摘要:
The exhaust gas cleaner comprising a heat-resistant, porous body and a catalyst supported by the body for cleaning an exhaust gas containing substantially no fine carbonaceous particles, which is equivalent to an oxidizing atmosphere, the catalyst consisting essentially of (a) one or more alkali metal elements; (b) one or more transition metal elements in Group IB; Group IIB, Group VB, Group VIB, Group VIIB and Group VIII of the Periodic Table (excluding platinum-group elements), and Sn; and (c) one or more rare earth elements. The second catalyst consisting essentially of at least one platinum-group element, may be supported by the heat-resistant, porous body.
摘要:
The method of cleaning an exhaust gas containing nitrogen oxides and oxygen in an amount larger than its stoichiometric amount relative to unburned components in the exhaust gas which includes (a) disposing an exhaust gas cleaner comprising a heat-resistant, porous inorganic oxide body made of alumina or composite oxide thereof and impregnated with Ag or its oxide, in a flow path of the exhaust gas; (b) introducing a reducing agent selected from the group consisting of gaseous hydrocarbons, liquid hydrocarbons and aliphatic oxygen-containing organic compounds into the exhaust gas on the upstream side of the exhaust gas cleaner; and (c) bringing the exhaust gas into contact with the exhaust gas cleaner at a temperature of 200.degree.-600.degree. C., thereby removing the nitrogen oxides.
摘要:
The method of cleaning an exhaust gas containing nitrogen oxides including disposing an exhaust gas cleaner comprising a heat-resistant, porous body, which may support a catalyst consisting essentially of (a) at least one of alkali metal elements; (b) at least one of elements selected from the group consisting of Cu, Co, Mn and V, (c) at least one of rare earth elements, in a flow path of the exhaust gas, spraying a liquid hydrocarbon into a stream of the exhaust gas on the upstream side of the exhaust gas cleaner, thereby causing atomized and gasified hydrocarbon to function as a reducing agent for reducing the nitrogen oxides in the exhaust gas.
摘要:
An exhaust gas containing nitrogen oxides and particulate matter is cleaned by using an exhaust gas cleaner including a heat-resistant, porous filter; a porous ceramic powder layer formed on the filter; and a catalyst supported by the ceramic powder layer, the catalyst consisting essentially of (a) at least one of alkali metal elements, (b) cobalt and/or manganese, (c) vanadium, and (d) at least one of rare earth elements, whereby the nitrogen oxides are reduced by the particulate matter in the exhaust gas serving as a reducing agent.
摘要:
An exhaust gas containing nitrogen oxides and particulate matter is cleaned by using an exhaust gas cleaner including a heat-resistant, porous filter; a porous ceramic powder layer formed on the filter; and a catalyst supported by the ceramic powder layer, the catalyst consisting essentially of (a) at least one of alkali metal elements, (b) cobalt and/or manganese, (c) vanadium, and (d) at least one of rare earth elements, whereby the nitrogen oxides are reduced by the particulate matter in the exhaust gas serving as a reducing agent.
摘要:
Nitrogen oxides are removed from an exhaust gas containing nitrogen oxides and oxygen in a proportion larger than its stoichiometric proportion relative to unburned components in the exhaust gas, by (i) disposing an exhaust gas cleaner in a flow path, the exhaust gas cleaner comprising a first catalyst composed of 0.2-20 parts by weight (on a metal basis) of silver or silver oxide supported on a porous inorganic oxide, and a second catalyst composed of 1-50 parts by weight (on an oxide basis) of tungsten and/or vanadium supported on a porous inorganic oxide; (ii) introducing oxygen-containing organic compounds having 2 or more carbon atoms or a fuel containing the oxygen-containing organic compounds into the exhaust gas on the upstream side of the exhaust gas cleaner; and (iii) bringing the exhaust gas into contact with the exhaust gas cleaner at a temperature of 150-650° C., thereby causing a reaction of the nitrogen oxides with the oxygen-containing organic compounds to remove the nitrogen oxides.
摘要:
Nitrogen oxides are removed from an exhaust gas containing nitrogen oxides and oxygen in a proportion larger than its stoichiometric proportion relative to unburned components in the exhaust gas, by (i) disposing an exhaust gas cleaner in a flow path, the exhaust gas cleaner comprising a first catalyst composed of 0.2-20 parts by weight (on a metal basis) of silver or silver oxide supported on a porous inorganic oxide, and a second catalyst composed of 1-50 parts by weight of tungsten and/or vanadium supported on a porous inorganic oxide; (ii) introducing oxygen-containing organic compounds having 2 or more carbon atoms or a fuel containing the oxygen-containing organic compounds into the exhaust gas on the upstream side of the exhaust gas cleaner; and (iii) bringing the exhaust gas into contact with the exhaust gas cleaner at a temperature of 150-650.degree. C., thereby causing a reaction of the nitrogen oxides with the oxygen-containing organic compounds to remove the nitrogen oxides.
摘要:
An exhaust gas cleaner comprising a catalyst carried on a heat-resistant ter, the catalyst comprising (a) one or more alkali metals, (b) one or more metals selected from the group consisting of Zn, Sn and transition metals excluding platinum-group metals, and (c) one or more rare earth metals, and a method of cleaning an exhaust gas with it. Alkali metals may be added to a fuel.
摘要:
Nitrogen oxides are removed from an exhaust gas containing nitrogen oxides and oxygen in an amount larger than its stoichiometric amount relative to unburned components in the exhaust gas, by (i) disposing an exhaust gas cleaner in a flow path of the exhaust gas, the exhaust gas cleaner comprising 0.2-15 weight % (on a metal basis) of fine silver or silver oxides having an average diameter of 10-1,000 nm and supported on a porous inorganic oxide; (ii) introducing hydrocarbons and/or oxygen-containing organic compounds into the exhaust gas on the upstream side of the exhaust gas cleaner; and (iii) bringing the exhaust gas into contact with the exhaust gas cleaner at a temperature of 200.degree.-600.degree. C., thereby causing a reaction of nitrogen oxides with the hydrocarbons and/or oxygen-containing organic compounds.
摘要:
An exhaust gas cleaner comprising (a) at least one filter made of a heat-resistant and electrically insulating material for trapping floating fine particles in an exhaust gas; and (b) at least a pair of electrodes stacked with the filter alternately, voltage being applied between the adjacent electrodes to burn electrically conductive and burnable fine particles trapped in the filter by heat generated by a current flowing between the adjacent electrodes, and the direction of the flow of the exhaust gas in the filter being essentially parallel to that of the laminate surface of the electrodes. The filter may carry a catalyst which functions to reduce harmful gas components in the exhaust gas.