cell oxygen electrode can be lowered, it is possible to exhibit excellent reversible fuel cell performances (excellent fuel cell performance and water electrolysis performance) by improving the mass transport of water and oxygen while being capable of reducing the loading amounts of IrO2 and platinum. Further, it is possible to exhibit a good activity of a catalyst when the present disclosure is applied to a reversible fuel cell oxygen electrode and to reduce corrosion of carbon.
Abstract:
Disclosed is an electrolyte membrane for a fuel cell including a polymer blend of a sulfonated polyethersulfone copolymer, hydroxyl group-containing polyethersulfone copolymer and a hydroxyl group-containing sulfonated polyethersulfone copolymer.
Abstract:
Disclosed is a carbon support for a fuel cell catalyst that supports a metal. The carbon support includes a conductive carbon support and nitrogen atoms doped into the conductive carbon support. Also disclosed is a method for preparing the carbon support. Also disclosed is a catalyst including the carbon support. The catalyst has greatly improved degradation resistance compared to conventional catalysts for fuel cells. In addition, the catalyst is not substantially degraded even when applied to a single cell.
Abstract:
Disclosed are a 5-(2,6-dioxyphenyl)tetrazole-containing polymer, a method for preparing the same, a membrane containing the same and an electrochemical device, particularly a high temperature polymer electrolyte membrane fuel cell, including the membrane. The membrane containing the 5-(2,6-dioxyphenyl)tetrazole-containing polymer is capable of providing high proton conductivity and exhibiting good mechanical properties, thereby capable of providing superior fuel cell performance. Accordingly, the membrane may be usefully used in an electrochemical device, particularly a fuel cell, more particularly a high temperature polymer electrolyte membrane fuel cell.
Abstract:
Disclosed is a non-precious metal based water electrolysis catalyst represented by CoX/C (X is at least one selected from the group consisting of P, O, B, S and N) for evolution of hydrogen and oxygen at a cathode and anode, respectively, at the same time, the catalyst including a cobalt-containing compound fixed to a carbon carrier.
Abstract:
Disclosed is a homogeneous catalyst having a single phase of Perovskite oxide, wherein at least one doping element is substituted at site A, site B or sites A and B in ABO3 Perovskite type oxide so that the wettability with a liquid molten carbonate electrolyte may be decreased. The catalyst may have high catalytic activity, inhibit catalyst poisoning caused by creepage and evaporation of a liquid molten carbonate electrolyte, maintain high reaction activity for a long time, provide high methane conversion, and allow production of synthetic gas having a high proportion of hydrogen.