摘要:
The invention relates to azaphospholenes of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.
摘要:
The invention relates to a process for dismutating at least one halosilane and reducing the content of extraneous metal and/or a compound containing extraneous metal in the at least one halosilane and in the at least one silane obtained, by contacting at least one halosilane of the general formula I, HnSiClm (I), where n and m are integers and n=1, 2 or 3 and m=1, 2 or 3 and n+m=4, with a particulate, organic, amino-functional resin to obtain at least one silane of the general formula II, HaSiClb (II), where a and b are integers and a=0, 2, 3 or 4 and b=0, 1, 2 or 4 where a+b=4, in one step, in which the content of extraneous metal and/or compounds containing extraneous metal has been reduced compared to the halosilane of the formula I. The invention further provides for the use of this resin for dismutating halosilanes and as an absorbent of extraneous metals or compounds containing extraneous metal in a process for preparing monosilane.
摘要:
The invention relates to a composition comprising olefinically functionalized siloxane oligomers derived from olefinically functionalized alkoxysilanes and optionally alkoxysilanes functionalized with saturated hydrocarbons, and also, optionally, a tetraalkoxysilane, which have not more than one olefinic radical on the silicon atom, and whose chloride content is reduced, and also to processes for preparing them and to the use thereof.
摘要:
The invention relates to a process for the catalytic hydrodehalogenation of SiCl4 to form HSiCl3, which comprises bringing a gaseous feed mixture comprising hydrogen and silicon tetrachloride into direct contact with at least one heating element of a resistance heating device, with the heating element being composed of a metal or a metal alloy and being heated to carry out the reaction.
摘要:
The invention relates to the use of organofunctional carboxy compounds as catalysts for silane hydrolysis and/or catalysts for silanol condensation, wherein according to the invention, the term carboxy compounds refers to an organic acid, preferably an organic carboxylic acid with 4 to 46 carbon atoms, such as fatty acids, or an organic acid precursor compound containing silicon, an α-carboxysilane ((R3—(CO)O)4-z-xSiR2x(A)z, α-Si-oxycarbonyl-R3), or an organic acid precursor compound which does not contain silicon. The term organic acid precursor compound means esters, lactones, anhydrides, salts of organic cations. The invention also relates to the use of at least one organofunctional carboxy compound for the surface modification of substrates, the substrates modified with the same, and a kit for use in the production of the substrate.
摘要:
The invention relates to an agent for providing substrates based on cellulose and/or starch with water-repellent and simultaneously antifungal, antibacterial, insect-repellent and antialgal properties, which contains water and, as active substance, at least one linear, cyclic, branched or crosslinked co-oligomer or mixtures of co-oligomers from the series consisting of the alkyl-/aminoalkyl-/alkoxy- or hydroxy-siloxanes, the use of such agents and a special treatment process using such agents.
摘要:
The present invention relates to composite materials based on (a) at least one cellulose- or lignocellulose-containing material and (b) at least one aminoalkylsilane of the formula (I) R1R2N(CHR4)aSi(R3)r(OR)3-r (I), in which groups R1 and R2 are identical or different and in each case are H or a linear, branched or cyclic C1- to C20-alkyl group or an aryl group or an aminocarbyl group, it being possible for groups R1 and R2 to be optionally substituted, groups R4 are identical or different and R is H or methyl, a is from 1 to 10, R3 is H or a linear or branched C1- to C8-alkyl group, groups R are identical or different and R is H or a linear or branched C1- to C8-alkyl group and r is 0 or 1 or 2, or at least one cocondensate of at least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II) R7(CHR6)bSi(R5)p(OR)3-p (II), in which R7 is H or a vinyl group or an amino group or a glycidyloxy group or an acryloyloxy group or a methacryloyloxy group or a mercapto group or a sulfane group or a linear or branched C1- to C20-alkyl group or an aryl group, it being possible for the group R7 to be optionally substituted, groups R6 are identical or different and R6 is H or methyl, b is from 0 to 18, R5 is H or a linear or branched C1- to C8-alkyl group, groups R are identical or different and R is H or a linear or branched C1- to C8-alkyl group and p is 0 or 1 or 2, it being possible for the amino functions in the cocondensate to be partly or completely neutralized with an inorganic or organic acid, or an aqueous solution which contains at least one aminoalkylsilane of the formula (I) or at least one cocondensate based on at least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II), as a binder, such composite materials being obtainable by—treating dried or moist cellulose- or lignocellulose-containing material with—a liquid which contains at least one aminosilane compound according to the formula (I) or at least one cocondensate based on at >least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II),—bringing the cellulose or lignocellulose material thus treated into a desired form and then hot-pressing it. The present invention furthermore relates to a corresponding process for the production of composite materials and the use of aminosilane compounds according to the formula (I) or at least one cocondensate based on at least one aminoalkylsilane of the general formula (I) and at least one further functional silane of the general formula (II) as a binder for producing wood-based materials.
摘要:
The present invention relates to a composite material based on (a) a cellulose- or lignocellulose-containing material and (b) a composite as a binder, the composite resulting from the reaction of at least the components (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having a solids content of >20% by weight, (iii) an organic acid as a hydrolysis catalyst and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as a crosslinking agent. The present invention furthermore relates to a process for the production of said composite materials and the use of a composite (b) as a binder for the production of wood-based materials.
摘要:
The present invention relates to a binder for composite materials comprising cellulose- or lignocellulose-containing materials, which is based on the components (i) at least one binder from the series consisting of organic resins, isocyanates, natural or near-natural binders and (ii) at least one composition based on an aminoalkylsilane. The invention furthermore relates to a composite material which is at least based on a cellulose- or lignocellulose-containing material and the abovementioned binder, a process for the production of such a composite material and the use of the binder system according to the invention for the production of wood-based materials.
摘要:
The present invention provides a composition based on the reaction at least of the following components: (i) a glycidyloxypropylalkoxysilane, (ii) an aqueous silica sol having an SiO2 content of >20% by weight, (iii) an organic acid hydrolysis catalyst, and (iv) n-propyl zirconate, butyl titanate or titanium acetylacetonate as crosslinker, a process for its preparation, and the use thereof, particularly as a composition for scratch resistant coatings, and also provides articles thus coated.