摘要:
A method for decreasing the amount of hydrogen and coke produced during the cracking of hydrocarbon feedstock to lower molecular weight products in a reaction zone is disclosed, where the feedstock contains at least one metal contaminant selected from the class consisting of nickel, vanadium and iron and where the contaminant becomes deposited on the catalyst such that at least 50 wt. % of the total of the metal contaminants comprises only one of the metal contaminants. The method comprises monitoring the composition of the metal contaminant on the catalyst, adding an effective passivating amount of at least one of the metal contaminants which is not the major contaminant on the catalyst and passing catalyst from the reaction zone through a regeneration zone operated under net reducing conditions and through a reduction zone maintained at an elevated temperature.
摘要:
The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprised of at least one chemical element selected from Groups 3-11 (including the lanthanides, atomic numbers 58 to 71), and at least one chemical element selected from Groups 13-15 from the IUPAC Periodic Table of Elements. These interstitial metal hydrides, their catalysts and processes using these interstitial metal hydrides and catalysts of the present invention improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.
摘要:
The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprised of at least one chemical element selected from Groups 3-11 (including the lanthanides, atomic numbers 58 to 71), and at least one chemical element selected from Groups 13-15 from the IUPAC Periodic Table of Elements. These interstitial metal hydrides, their catalysts and processes using these interstitial metal hydrides and catalysts of the present invention improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.
摘要:
The present invention relates to novel interstitial metal hydrides and catalyst containing interstitial metal hydrides that are resistant to oxidation and resultant loss of catalytic activity. The processes of the present invention include use of these improved, oxidation resistant interstitial metal hydride compositions for improved overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.
摘要:
The present invention relates to the processing of hydrocarbon-containing feedstreams in the presence of an interstitial metal hydride comprised of at least one chemical element selected from Groups 3-11 (including the lanthanides, atomic numbers 58 to 71), and at least one chemical element selected from Groups 13-15 from the IUPAC Periodic Table of Elements. These interstitial metal hydrides, their catalysts and processes using these interstitial metal hydrides and catalysts of the present invention improve overall hydrogenation, product conversion, as well as sulfur reduction in hydrocarbon feedstreams.
摘要:
A slurry hydroconversion process is provided wherein a heavy hydrocarbonaceous oil, in which is dispersed a metal-contaminated, partially deactivated zeolitic cracking catalyst, is converted to lower boiling products in the presence of a molecular hydrogen-containing gas, and a hydrogen donor diluent.
摘要:
A process for upgrading a heavy hydrocarbonaceous oil is provided in which the heavy oil is hydrorefined in the presence of a hydrorefining catalyst at conditions to convert a portion of the heavy constituents of the oil, followed by cracking the hydrorefined oil in the presence of the hydrogen donor diluent. The hydrorefining and cracking stages are conducted at a relatively low hydrogen partial pressure while obtaining a high level of conversion of the heavy constituents of the oil.
摘要:
A method for decreasing the amount of coke produced during the cracking of hydrocarbon feedstock to lower molecular weight products in a reaction zone is disclosed, where the feedstock contains at least two metal contaminants selected from the class consisting of nickel, vanadium and iron, and where these contaminants become deposited on the catalyst. The method comprises adding a hydrogen donor material to the reaction zone and passing the catalyst from the reaction zone through a reduction zone maintained at an elevated temperature for a time sufficient to at least partially passivate the catalyst.
摘要:
A distillate fuel composition boiling in the range of about 190° C. to 400° C. with a T10 point greater than 205° C., and having a sulfur level of less than about 100 wppm, a total aromatics content of about 15 to 35 wt. %, a polynuclear aromatics content of less than about 3 wt. %, wherein the ratio of total aromatics to polynuclear aromatics is greater than about 11.
摘要:
A process for producing distillate boiling range streams that are low in both sulfur and aromatics. A distillate feedstock is treated in a first hydrodesulfurization stage in the presence of a hydrogen-containing treat gas and a hydrodesulfurization catalyst, thereby resulting in partial desufurization of the stream. The partially desulfurized distillate stream is then treated in a second hydrodesulfurization stage, also in the presence of a hydrogen-containing treat gas and a hydrodesulfurization catalyst. The hydrogen-containing treat gas is cascaded from the next downstream reaction stage, which is an aromatics hydrogenation stage.